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Title: Cleavable magnetic materials from van der Waals layered transition metal halides and chalcogenides

Abstract

The study of exfoliated 2D magnetic materials is a vibrant and rapidly progressing field and is impacting many areas of condensed matter research including fundamental magnetism, spintronics and optoelectronics, and topological spin and electronic systems. The availability of promising candidate materials has enabled much of the progress in this field. Here, I present my perspective on the development of cleavable magnetic materials with a focus on transition metal halides and chalcogenides and an emphasis on crystal structure and magnetic order. To give proper context for these discussions, brief and incomplete surveys of recent work are included, focusing on specific aspects that I find most useful for guiding work on emerging materials and motivating expansion into other compounds and material families. Several instances of structural changes that can differentiate behaviors of bulk and ultrathin specimens are noted. Probing and understanding potential structural differences present a challenge but also an opportunity for material and device development, if they can be predicted and controlled. It is clear that careful investigations of structure, layer stacking, and defects in materials, how they may relate to the crystal chemistry, and how they may be different in crystals and mono- or few-layer specimens provide invaluable context formore » understanding the behavior of van der Waals layered magnetic materials.« less

Authors:
ORCiD logo [1]
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1665987
Alternate Identifier(s):
OSTI ID: 1664476
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Applied Physics
Additional Journal Information:
Journal Volume: 128; Journal Issue: 11; Journal ID: ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Spintronics; Chalcogenides; Chemical compounds; Heterostructures; Ferromagnetism; Phase transitions; Crystallography; Magnetic materials; Optical electronics; Transition metals

Citation Formats

McGuire, Michael A. Cleavable magnetic materials from van der Waals layered transition metal halides and chalcogenides. United States: N. p., 2020. Web. https://doi.org/10.1063/5.0023729.
McGuire, Michael A. Cleavable magnetic materials from van der Waals layered transition metal halides and chalcogenides. United States. https://doi.org/10.1063/5.0023729
McGuire, Michael A. Mon . "Cleavable magnetic materials from van der Waals layered transition metal halides and chalcogenides". United States. https://doi.org/10.1063/5.0023729.
@article{osti_1665987,
title = {Cleavable magnetic materials from van der Waals layered transition metal halides and chalcogenides},
author = {McGuire, Michael A.},
abstractNote = {The study of exfoliated 2D magnetic materials is a vibrant and rapidly progressing field and is impacting many areas of condensed matter research including fundamental magnetism, spintronics and optoelectronics, and topological spin and electronic systems. The availability of promising candidate materials has enabled much of the progress in this field. Here, I present my perspective on the development of cleavable magnetic materials with a focus on transition metal halides and chalcogenides and an emphasis on crystal structure and magnetic order. To give proper context for these discussions, brief and incomplete surveys of recent work are included, focusing on specific aspects that I find most useful for guiding work on emerging materials and motivating expansion into other compounds and material families. Several instances of structural changes that can differentiate behaviors of bulk and ultrathin specimens are noted. Probing and understanding potential structural differences present a challenge but also an opportunity for material and device development, if they can be predicted and controlled. It is clear that careful investigations of structure, layer stacking, and defects in materials, how they may relate to the crystal chemistry, and how they may be different in crystals and mono- or few-layer specimens provide invaluable context for understanding the behavior of van der Waals layered magnetic materials.},
doi = {10.1063/5.0023729},
journal = {Journal of Applied Physics},
number = 11,
volume = 128,
place = {United States},
year = {2020},
month = {9}
}

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Works referenced in this record:

VI 3 —a New Layered Ferromagnetic Semiconductor
journal, March 2019

  • Kong, Tai; Stolze, Karoline; Timmons, Erik I.
  • Advanced Materials, Vol. 31, Issue 17
  • DOI: 10.1002/adma.201808074

Controlling the Magnetic Anisotropy of the van der Waals Ferromagnet Fe 3 GeTe 2 through Hole Doping
journal, November 2019


Magnetic behavior and spin-lattice coupling in cleavable van der Waals layered CrCl 3 crystals
journal, June 2017


Van der Waals magnets: Wonder building blocks for two‐dimensional spintronics?
journal, October 2019

