Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering

Sheets, Donal; Flynn, Vincent; Kim, Jungho; Upton, Mary; Casa, Diego; Gog, Thomas; Fisk, Zachary; Dzero, Maxim; Rosa, Priscila S.; Mazzone, Daniel G.; Jarrige, Ignace; Zhu, Jian-Xin; Hancock, Jason

doi:10.1088/1361-648x/ab5e0f

Title: Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering

Abstract

We present a study of resonant inelastic x-ray scattering (RIXS) spectra collected at the rare-earth L edges of divalent hexaborides YbB₆ and EuB₆. In both systems, RIXS-active features are observed at two distinct resonances separated by ~10 eV in incident energy, with angle-dependence suggestive of distinct photon scattering processes. RIXS spectra collected at the divalent absorption peak resemble the unoccupied 5d density of states calculated using density functional theory. We discuss possible origins of this correspondence including a scenario which changes the 4f valence. In addition, anomalous resonant scattering is observed at higher incident energy, where no corresponding absorption feature is present. Our results demonstrate the potential for L-edge RIXS to assess the itinerant-state properties of -electron materials.

Authors:

^[1]; Flynn, Vincent ^[2]; Kim, Jungho ^[3]; Upton, Mary ^[3]; Casa, Diego ^[3]; Gog, Thomas ^[3]; Fisk, Zachary ^[4]; Dzero, Maxim ^[5];

^[6]; Mazzone, Daniel G. ^[7]; Jarrige, Ignace ^[7]; Zhu, Jian-Xin ^[6];

^[1]

Univ. of Connecticut, Storrs, CT (United States)
Univ. of Connecticut, Storrs, CT (United States); Dartmouth College, Hanover, NH (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of California, Irvine, CA (United States)
Kent State Univ., Kent, OH (United States)
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)

Publication Date:: Mon Dec 30 00:00:00 EST 2019

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC). Basic Energy Sciences (BES); Swiss National Science Foundation (SNSF); National Science Foundation (NSF)

OSTI Identifier:: 1659181

Alternate Identifier(s):: OSTI ID: 1775520

Report Number(s):: LA-UR-19-23023
Journal ID: ISSN 0953-8984; TRN: US2203398

Grant/Contract Number:: 89233218CNA000001; SC0016481; AC02-06CH11357; NSF-DMR-1506547

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physics. Condensed Matter

Additional Journal Information:: Journal Volume: 32; Journal Issue: 13; Journal ID: ISSN 0953-8984

Publisher:: IOP Publishing

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; RIXS; correlated electron system; resonant inelastic x-ray scattering

Citation Formats


                    Sheets, Donal, Flynn, Vincent, Kim, Jungho, Upton, Mary, Casa, Diego, Gog, Thomas, Fisk, Zachary, Dzero, Maxim, Rosa, Priscila S., Mazzone, Daniel G., Jarrige, Ignace, Zhu, Jian-Xin, and Hancock, Jason. Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering.  United States: N. p., 2019. 
Web.  doi:10.1088/1361-648x/ab5e0f.

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                    Sheets, Donal, Flynn, Vincent, Kim, Jungho, Upton, Mary, Casa, Diego, Gog, Thomas, Fisk, Zachary, Dzero, Maxim, Rosa, Priscila S., Mazzone, Daniel G., Jarrige, Ignace, Zhu, Jian-Xin, & Hancock, Jason. Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering.  United States.  https://doi.org/10.1088/1361-648x/ab5e0f

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                    Sheets, Donal, Flynn, Vincent, Kim, Jungho, Upton, Mary, Casa, Diego, Gog, Thomas, Fisk, Zachary, Dzero, Maxim, Rosa, Priscila S., Mazzone, Daniel G., Jarrige, Ignace, Zhu, Jian-Xin, and Hancock, Jason. Mon .  
"Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering".  United States.  https://doi.org/10.1088/1361-648x/ab5e0f.  https://www.osti.gov/servlets/purl/1659181.

