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Title: Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts

Authors:
 [1];  [2];  [1];  [1];  [1];  [2];  [3];  [4];  [4];  [2]; ORCiD logo [1]
  1. Department of Chemical and Biological Engineering University at Buffalo, The State University of New York Buffalo NY 14260 USA
  2. School of Chemical, Biological, and Environmental Engineering Oregon State University Corvallis OR 97331 USA
  3. DND-CAT Synchrotron Research Center Northwestern University Evanston IL 60208 USA
  4. Materials Science and Technology Division Oak Ridge National Laboratory Oak Ridge TN 37831 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1664565
Grant/Contract Number:  
EE0008075, DE-EE0008076, and DE-EE0008417
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Angewandte Chemie
Additional Journal Information:
Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 48; Journal ID: ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Liu, Shengwen, Wang, Maoyu, Yang, Xiaoxuan, Shi, Qiurong, Qiao, Zhi, Lucero, Marcos, Ma, Qing, More, Karren L., Cullen, David A., Feng, Zhenxing, and Wu, Gang. Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts. Germany: N. p., 2020. Web. https://doi.org/10.1002/ange.202009331.
Liu, Shengwen, Wang, Maoyu, Yang, Xiaoxuan, Shi, Qiurong, Qiao, Zhi, Lucero, Marcos, Ma, Qing, More, Karren L., Cullen, David A., Feng, Zhenxing, & Wu, Gang. Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts. Germany. https://doi.org/10.1002/ange.202009331
Liu, Shengwen, Wang, Maoyu, Yang, Xiaoxuan, Shi, Qiurong, Qiao, Zhi, Lucero, Marcos, Ma, Qing, More, Karren L., Cullen, David A., Feng, Zhenxing, and Wu, Gang. Wed . "Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts". Germany. https://doi.org/10.1002/ange.202009331.
@article{osti_1664565,
title = {Chemical Vapor Deposition for Atomically Dispersed and Nitrogen Coordinated Single Metal Site Catalysts},
author = {Liu, Shengwen and Wang, Maoyu and Yang, Xiaoxuan and Shi, Qiurong and Qiao, Zhi and Lucero, Marcos and Ma, Qing and More, Karren L. and Cullen, David A. and Feng, Zhenxing and Wu, Gang},
abstractNote = {},
doi = {10.1002/ange.202009331},
journal = {Angewandte Chemie},
number = 48,
volume = 132,
place = {Germany},
year = {2020},
month = {9}
}

Journal Article:
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This content will become publicly available on August 21, 2021
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Works referenced in this record:

Fabricating Single‐Atom Catalysts from Chelating Metal in Open Frameworks
journal, February 2019


Evolution Pathway from Iron Compounds to Fe 1 (II)–N 4 Sites through Gas-Phase Iron during Pyrolysis
journal, December 2019

  • Li, Jingkun; Jiao, Li; Wegener, Evan
  • Journal of the American Chemical Society, Vol. 142, Issue 3
  • DOI: 10.1021/jacs.9b11197

Room-Temperature Organometallic Synthesis of Soluble and Crystalline ZnO Nanoparticles of Controlled Size and Shape
journal, November 2003

  • Monge, Miguel; Kahn, Myrtil L.; Maisonnat, André
  • Angewandte Chemie, Vol. 115, Issue 43
  • DOI: 10.1002/ange.200351949

Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction
journal, November 2019

  • Li, Jiazhan; Zhang, Hanguang; Samarakoon, Widitha
  • Angewandte Chemie International Edition, Vol. 58, Issue 52
  • DOI: 10.1002/anie.201909312

In situ electrochemical quantification of active sites in Fe–N/C non-precious metal catalysts
journal, October 2016

  • Malko, Daniel; Kucernak, Anthony; Lopes, Thiago
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms13285

PGM‐Free Cathode Catalysts for PEM Fuel Cells: A Mini‐Review on Stability Challenges
journal, December 2018