  • Zhang, Wen; Wong, Ping Kwan Johnny; Zhu, Rui
  • InfoMat, Vol. 1, Issue 4
  • DOI: 10.1002/inf2.12048

Single-layer metal halides MX 2 (X = Cl, Br, I): stability and tunable magnetism from first principles and Monte Carlo simulations
journal, January 2017

  • Kulish, Vadym V.; Huang, Wei
  • Journal of Materials Chemistry C, Vol. 5, Issue 34
  • DOI: 10.1039/C7TC02664A

Probing Magnetism in Insulating Cr 2 Ge 2 Te 6 by Induced Anomalous Hall Effect in Pt
journal, March 2019


Record High-Proximity-Induced Anomalous Hall Effect in (Bi x Sb 1– x ) 2 Te 3 Thin Film Grown on CrGeTe 3 Substrate
journal, June 2019


Excitations in the field-induced quantum spin liquid state of α-RuCl3
journal, February 2018

  • Banerjee, Arnab; Lampen-Kelley, Paula; Knolle, Johannes
  • npj Quantum Materials, Vol. 3, Issue 1
  • DOI: 10.1038/s41535-018-0079-2

Two-dimensional itinerant ferromagnetism in atomically thin Fe3GeTe2
journal, August 2018


Cation–Eutectic Transition via Sublattice Melting in CuInP 2 S 6 /In 4/3 P 2 S 6 van der Waals Layered Crystals
journal, July 2017

  • Susner, Michael A.; Chyasnavichyus, Marius; Puretzky, Alexander A.
  • ACS Nano, Vol. 11, Issue 7
  • DOI: 10.1021/acsnano.7b02695

Accessing new magnetic regimes by tuning the ligand spin-orbit coupling in van der Waals magnets
journal, July 2020

  • Tartaglia, Thomas A.; Tang, Joseph N.; Lado, Jose L.
  • Science Advances, Vol. 6, Issue 30
  • DOI: 10.1126/sciadv.abb9379

Room-temperature ferroelectricity in CuInP2S6 ultrathin flakes
journal, August 2016

  • Liu, Fucai; You, Lu; Seyler, Kyle L.
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12357

Magnetic-Field Induced Competition of Two Multiferroic Orders in a Triangular-Lattice Helimagnet MnI 2
journal, April 2011


Coupling of Crystal Structure and Magnetism in the Layered, Ferromagnetic Insulator CrI 3
journal, January 2015

  • McGuire, Michael A.; Dixit, Hemant; Cooper, Valentino R.
  • Chemistry of Materials, Vol. 27, Issue 2
  • DOI: 10.1021/cm504242t

Bulk properties of the van der Waals hard ferromagnet VI 3
journal, January 2019


On CuCrP2S6: Copper Disorder, Stacking Distortions, and Magnetic Ordering
journal, April 1995

  • Maisonneuve, V.; Payen, C.; Cajipe, V. B.
  • Journal of Solid State Chemistry, Vol. 116, Issue 1
  • DOI: 10.1006/jssc.1995.1204

Multiple ferromagnetic transitions and structural distortion in the van der Waals ferromagnet VI 3 at ambient and finite pressures
journal, September 2019


Topological Axion States in the Magnetic Insulator MnBi 2 Te 4 with the Quantized Magnetoelectric Effect
journal, May 2019


Strong room-temperature ferromagnetism in VSe2 monolayers on van der Waals substrates
journal, February 2018


Absence of Ferromagnetism in VSe 2 Caused by Its Charge Density Wave Phase
journal, October 2019

  • Fumega, Adolfo O.; Gobbi, M.; Dreher, P.
  • The Journal of Physical Chemistry C, Vol. 123, Issue 45
  • DOI: 10.1021/acs.jpcc.9b08868

Phase transition upon d10 Cd2+ ordering in CdPS3
journal, December 1995

  • Boucher, F.; Evain, M.; Brec, R.
  • Acta Crystallographica Section B Structural Science, Vol. 51, Issue 6
  • DOI: 10.1107/S0108768195004824

Magnetic structure and phase stability of the van der Waals bonded ferromagnet Fe 3 x GeTe 2
journal, January 2016


