Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO2
Abstract
In this Minireview, we discuss recent advances in understanding nanocluster and single-atom catalysts for CO and CO2 emissions control applications. Through analyzing thermocatalytic CO oxidation and CO2 reduction, two fundamentally and industrially important reactions, we compare representative nanocluster and single-atom catalytic systems from perspectives of intrinsic chemistry and reaction engineering. Generally, nanoclusters and single atoms display different catalytic performances (i.e., activity, selectivity, and stability) for these reactions depending on the synthesis methods, support materials, and reaction conditions. Key observations of activity and selectivity tradeoffs between nanoclusters and single-atom catalysts are highlighted. Here, the dynamic structural responses of these catalytic species under CO oxidation or CO2 reduction reaction conditions are also discussed. Synthetic control and detailed experimental and computational characterization of single-atom and nanocluster catalysts for CO and CO2 conversion have led to exciting progress over the past decade. Still, more efforts are needed to understand and develop catalysts that meet the environmental, energy, and technical requirements to power a sustainable global economy.
- Authors:
-
[1];
[3];
[1]
- University of Michigan, Ann Arbor, MI (United States)
- Tianjin University of Technology (China)
- General Motors Global Research and Development, Warren, MI (United States); Clemson University, SC (United States)
- Publication Date:
- Research Org.:
- Univ. of Michigan, Ann Arbor, MI (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Fusion Energy Sciences (FES)
- OSTI Identifier:
- 1658251
- Alternate Identifier(s):
- OSTI ID: 1647267
- Grant/Contract Number:
- SC0020232
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Catalysis Science and Technology
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 17; Journal ID: ISSN 2044-4753
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 03 NATURAL GAS; Heterogeneous catalysis
Citation Formats
Doherty, Francis, Wang, Hui, Yang, Ming, and Goldsmith, Bryan R. Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO2. United States: N. p., 2020.
Web. doi:10.1039/d0cy01316a.
Doherty, Francis, Wang, Hui, Yang, Ming, & Goldsmith, Bryan R. Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO2. United States. https://doi.org/10.1039/d0cy01316a
Doherty, Francis, Wang, Hui, Yang, Ming, and Goldsmith, Bryan R. Wed .
"Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO2". United States. https://doi.org/10.1039/d0cy01316a. https://www.osti.gov/servlets/purl/1658251.
@article{osti_1658251,
title = {Nanocluster and single-atom catalysts for thermocatalytic conversion of CO and CO2},
author = {Doherty, Francis and Wang, Hui and Yang, Ming and Goldsmith, Bryan R.},
abstractNote = {In this Minireview, we discuss recent advances in understanding nanocluster and single-atom catalysts for CO and CO2 emissions control applications. Through analyzing thermocatalytic CO oxidation and CO2 reduction, two fundamentally and industrially important reactions, we compare representative nanocluster and single-atom catalytic systems from perspectives of intrinsic chemistry and reaction engineering. Generally, nanoclusters and single atoms display different catalytic performances (i.e., activity, selectivity, and stability) for these reactions depending on the synthesis methods, support materials, and reaction conditions. Key observations of activity and selectivity tradeoffs between nanoclusters and single-atom catalysts are highlighted. Here, the dynamic structural responses of these catalytic species under CO oxidation or CO2 reduction reaction conditions are also discussed. Synthetic control and detailed experimental and computational characterization of single-atom and nanocluster catalysts for CO and CO2 conversion have led to exciting progress over the past decade. Still, more efforts are needed to understand and develop catalysts that meet the environmental, energy, and technical requirements to power a sustainable global economy.},
doi = {10.1039/d0cy01316a},
journal = {Catalysis Science and Technology},
number = 17,
volume = 10,
place = {United States},
year = {Wed Aug 05 00:00:00 EDT 2020},
month = {Wed Aug 05 00:00:00 EDT 2020}
}
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