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@article{osti_1659181,

  title        = {Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering},

  author       = {Sheets, Donal and Flynn, Vincent and Kim, Jungho and Upton, Mary and Casa, Diego and Gog, Thomas and Fisk, Zachary and Dzero, Maxim and Rosa, Priscila S. and Mazzone, Daniel G. and Jarrige, Ignace and Zhu, Jian-Xin and Hancock, Jason},

  abstractNote = {We present a study of resonant inelastic x-ray scattering (RIXS) spectra collected at the rare-earth L edges of divalent hexaborides YbB6 and EuB6. In both systems, RIXS-active features are observed at two distinct resonances separated by ~10 eV in incident energy, with angle-dependence suggestive of distinct photon scattering processes. RIXS spectra collected at the divalent absorption peak resemble the unoccupied 5d density of states calculated using density functional theory. We discuss possible origins of this correspondence including a scenario which changes the 4f valence. In addition, anomalous resonant scattering is observed at higher incident energy, where no corresponding absorption feature is present. Our results demonstrate the potential for L-edge RIXS to assess the itinerant-state properties of -electron materials.},

  doi          = {10.1088/1361-648x/ab5e0f},

  journal      = {Journal of Physics. Condensed Matter},

  number       = 13,

  volume       = 32,

  place        = {United States},

  year         = {Mon Dec 30 00:00:00 EST 2019},

  month        = {Mon Dec 30 00:00:00 EST 2019}

}

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Title: Exploring itinerant states in divalent hexaborides using rare-earth L edge resonant inelastic x-ray scattering

Abstract

Citation Formats

Electrical transport properties and small polarons in Eu 1 − x Ca x B 6 journal, March 2003

Generalized Gradient Approximation Made Simple journal, October 1996

Lattice coupling and Franck–Condon effects in K-edge resonant inelastic x-ray scattering journal, March 2010

Experimental observation of incoherent-coherent crossover and orbital-dependent band renormalization in iron chalcogenide superconductors journal, December 2015

Pressure-induced quantum phase transitions in a Yb B 6 single crystal journal, December 2015

Unraveling the Nature of Charge Excitations in La 2 CuO 4 with Momentum-Resolved Cu K -Edge Resonant Inelastic X-Ray Scattering journal, October 2010

The simultaneous measurement of energy and linear polarization of the scattered radiation in resonant inelastic soft x-ray scattering journal, November 2014

Magnetic and transport properties of pure and carbon‐doped divalent RE hexaboride single crystals journal, January 1980

Comparative study of rare earth hexaborides using high resolution angle-resolved photoemission journal, April 2016

Electronic structure of rare-earth hexaborides journal, November 1992

MERIX—Next generation medium energy resolution inelastic X-ray scattering instrument at the APS journal, June 2013

Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering journal, June 2000

Polarization dependence and symmetry analysis in indirect K -edge RIXS journal, July 2010

Nesting-driven multipolar order in CeB6 from photoemission tomography journal, March 2016

Polarization-resolved Cu L 3 -edge resonant inelastic x-ray scattering of orbital and spin excitations in NdBa 2 Cu 3 O 7 − δ journal, April 2019

Electronic structures and properties of lanthanide hexaboride nanowires journal, October 2013

Resonant inelastic x-ray scattering studies of elementary excitations journal, June 2011

Magnetic, transport, and thermal properties of ferromagnetic EuB 6 journal, March 1979

Long-Range Incommensurate Charge Fluctuations in (Y,Nd)Ba2Cu3O6+x journal, July 2012

Single-crystal X-ray diffraction study of NdB6, EuB6 and YbB6 journal, January 1995

Non-Kondo-like Electronic Structure in the Correlated Rare-Earth Hexaboride Y b B 6 journal, January 2015

Intense paramagnon excitations in a large family of high-temperature superconductors journal, July 2011