Intrinsic Van Der Waals Magnetic Materials from Bulk to the 2D Limit: New Frontiers of Spintronics
journal, May 2019


Direct observation of van der Waals stacking–dependent interlayer magnetism
journal, November 2019


Van der Waals engineering of ferromagnetic semiconductor heterostructures for spin and valleytronics
journal, May 2017


Probing the Magnetic Ordering of Antiferromagnetic MnPS 3 by Raman Spectroscopy
journal, May 2019

  • Sun, Yu-Jia; Tan, Qing-Hai; Liu, Xue-Lu
  • The Journal of Physical Chemistry Letters, Vol. 10, Issue 11
  • DOI: 10.1021/acs.jpclett.9b00758

Can Reconstructed Se‐Deficient Line Defects in Monolayer VSe 2 Induce Magnetism?
journal, May 2020


Raman spectroscopy of atomically thin two-dimensional magnetic iron phosphorus trisulfide (FePS 3 ) crystals
journal, August 2016


Low-temperature crystal and magnetic structure of α RuCl 3
journal, April 2016


Crystal structures and phase transitions of the van der Waals ferromagnet V I 3
journal, December 2019


Proximate Kitaev quantum spin liquid behaviour in a honeycomb magnet
journal, April 2016

  • Banerjee, A.; Bridges, C. A.; Yan, J. -Q.
  • Nature Materials, Vol. 15, Issue 7
  • DOI: 10.1038/nmat4604

Metal Thio- and Selenophosphates as Multifunctional van der Waals Layered Materials
journal, August 2017

  • Susner, Michael A.; Chyasnavichyus, Marius; McGuire, Michael A.
  • Advanced Materials, Vol. 29, Issue 38
  • DOI: 10.1002/adma.201602852

Observation of Magnetic Skyrmion Bubbles in a van der Waals Ferromagnet Fe 3 GeTe 2
journal, December 2019


Successive phase transitions in the hexagonal-layered Heisenberg antiferromagnets MnX2 (X = Br, I)
journal, August 1995


Magnetic interactions in the layer compounds MPX3 (M = Mn, Fe, Ni; X = S, Se)
journal, January 1982


Magnetic order in α RuCl 3 : A honeycomb-lattice quantum magnet with strong spin-orbit coupling
journal, April 2015


A-type antiferromagnetic order in MnBi 4 Te 7 and MnBi 6 Te 10 single crystals
journal, May 2020


Evolution of structural, magnetic, and transport properties in MnBi 2 x Sb x Te 4
journal, September 2019


Multiferroicity in NiBr 2 with long-wavelength cycloidal spin structure on a triangular lattice
journal, August 2011


Nearly room temperature ferromagnetism in a magnetic metal-rich van der Waals metal
journal, January 2020


Majorana fermions in the Kitaev quantum spin system α-RuCl3
journal, September 2017

  • Do, Seung-Hwan; Park, Sang-Youn; Yoshitake, Junki
  • Nature Physics, Vol. 13, Issue 11
  • DOI: 10.1038/nphys4264

Interplay between interlayer exchange and stacking in CrI3 bilayers
journal, September 2019


Ferromagnetic van der Waals Crystal VI 3
journal, March 2019

  • Tian, Shangjie; Zhang, Jian-Feng; Li, Chenghe
  • Journal of the American Chemical Society, Vol. 141, Issue 13
  • DOI: 10.1021/jacs.8b13584

Crystal and Magnetic Structures in Layered, Transition Metal Dihalides and Trihalides
journal, April 2017


Ferrielectric ordering in lamellar CuInP 2 S 6
journal, November 1997


Realization of interlayer ferromagnetic interaction in MnS b 2 T e 4 toward the magnetic Weyl semimetal state
journal, November 2019


Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit
journal, June 2017

  • Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén
  • Nature, Vol. 546, Issue 7657
  • DOI: 10.1038/nature22391

Thickness dependence of the charge-density-wave transition temperature in VSe 2
journal, August 2014

  • Yang, Jiyong; Wang, Weike; Liu, Yan
  • Applied Physics Letters, Vol. 105, Issue 6
  • DOI: 10.1063/1.4893027

Ultrathin nanosheets of CrSiTe 3 : a semiconducting two-dimensional ferromagnetic material
journal, January 2016