  • Shao, Yuyan; Dodelet, Jean‐Pol; Wu, Gang
  • Advanced Materials, Vol. 31, Issue 31
  • DOI: 10.1002/adma.201807615

3D porous graphitic nanocarbon for enhancing the performance and durability of Pt catalysts: a balance between graphitization and hierarchical porosity
journal, January 2019

  • Qiao, Zhi; Hwang, Sooyeon; Li, Xing
  • Energy & Environmental Science, Vol. 12, Issue 9
  • DOI: 10.1039/C9EE01899A

On the Influence of Oxygen on the Degradation of Fe‐N‐C Catalysts
journal, February 2020

  • Kumar, Kavita; Dubau, Laetitia; Mermoux, Michel
  • Angewandte Chemie International Edition, Vol. 59, Issue 8
  • DOI: 10.1002/anie.201912451

Atomically Dispersed Metal Catalysts for Oxygen Reduction
journal, June 2019


Structural Descriptors of Zeolitic–Imidazolate Frameworks Are Keys to the Activity of Fe–N–C Catalysts
journal, December 2016

  • Armel, Vanessa; Hindocha, Sheena; Salles, Fabrice
  • Journal of the American Chemical Society, Vol. 139, Issue 1
  • DOI: 10.1021/jacs.6b11248

Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017

  • Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
  • Angewandte Chemie International Edition, Vol. 56, Issue 24
  • DOI: 10.1002/anie.201702473

Degradation by Hydrogen Peroxide of Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction
journal, January 2015

  • Goellner, Vincent; Armel, Vanessa; Zitolo, Andrea
  • Journal of The Electrochemical Society, Vol. 162, Issue 6
  • DOI: 10.1149/2.1091506jes

Advanced Electrocatalysis for Energy and Environmental Sustainability via Water and Nitrogen Reactions
journal, July 2020


High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
journal, April 2011


Synthesis of minimal-size ZnO nanoparticles through sol–gel method: Taguchi design optimisation
journal, December 2015


Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength
journal, May 2013

  • Tian, Juan; Morozan, Adina; Sougrati, Moulay Tahar
  • Angewandte Chemie International Edition, Vol. 52, Issue 27
  • DOI: 10.1002/anie.201303025

Synthesis of porous small-sized ZnO nanoparticles and their gas-sensing performance
journal, October 2015


Atomically dispersed manganese catalysts for oxygen reduction in proton-exchange membrane fuel cells
journal, October 2018


Unveiling the high-activity origin of single-atom iron catalysts for oxygen reduction reaction
journal, June 2018

  • Yang, Liu; Cheng, Daojian; Xu, Haoxiang
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 26
  • DOI: 10.1073/pnas.1800771115

Raman spectroscopy as a versatile tool for studying the properties of graphene
journal, April 2013


Synthesis of ZnO Nanoparticles with Controlled Shapes, Sizes, Aggregations, and Surface Complex Compounds for Tuning or Switching the Photoluminescence
journal, May 2015

  • Zhang, Jianhui; Zhao, Baodan; Pan, Zhongda
  • Crystal Growth & Design, Vol. 15, Issue 7
  • DOI: 10.1021/cg5017017

Isolated Single Iron Atoms Anchored on N-Doped Porous Carbon as an Efficient Electrocatalyst for the Oxygen Reduction Reaction
journal, April 2017

  • Chen, Yuanjun; Ji, Shufang; Wang, Yanggang
  • Angewandte Chemie, Vol. 129, Issue 24
  • DOI: 10.1002/ange.201702473

Single-Iron Site Catalysts with Self-Assembled Dual-size Architecture and Hierarchical Porosity for Proton-Exchange Membrane Fuel Cells
journal, December 2020


Room-Temperature Organometallic Synthesis of Soluble and Crystalline ZnO Nanoparticles of Controlled Size and Shape
journal, November 2003

  • Monge, Miguel; Kahn, Myrtil L.; Maisonnat, André
  • Angewandte Chemie International Edition, Vol. 42, Issue 43
  • DOI: 10.1002/anie.200351949

