High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes
Abstract
It is well established that the miniaturization of batteries has not kept pace with the miniaturization of electronics. Three-dimensional (3D) batteries, which were developed with the intent of improving microbattery performance, have had limited success because of fabrication challenges and material constraints. Solid-state, 3D batteries have been particularly susceptible to these shortcomings. In this paper, we demonstrate that the incorporation of a high-conductivity, solid electrolyte is the key to achieving a nonplanar solid-state battery with high areal capacity and high power density. The model 2.5D platform used in this study is a modification of the more typical 3D configuration in that it is comprised of a cathode array of pillars (3D) and a planar (two-dimensional, 2D) anode. This 2.5D geometry exploits the use of a high-conductivity, ionogel electrolyte (10–3 S cm–1), which interpenetrates the 3D electrode array. The 2.5D battery offers high areal energy densities from the post array, while the high-conductivity, solid electrolyte enables high power densities (3.7 mWh cm–2 at 2.8 mW cm–2). The reported solid-state 2.5D device exceeds the energy and power densities of any 3D solid-state system and the derived multiphysics model provides guidance for achieving significantly higher energy and power densities.
- Authors:
-
[3];
[4];
[2]
- University of California, Los Angeles, CA (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- University of California, Los Angeles, CA (United States)
- Univ. of Utah, Salt Lake City, UT (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Univ. of Maryland, College Park, MD (United States); Univ. of California, Los Angeles, CA (United States); Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Biological and Environmental Research (BER). Earth and Environmental Systems Science Division; USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1658616
- Alternate Identifier(s):
- OSTI ID: 1643950; OSTI ID: 1660984; OSTI ID: 1668365
- Report Number(s):
- SAND-2020-5248J
Journal ID: ISSN 2574-0962
- Grant/Contract Number:
- SC0001160; NA0003525; AC04-94AL85000
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Energy Materials
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 9; Journal ID: ISSN 2574-0962
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 2.5D batteries; array electrodes; microbatteries; ionogels; 3D battery; solid-state electrolyte; Li-ion energy storage; microelectronic
Citation Formats
Ashby, David S., Choi, Christopher S., Edwards, Martin A., Talin, A. Alec, White, Henry S., and Dunn, Bruce S. High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes. United States: N. p., 2020.
Web. doi:10.1021/acsaem.0c01029.
Ashby, David S., Choi, Christopher S., Edwards, Martin A., Talin, A. Alec, White, Henry S., & Dunn, Bruce S. High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes. United States. https://doi.org/10.1021/acsaem.0c01029
Ashby, David S., Choi, Christopher S., Edwards, Martin A., Talin, A. Alec, White, Henry S., and Dunn, Bruce S. Tue .
"High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes". United States. https://doi.org/10.1021/acsaem.0c01029. https://www.osti.gov/servlets/purl/1658616.
@article{osti_1658616,
title = {High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes},
author = {Ashby, David S. and Choi, Christopher S. and Edwards, Martin A. and Talin, A. Alec and White, Henry S. and Dunn, Bruce S.},
abstractNote = {It is well established that the miniaturization of batteries has not kept pace with the miniaturization of electronics. Three-dimensional (3D) batteries, which were developed with the intent of improving microbattery performance, have had limited success because of fabrication challenges and material constraints. Solid-state, 3D batteries have been particularly susceptible to these shortcomings. In this paper, we demonstrate that the incorporation of a high-conductivity, solid electrolyte is the key to achieving a nonplanar solid-state battery with high areal capacity and high power density. The model 2.5D platform used in this study is a modification of the more typical 3D configuration in that it is comprised of a cathode array of pillars (3D) and a planar (two-dimensional, 2D) anode. This 2.5D geometry exploits the use of a high-conductivity, ionogel electrolyte (10–3 S cm–1), which interpenetrates the 3D electrode array. The 2.5D battery offers high areal energy densities from the post array, while the high-conductivity, solid electrolyte enables high power densities (3.7 mWh cm–2 at 2.8 mW cm–2). The reported solid-state 2.5D device exceeds the energy and power densities of any 3D solid-state system and the derived multiphysics model provides guidance for achieving significantly higher energy and power densities.},
doi = {10.1021/acsaem.0c01029},
journal = {ACS Applied Energy Materials},
number = 9,
volume = 3,
place = {United States},
year = {Tue Jul 21 00:00:00 EDT 2020},
month = {Tue Jul 21 00:00:00 EDT 2020}
}
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