  • Lin, Ming-Wei; Zhuang, Houlong L.; Yan, Jiaqiang
  • Journal of Materials Chemistry C, Vol. 4, Issue 2
  • DOI: 10.1039/C5TC03463A

Crystal and magnetic structures of magnetic topological insulators MnBi 2 Te 4 and MnBi 4 Te 7
journal, January 2020


Electronic structure and magnetism of transition metal dihalides: Bulk to monolayer
journal, April 2019


Thickness‐Dependent In‐Plane Polarization and Structural Phase Transition in van der Waals Ferroelectric CuInP 2 S 6
journal, December 2019


Magnetic 2D materials and heterostructures
journal, May 2019


Electronic Properties of α RuCl 3 in Proximity to Graphene
journal, December 2019


Two-dimensional materials from high-throughput computational exfoliation of experimentally known compounds
journal, February 2018

  • Mounet, Nicolas; Gibertini, Marco; Schwaller, Philippe
  • Nature Nanotechnology, Vol. 13, Issue 3
  • DOI: 10.1038/s41565-017-0035-5

Magnetic Properties of Restacked 2D Spin 1/2 honeycomb RuCl 3 Nanosheets
journal, May 2016


Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures
journal, May 2018


Controlling Magnetic and Optical Properties of the van der Waals Crystal CrCl 3− x Br x via Mixed Halide Chemistry
journal, May 2018

  • Abramchuk, Mykola; Jaszewski, Samantha; Metz, Kenneth R.
  • Advanced Materials, Vol. 30, Issue 25
  • DOI: 10.1002/adma.201801325

Switching 2D magnetic states via pressure tuning of layer stacking
journal, October 2019


Atomically Thin CrCl 3 : An In-Plane Layered Antiferromagnetic Insulator
journal, April 2019


Recent advances in two-dimensional ferromagnetism: materials synthesis, physical properties and device applications
journal, January 2020

  • Huang, Pu; Zhang, Peng; Xu, Shaogang
  • Nanoscale, Vol. 12, Issue 4
  • DOI: 10.1039/C9NR08890C

Charge Density Wave State Suppresses Ferromagnetic Ordering in VSe 2 Monolayers
journal, May 2019

  • Coelho, Paula Mariel; Nguyen Cong, Kien; Bonilla, Manuel
  • The Journal of Physical Chemistry C, Vol. 123, Issue 22
  • DOI: 10.1021/acs.jpcc.9b04281

The question of silver pairing in the new structurally resolved two-dimensional phase Ag2MnP2S6
journal, January 1991


Unconventional superconductivity in magic-angle graphene superlattices
journal, March 2018


Exfoliation and Raman Spectroscopic Fingerprint of Few-Layer NiPS3 Van der Waals Crystals
journal, February 2016

  • Kuo, Cheng-Tai; Neumann, Michael; Balamurugan, Karuppannan
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep20904

Coexistence of Magnetic Orders in Two-Dimensional Magnet CrI 3
journal, November 2019


Efficient Spin‐Orbit Torque Switching of the Semiconducting Van Der Waals Ferromagnet Cr 2 Ge 2 Te 6
journal, November 2019

  • Ostwal, Vaibhav; Shen, Tingting; Appenzeller, Joerg
  • Advanced Materials, Vol. 32, Issue 7
  • DOI: 10.1002/adma.201906021

Ferroelectric Field-Effect Transistors Based on MoS 2 and CuInP 2 S 6 Two-Dimensional van der Waals Heterostructure
journal, June 2018


Physical properties and thermal stability of Fe 5 x GeTe 2 single crystals
journal, October 2019


Magnetic-Field-Induced Quantum Phase Transitions in a van der Waals Magnet
journal, March 2020


Tunable quadruple-well ferroelectric van der Waals crystals
journal, November 2019


Prospects and Opportunities of 2D van der Waals Magnetic Systems
journal, March 2020

  • Wang, Meng‐Chien; Huang, Che‐Chun; Cheung, Chi‐Ho
  • Annalen der Physik, Vol. 532, Issue 5
  • DOI: 10.1002/andp.201900452