On the Influence of Oxygen on the Degradation of Fe‐N‐C Catalysts
journal, January 2020

  • Kumar, Kavita; Dubau, Laetitia; Mermoux, Michel
  • Angewandte Chemie, Vol. 132, Issue 8
  • DOI: 10.1002/ange.201912451

In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework
journal, March 2015

  • Katsenis, Athanassios D.; Puškarić, Andreas; Štrukil, Vjekoslav
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7662

Atomic Fe Dispersed on N-Doped Carbon Hollow Nanospheres for High-Efficiency Electrocatalytic Oxygen Reduction
journal, December 2018


Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction
journal, July 2009

  • Jaouen, Frédéric; Herranz, Juan; Lefèvre, Michel
  • ACS Applied Materials & Interfaces, Vol. 1, Issue 8, p. 1623-1639
  • DOI: 10.1021/am900219g

Tailoring FeN 4 Sites with Edge Enrichment for Boosted Oxygen Reduction Performance in Proton Exchange Membrane Fuel Cell
journal, January 2019


High-performance fuel cell cathodes exclusively containing atomically dispersed iron active sites
journal, January 2019

  • Zhang, Hanguang; Chung, Hoon T.; Cullen, David A.
  • Energy & Environmental Science, Vol. 12, Issue 8
  • DOI: 10.1039/C9EE00877B

Solvent/additive-free synthesis of porous/zeolitic metal azolate frameworks from metal oxide/hydroxide
journal, January 2011

  • Lin, Jian-Bin; Lin, Rui-Biao; Cheng, Xiao-Ning
  • Chemical Communications, Vol. 47, Issue 32
  • DOI: 10.1039/c1cc12763b

Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials
journal, August 2015

  • Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa
  • Nature Materials, Vol. 14, Issue 9
  • DOI: 10.1038/nmat4367

Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation
journal, July 2019


Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength
journal, May 2013

  • Tian, Juan; Morozan, Adina; Sougrati, Moulay Tahar
  • Angewandte Chemie, Vol. 125, Issue 27
  • DOI: 10.1002/ange.201303025

Ionomer distribution control in porous carbon-supported catalyst layers for high-power and low Pt-loaded proton exchange membrane fuel cells
journal, September 2019


Boosting Fuel Cell Performance with Accessible Carbon Mesopores
journal, February 2018


Single Atomic Iron Catalysts for Oxygen Reduction in Acidic Media: Particle Size Control and Thermal Activation
journal, September 2017

  • Zhang, Hanguang; Hwang, Sooyeon; Wang, Maoyu
  • Journal of the American Chemical Society, Vol. 139, Issue 40
  • DOI: 10.1021/jacs.7b06514

Design of N-Coordinated Dual-Metal Sites: A Stable and Active Pt-Free Catalyst for Acidic Oxygen Reduction Reaction
journal, November 2017

  • Wang, Jing; Huang, Zhengqing; Liu, Wei
  • Journal of the American Chemical Society, Vol. 139, Issue 48
  • DOI: 10.1021/jacs.7b10385

Role of Local Carbon Structure Surrounding FeN 4 Sites in Boosting the Catalytic Activity for Oxygen Reduction
journal, May 2017

  • Liu, Kexi; Wu, Gang; Wang, Guofeng
  • The Journal of Physical Chemistry C, Vol. 121, Issue 21
  • DOI: 10.1021/acs.jpcc.7b00913

Atomically Dispersed Fe-N x /C Electrocatalyst Boosts Oxygen Catalysis via a New Metal-Organic Polymer Supramolecule Strategy
journal, July 2018

  • Miao, Zhengpei; Wang, Xiaoming; Tsai, Meng-Che
  • Advanced Energy Materials, Vol. 8, Issue 24
  • DOI: 10.1002/aenm.201801226

The Solid-Phase Synthesis of an Fe-N-C Electrocatalyst for High-Power Proton-Exchange Membrane Fuel Cells
journal, January 2018


Atomically dispersed metal–nitrogen–carbon catalysts for fuel cells: advances in catalyst design, electrode performance, and durability improvement
journal, January 2020

