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Title: Ultrahigh temperature in situ transmission electron microscopy based bicrystal coble creep in Zirconia II: Interfacial thermodynamics and transport mechanisms

Abstract

This work uses a combination of stress dependent single grain boundary Coble creep and zero-creep experiments to measure interfacial energies, along with grain boundary point defect formation and migration volumes in cubic ZrO2. These data, along with interfacial diffusivities measured in a companion paper are then applied to analyzing two-particle sintering. The analysis presented here indicates that the large activation volume, v * = v f + v m primarily derives from a large migration volume and suggests that the grain boundary rate limiting defects are delocalized, possibly due to electrostatic interactions between charge compensating defects. The discrete nature of the sintering and creep process observed in the small-scale experiments supports the hypothesis that grain boundary dislocations serve as sources and sinks for grain boundary point defects and facilitate strain during sintering and Coble creep. Model two-particle sintering experiments demonstrate that initial-stage densification follows interface reaction rate-limited kinetics.

Authors:
 [1];  [2];  [3];  [4];  [5];  [6];  [3];  [7];  [5];  [2];  [7];  [6]
  1. Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering; Energy and Nuclear Research Inst., Sao Paulo (Brazil); Univ. of California, Davis, CA (United States). Dept. of Materials Science and Engineering
  2. Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering
  3. Sun Yat-Sen Univ., Zhuhai (China). School of Chemical Engineering and Technology
  4. Energy and Nuclear Research Inst., Sao Paulo (Brazil)
  5. Univ. of California, Davis, CA (United States). Dept. of Materials Science and Engineering
  6. Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering
  7. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Materials, Physical, and Chemical Sciences
Publication Date:
Research Org.:
Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Center for Integrated Nanotechnologies (CINT)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA); São Paulo Research Foundation (FAPESP); Coordination for the Improvement of Higher Education Personnel of Brazil (CAPES); National Council for Scientific and Technological Development (CNPq); US Army Research Office (ARO); US Department of the Navy, Office of Naval Research (ONR)
OSTI Identifier:
1667415
Report Number(s):
SAND-2020-9026J
Journal ID: ISSN 1359-6454; 690250
Grant/Contract Number:  
AC04-94AL85000; DMR-1922867; 2016/06205-1; 2017/25501-3; 305889/2018-4; W911NF1810361; W911NF1710026; ONR N00014- 17-1-2087; FWP-15013170; NA-0003525
Resource Type:
Accepted Manuscript
Journal Name:
Acta Materialia
Additional Journal Information:
Journal Volume: 200; Journal ID: ISSN 1359-6454
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Grosso, Robson L., Vikrant, K. S. N., Feng, Lin, Muccillo, Eliana N. S., Muche, Dereck N. F., Jawaharram, Gowtham S., Barr, Christopher M., Monterrosa, Anthony M., Castro, Ricardo H. R., Garcia, R. Edwin, Hattar, Khalid Mikhiel, and Dillon, Shen J.. Ultrahigh temperature in situ transmission electron microscopy based bicrystal coble creep in Zirconia II: Interfacial thermodynamics and transport mechanisms. United States: N. p., 2020. Web. https://doi.org/10.1016/j.actamat.2020.08.070.
Grosso, Robson L., Vikrant, K. S. N., Feng, Lin, Muccillo, Eliana N. S., Muche, Dereck N. F., Jawaharram, Gowtham S., Barr, Christopher M., Monterrosa, Anthony M., Castro, Ricardo H. R., Garcia, R. Edwin, Hattar, Khalid Mikhiel, & Dillon, Shen J.. Ultrahigh temperature in situ transmission electron microscopy based bicrystal coble creep in Zirconia II: Interfacial thermodynamics and transport mechanisms. United States. https://doi.org/10.1016/j.actamat.2020.08.070
Grosso, Robson L., Vikrant, K. S. N., Feng, Lin, Muccillo, Eliana N. S., Muche, Dereck N. F., Jawaharram, Gowtham S., Barr, Christopher M., Monterrosa, Anthony M., Castro, Ricardo H. R., Garcia, R. Edwin, Hattar, Khalid Mikhiel, and Dillon, Shen J.. Fri . "Ultrahigh temperature in situ transmission electron microscopy based bicrystal coble creep in Zirconia II: Interfacial thermodynamics and transport mechanisms". United States. https://doi.org/10.1016/j.actamat.2020.08.070. https://www.osti.gov/servlets/purl/1667415.
@article{osti_1667415,
title = {Ultrahigh temperature in situ transmission electron microscopy based bicrystal coble creep in Zirconia II: Interfacial thermodynamics and transport mechanisms},
author = {Grosso, Robson L. and Vikrant, K. S. N. and Feng, Lin and Muccillo, Eliana N. S. and Muche, Dereck N. F. and Jawaharram, Gowtham S. and Barr, Christopher M. and Monterrosa, Anthony M. and Castro, Ricardo H. R. and Garcia, R. Edwin and Hattar, Khalid Mikhiel and Dillon, Shen J.},
abstractNote = {This work uses a combination of stress dependent single grain boundary Coble creep and zero-creep experiments to measure interfacial energies, along with grain boundary point defect formation and migration volumes in cubic ZrO2. These data, along with interfacial diffusivities measured in a companion paper are then applied to analyzing two-particle sintering. The analysis presented here indicates that the large activation volume, v*=vf+vmprimarily derives from a large migration volume and suggests that the grain boundary rate limiting defects are delocalized, possibly due to electrostatic interactions between charge compensating defects. The discrete nature of the sintering and creep process observed in the small-scale experiments supports the hypothesis that grain boundary dislocations serve as sources and sinks for grain boundary point defects and facilitate strain during sintering and Coble creep. Model two-particle sintering experiments demonstrate that initial-stage densification follows interface reaction rate-limited kinetics.},
doi = {10.1016/j.actamat.2020.08.070},
journal = {Acta Materialia},
number = ,
volume = 200,
place = {United States},
year = {2020},
month = {8}
}

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