From negative to positive magnetoresistance in the intrinsic magnetic topological insulator MnB i 2 T e 4
journal, February 2020


Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling
journal, May 2018


Possible structural transformation and enhanced magnetic fluctuations in exfoliated α-RuCl3
journal, May 2019

  • Zhou, Boyi; Wang, Yiping; Osterhoudt, Gavin B.
  • Journal of Physics and Chemistry of Solids, Vol. 128
  • DOI: 10.1016/j.jpcs.2018.01.026

Crystal structure reconstruction in the surface monolayer of the quantum spin liquid candidate α -RuCl 3
journal, May 2020


The magnetic properties and structure of the quasi-two-dimensional antiferromagnet CoPS 3
journal, October 2017

  • Wildes, A. R.; Simonet, V.; Ressouche, E.
  • Journal of Physics: Condensed Matter, Vol. 29, Issue 45
  • DOI: 10.1088/1361-648X/aa8a43

Chemically Exfoliated VSe 2 Monolayers with Room‐Temperature Ferromagnetism
journal, August 2019


In-Plane Magnetic Domains and Néel-like Domain Walls in Thin Flakes of the Room Temperature CrTe 2 Van der Waals Ferromagnet
journal, June 2020

  • Purbawati, Anike; Coraux, Johann; Vogel, Jan
  • ACS Applied Materials & Interfaces, Vol. 12, Issue 27
  • DOI: 10.1021/acsami.0c07017

van der Waals Layered Materials: Opportunities and Challenges
journal, October 2016


Determination of Anomalous Superexchange in MnC l 2 and Its Graphite Intercalation Compound
journal, July 1995

  • Wiesler, David G.; Suzuki, Masatsugu; Suzuki, Itsuko S.
  • Physical Review Letters, Vol. 75, Issue 5
  • DOI: 10.1103/PhysRevLett.75.942

Discovery of stable and intrinsic antiferromagnetic iron oxyhalide monolayers
journal, January 2020

  • Wang, Shiyao; Wang, Junjie; Khazaei, Mohammad
  • Physical Chemistry Chemical Physics, Vol. 22, Issue 20
  • DOI: 10.1039/D0CP01767A

Hard ferromagnetic van-der-Waals metal (Fe,Co) 3 GeTe 2 : a new platform for the study of low-dimensional magnetic quantum criticality
journal, September 2019

  • Hwang, Inho; Coak, Matthew J.; Lee, Nahyun
  • Journal of Physics: Condensed Matter, Vol. 31, Issue 50
  • DOI: 10.1088/1361-648X/ab3135

Low-temperature monoclinic layer stacking in atomically thin CrI 3 crystals
journal, November 2019


Chemical disorder and spin-liquid-like magnetism in the van der Waals layered 5 d transition metal halide Os 0.55 Cl 2
journal, June 2019


Intrinsic magnetic topological insulators in van der Waals layered MnBi 2 Te 4 -family materials
journal, June 2019


Two-dimensional magnetic crystals and emergent heterostructure devices
journal, February 2019


Van der Waals 2D Transition Metal Tellurides
journal, August 2019

  • Su, Jianwei; Liu, Kailang; Wang, Fakun
  • Advanced Materials Interfaces, Vol. 6, Issue 19
  • DOI: 10.1002/admi.201900741

Controlling magnetism in 2D CrI3 by electrostatic doping
journal, May 2018


Monoclinic crystal structure of α RuCl 3 and the zigzag antiferromagnetic ground state
journal, December 2015


Neutron-Diffraction Study of Antiferromagnetic Fe Cl 3
journal, August 1962


Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals
journal, April 2017


Suppression of magnetic ordering in XXZ-type antiferromagnetic monolayer NiPS3
journal, January 2019


Gate-tunable room-temperature ferromagnetism in two-dimensional Fe3GeTe2
journal, October 2018


Enhancement of interlayer exchange in an ultrathin two-dimensional magnet
journal, September 2019


Magnon-assisted tunnelling in van der Waals heterostructures based on CrBr3
journal, June 2018


Stacking-Dependent Magnetism in Bilayer CrI 3
journal, November 2018


Chemical Aspects of the Candidate Antiferromagnetic Topological Insulator MnBi 2 Te 4
journal, March 2019


