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Title: Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds

Abstract

A series of diphosphine-ligated rhodium( i ) alkoxo alkene complexes is reported and the migratory insertion of the alkene moiety into the rhodium–oxygen bond in these complexes was studied, revealing the effects of the ligand on the insertion process.

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry, University of California, United States and Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1664473
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science Journal Volume: 11 Journal Issue: 38; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Richers, Casseday P., Roediger, Sven, Laserna, Victor, and Hartwig, John F. Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds. United Kingdom: N. p., 2020. Web. doi:10.1039/D0SC04402D.
Richers, Casseday P., Roediger, Sven, Laserna, Victor, & Hartwig, John F. Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds. United Kingdom. doi:10.1039/D0SC04402D.
Richers, Casseday P., Roediger, Sven, Laserna, Victor, and Hartwig, John F. Wed . "Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds". United Kingdom. doi:10.1039/D0SC04402D.
@article{osti_1664473,
title = {Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds},
author = {Richers, Casseday P. and Roediger, Sven and Laserna, Victor and Hartwig, John F.},
abstractNote = {A series of diphosphine-ligated rhodium( i ) alkoxo alkene complexes is reported and the migratory insertion of the alkene moiety into the rhodium–oxygen bond in these complexes was studied, revealing the effects of the ligand on the insertion process.},
doi = {10.1039/D0SC04402D},
journal = {Chemical Science},
number = 38,
volume = 11,
place = {United Kingdom},
year = {2020},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1039/D0SC04402D

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