Electronic transport in EuB 6 journal, March 2004

Kondo and anti-Kondo coupling to local moments in EuB 6 journal, April 2004

Lattice Strain Accompanying the Colossal Magnetoresistance Effect in EuB 6 journal, August 2014

Magnetic structures determined by neutron diffraction in the EuBϵ−xCx system journal, January 1981

Light scattering in solids journal, December 1976

Angle-resolved Photoemission Spectroscopy Study on the Surface States of the Correlated Topological Insulator YbB6 journal, August 2014

Structure and magnetic order of EuB 6 journal, March 1998

Density-functional theory and NiO photoemission spectra journal, December 1993

Topological Kondo Insulators journal, March 2016

Electronic Structure of YbB 6 : Is it a Topological Insulator or Not? journal, March 2016

Spin excitations in a single La2CuO4 layer journal, September 2012

Resonant inelastic x-ray scattering in electronically quasi-zero-dimensional CuB 2 O 4 journal, September 2009

Localized and delocalized Ti 3 d carriers in LaAlO 3 /SrTiO 3 superlattices revealed by resonant inelastic x-ray scattering journal, May 2011

Origin of the Anomalous Mass Renormalization in Metallic Quantum Well States of Strongly Correlated Oxide SrVO 3 journal, August 2015

Spin-split conduction band in EuB 6 and tuning of half-metallicity with external stimuli journal, April 2013

Electronic structure and superconductivity in metal hexaborides journal, February 1982

Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF 3 journal, June 2011

Resonant Inelastic X-Ray Scattering from Valence Excitations in Insulating Copper Oxides journal, July 1999

Kondo Interactions from Band Reconstruction in YbInCu 4 journal, March 2015

Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure journal, March 2013

Polarization dependence and symmetry analysis in indirect K-edge RIXS text, January 2010

Lattice coupling and Franck-Condon effects in K-edge resonant inelastic X-ray scattering text, January 2010

Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF3 text, January 2010

Intense paramagnon excitations in a large family of high-temperature superconductors text, January 2011

Long-range incommensurate charge fluctuations in (Y,Nd)Ba2Cu3O(6+x) text, January 2012

Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure text, January 2013

Angle-resolved Photoemission Spectroscopy Study on the Surface States of the Correlated Topological Insulator YbB6 text, January 2014

Non-Kondo-like Electronic Structure in the Correlated Rare-Earth Hexaboride YbB$_6$ text, January 2014

The simultaneous measurement of energy and linear polarization of the scattered radiation in resonant inelastic soft x-ray scattering text, January 2014

Experimental Observation of Incoherent-Coherent Crossover and Orbital Dependent Band Renormalization in Iron Chalcogenide Superconductors text, January 2015

Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering text, January 2001

Resonant Inelastic X-Ray Scattering from Valence Excitations in Insulating Copper-Oxides text, January 1998

Thermodynamic properties of the rare earth borides and carbides a wide temperature range journal, November 1993

Electrical transport properties and small polarons in ${Eu}_{1 - x} {Ca}_{x} B_{6}$
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Generalized Gradient Approximation Made Simple
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Lattice coupling and Franck–Condon effects in K-edge resonant inelastic x-ray scattering
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Experimental observation of incoherent-coherent crossover and orbital-dependent band renormalization in iron chalcogenide superconductors
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Pressure-induced quantum phase transitions in a $Yb B_{6}$ single crystal
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Unraveling the Nature of Charge Excitations in ${La}_{2} {CuO}_{4}$ with Momentum-Resolved Cu $K$ -Edge Resonant Inelastic X-Ray Scattering
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The simultaneous measurement of energy and linear polarization of the scattered radiation in resonant inelastic soft x-ray scattering
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Comparative study of rare earth hexaborides using high resolution angle-resolved photoemission
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Electronic structure of rare-earth hexaborides
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Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering
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Polarization dependence and symmetry analysis in indirect $K$ -edge RIXS
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Nesting-driven multipolar order in CeB6 from photoemission tomography
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Polarization-resolved Cu $L_{3}$ -edge resonant inelastic x-ray scattering of orbital and spin excitations in ${NdBa}_{2} {Cu}_{3} O_{7 - δ}$
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Electronic structures and properties of lanthanide hexaboride nanowires
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Resonant inelastic x-ray scattering studies of elementary excitations
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Magnetic, transport, and thermal properties of ferromagnetic EuB ₆
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Long-Range Incommensurate Charge Fluctuations in (Y,Nd)Ba2Cu3O6+x
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Single-crystal X-ray diffraction study of NdB6, EuB6 and YbB6
journal, January 1995