  • He, Yanghua; Liu, Shengwen; Priest, Cameron
  • Chemical Society Reviews, Vol. 49, Issue 11
  • DOI: 10.1039/C9CS00903E

Durability challenges and perspective in the development of PGM-free electrocatalysts for the oxygen reduction reaction
journal, June 2018


(Plenary) Electrochemical Diagnostics and Modeling in Developing the PEMFC Cathode
journal, August 2016

  • Kongkanand, A.; Yarlagadda, V.; Garrick, T. R.
  • ECS Transactions, Vol. 75, Issue 14
  • DOI: 10.1149/07514.0025ecst

Highly active atomically dispersed CoN 4 fuel cell cathode catalysts derived from surfactant-assisted MOFs: carbon-shell confinement strategy
journal, January 2019

  • He, Yanghua; Hwang, Sooyeon; Cullen, David A.
  • Energy & Environmental Science, Vol. 12, Issue 1
  • DOI: 10.1039/C8EE02694G

SiO 2 -protected shell mediated templating synthesis of Fe–N-doped carbon nanofibers and their enhanced oxygen reduction reaction performance
journal, January 2018

  • Hu, Bi-Cheng; Wu, Zhen-Yu; Chu, Sheng-Qi
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE00673C

In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
journal, June 2019


Thermally Driven Structure and Performance Evolution of Atomically Dispersed FeN 4 Sites for Oxygen Reduction
journal, November 2019

  • Li, Jiazhan; Zhang, Hanguang; Samarakoon, Widitha
  • Angewandte Chemie, Vol. 131, Issue 52
  • DOI: 10.1002/ange.201909312

The Solid-Phase Synthesis of an Fe-N-C Electrocatalyst for High-Power Proton-Exchange Membrane Fuel Cells
journal, January 2018

  • Liu, Qingtao; Liu, Xiaofang; Zheng, Lirong
  • Angewandte Chemie International Edition, Vol. 57, Issue 5
  • DOI: 10.1002/anie.201709597

Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells
journal, August 2011

  • Proietti, Eric; Jaouen, Frédéric; Lefèvre, Michel
  • Nature Communications, Vol. 2, Issue 1
  • DOI: 10.1038/ncomms1427

Engineering Local Coordination Environments of Atomically Dispersed and Heteroatom‐Coordinated Single Metal Site Electrocatalysts for Clean Energy‐Conversion
journal, November 2019

  • Zhu, Yuanzhi; Sokolowski, Joshua; Song, Xiancheng
  • Advanced Energy Materials, Vol. 10, Issue 11
  • DOI: 10.1002/aenm.201902844

Boosting Oxygen Reduction Catalysis with Fe–N 4 Sites Decorated Porous Carbons toward Fuel Cells
journal, January 2019


Nitrogen-Coordinated Single Cobalt Atom Catalysts for Oxygen Reduction in Proton Exchange Membrane Fuel Cells
journal, January 2018

  • Wang, Xiao Xia; Cullen, David A.; Pan, Yung-Tin
  • Advanced Materials, Vol. 30, Issue 11
  • DOI: 10.1002/adma.201706758

Is the rapid initial performance loss of Fe/N/C non precious metal catalysts due to micropore flooding?
journal, January 2017

  • Choi, Ja-Yeon; Yang, Lijun; Kishimoto, Takeaki
  • Energy & Environmental Science, Vol. 10, Issue 1
  • DOI: 10.1039/C6EE03005J

Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells
journal, April 2009

  • Lefèvre, Michel; Proietti, Eric; Jaouen, Frédéric
  • Science, Vol. 324, Issue 5923, p. 71-74
  • DOI: 10.1126/science.1170051

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017


Current progress of Pt and Pt-based electrocatalysts used for fuel cells
journal, January 2020

  • Ren, Xuefeng; Lv, Qianyuan; Liu, Lifen
  • Sustainable Energy & Fuels, Vol. 4, Issue 1
  • DOI: 10.1039/C9SE00460B