Probing and controlling magnetic states in 2D layered magnetic materials
journal, September 2019


The van der Waals Ferromagnets Fe 5- δ GeTe 2 and Fe 5- δ -x Ni x GeTe 2 - Crystal Structure, Stacking Faults, and Magnetic Properties : The van der Waals Ferromagnets Fe
journal, November 2018

  • Stahl, Juliane; Shlaen, Evgeniya; Johrendt, Dirk
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 644, Issue 24
  • DOI: 10.1002/zaac.201800456

Persistence of Magnetism in Atomically Thin MnPS 3 Crystals
journal, March 2020


Fe3GeTe2 and Ni3GeTe2 – Two New Layered Transition-Metal Compounds: Crystal Structures, HRTEM Investigations, and Magnetic and Electrical Properties
journal, April 2006

  • Deiseroth, Hans-Jörg; Aleksandrov, Krasimir; Reiner, Christof
  • European Journal of Inorganic Chemistry, Vol. 2006, Issue 8
  • DOI: 10.1002/ejic.200501020

Majorana quantization and half-integer thermal quantum Hall effect in a Kitaev spin liquid
journal, July 2018


Crystal structure and magnetic properties of the layered van der Waals compound VB r 3
journal, August 2019


Current-driven magnetization switching in a van der Waals ferromagnet Fe 3 GeTe 2
journal, August 2019


Quantum anomalous Hall effect in intrinsic magnetic topological insulator MnBi 2 Te 4
journal, January 2020


Skyrmions in the Moiré of van der Waals 2D Magnets
journal, October 2018


Ising-Type Magnetic Ordering in Atomically Thin FePS 3
journal, November 2016


Direct Photoluminescence Probing of Ferromagnetism in Monolayer Two-Dimensional CrBr 3
journal, March 2019


Magnetism in two-dimensional van der Waals materials
journal, October 2018


Evolution of interlayer and intralayer magnetism in three atomically thin chromium trihalides
journal, May 2019

  • Kim, Hyun Ho; Yang, Bowen; Li, Siwen
  • Proceedings of the National Academy of Sciences, Vol. 116, Issue 23
  • DOI: 10.1073/pnas.1902100116

Ferromagnetism Near Room Temperature in the Cleavable van der Waals Crystal Fe 5 GeTe 2
journal, March 2019


Natural van der Waals heterostructural single crystals with both magnetic and topological properties
journal, November 2019


Neutron diffraction study of the layered compounds MnPSe3 and FePSe3
journal, December 1981


Room Temperature Intrinsic Ferromagnetism in Epitaxial Manganese Selenide Films in the Monolayer Limit
journal, April 2018


Size-effect in layered ferrielectric CuInP2S6
journal, October 2016

  • Chyasnavichyus, Marius; Susner, Michael A.; Ievlev, Anton V.
  • Applied Physics Letters, Vol. 109, Issue 17
  • DOI: 10.1063/1.4965837

Magnetic structure of FeI2 by neutron diffraction experiments
journal, January 1974


Materials design of Kitaev spin liquids beyond the Jackeli–Khaliullin mechanism
journal, June 2020

  • Motome, Yukitoshi; Sano, Ryoya; Jang, Seonghoon
  • Journal of Physics: Condensed Matter, Vol. 32, Issue 40
  • DOI: 10.1088/1361-648X/ab8525

Chromium sulfide halide monolayers: intrinsic ferromagnetic semiconductors with large spin polarization and high carrier mobility
journal, January 2018

  • Guo, Yilv; Zhang, Yehui; Yuan, Shijun
  • Nanoscale, Vol. 10, Issue 37
  • DOI: 10.1039/C8NR06368K

2D Intrinsic Ferromagnets from van der Waals Antiferromagnets
journal, February 2018

  • Miao, Naihua; Xu, Bin; Zhu, Linggang
  • Journal of the American Chemical Society, Vol. 140, Issue 7
  • DOI: 10.1021/jacs.7b12976

Ferromagnetism in layered metastable 1 T -CrTe 2
journal, April 2015


Giant nonreciprocal second-harmonic generation from antiferromagnetic bilayer CrI3
journal, July 2019