Non-Kondo-like Electronic Structure in the Correlated Rare-Earth Hexaboride ${Y b B}_{6}$
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Intense paramagnon excitations in a large family of high-temperature superconductors
journal, July 2011

Electronic transport in ${EuB}_{6}$
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Kondo and anti-Kondo coupling to local moments in ${EuB}_{6}$
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Lattice Strain Accompanying the Colossal Magnetoresistance Effect in ${EuB}_{6}$
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Magnetic structures determined by neutron diffraction in the EuBϵ−xCx system
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Light scattering in solids
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Angle-resolved Photoemission Spectroscopy Study on the Surface States of the Correlated Topological Insulator YbB6
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Structure and magnetic order of ${EuB}_{6}$
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Density-functional theory and NiO photoemission spectra
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Topological Kondo Insulators
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Electronic Structure of ${YbB}_{6}$ : Is it a Topological Insulator or Not?
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Spin excitations in a single La2CuO4 layer
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Resonant inelastic x-ray scattering in electronically quasi-zero-dimensional ${CuB}_{2} O_{4}$
journal, September 2009

Localized and delocalized Ti 3 $d$ carriers in LaAlO $_{3}$ /SrTiO $_{3}$ superlattices revealed by resonant inelastic x-ray scattering
journal, May 2011

Origin of the Anomalous Mass Renormalization in Metallic Quantum Well States of Strongly Correlated Oxide ${SrVO}_{3}$
journal, August 2015

Spin-split conduction band in EuB $_{6}$ and tuning of half-metallicity with external stimuli
journal, April 2013

Electronic structure and superconductivity in metal hexaborides
journal, February 1982

Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF $_{3}$
journal, June 2011

Resonant Inelastic X-Ray Scattering from Valence Excitations in Insulating Copper Oxides
journal, July 1999

Kondo Interactions from Band Reconstruction in ${YbInCu}_{4}$
journal, March 2015

Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure
journal, March 2013

Polarization dependence and symmetry analysis in indirect K-edge RIXS
text, January 2010

Lattice coupling and Franck-Condon effects in K-edge resonant inelastic X-ray scattering
text, January 2010

Polarization-analyzed resonant inelastic x-ray scattering of the orbital excitations in KCuF3
text, January 2010

Intense paramagnon excitations in a large family of high-temperature superconductors
text, January 2011

Long-range incommensurate charge fluctuations in (Y,Nd)Ba2Cu3O(6+x)
text, January 2012

Unified understanding of the valence transition in the rare-earth monochalcogenides under pressure
text, January 2013

Angle-resolved Photoemission Spectroscopy Study on the Surface States of the Correlated Topological Insulator YbB6
text, January 2014

Non-Kondo-like Electronic Structure in the Correlated Rare-Earth Hexaboride YbB$_6$
text, January 2014

The simultaneous measurement of energy and linear polarization of the scattered radiation in resonant inelastic soft x-ray scattering
text, January 2014

Experimental Observation of Incoherent-Coherent Crossover and Orbital Dependent Band Renormalization in Iron Chalcogenide Superconductors
text, January 2015

Electronic Structure of Mott Insulators Studied by Inelastic X-ray Scattering
text, January 2001

Resonant Inelastic X-Ray Scattering from Valence Excitations in Insulating Copper-Oxides
text, January 1998

Thermodynamic properties of the rare earth borides and carbides a wide temperature range
journal, November 1993