Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film

Zhao, Yuming; Gao, Yue; Li, Guoxing; Wang, Daiwei; Huang, Qingquan; Wang, Donghai

doi:10.1021/acsenergylett.9b00539

Title: Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film

Abstract

The practical application of rechargeable lithium (Li) metal batteries has long been hindered by the unstable Li metal anode with problems like Li dendrite growth, low Coulombic efficiency (CE), and short cycle life. Here, we demonstrate a multifunctional sulfur-containing hybrid Li polysulfidophosphate and poly(2-chloroethyl acrylate) cross-linking film that can provide effective protection for Li metal anode. This film can facilitate Li metal anode generating a stable organic/inorganic hybrid solid electrolyte interphase (SEI) layer containing multiple components such as polymer-tethered organo(poly)sulfide, inorganic Li polysulfidophosphate, Li sulfides, and Li salts. Thanks to this hybrid robust SEI layer, dendrite-free Li deposition and stable cycling of Li metal anode can be achieved (e.g. CE >98.7% over 950 cycles). We demonstrated this Li protection technique enables both the protected Li metal anode and Li-metal-free anode cycling with significantly improved CEs and stability in full cells using LiFePO₄ (~2.4 mAh/cm²) cathode.

Authors:

Zhao, Yuming ^[1];

^[1];

^[1]; Wang, Daiwei ^[1]; Huang, Qingquan ^[1];

^[1]

Pennsylvania State Univ., University Park, PA (United States)

Publication Date:: Tue Apr 30 00:00:00 EDT 2019

Research Org.:: Pennsylvania State Univ., University Park, PA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1657237

Grant/Contract Number:: EE0007795

Resource Type:: Accepted Manuscript

Journal Name:: ACS Energy Letters

Additional Journal Information:: Journal Volume: 4; Journal Issue: 6; Journal ID: ISSN 2380-8195

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 42 ENGINEERING; lithium (Li) metal batteries; solid electrolyte interphase (SEI) layer; Polymer Crosslinking Film

Citation Formats


                    Zhao, Yuming, Gao, Yue, Li, Guoxing, Wang, Daiwei, Huang, Qingquan, and Wang, Donghai. Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film.  United States: N. p., 2019. 
Web.  doi:10.1021/acsenergylett.9b00539.

Copy to clipboard


                    Zhao, Yuming, Gao, Yue, Li, Guoxing, Wang, Daiwei, Huang, Qingquan, & Wang, Donghai. Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film.  United States.  https://doi.org/10.1021/acsenergylett.9b00539

Copy to clipboard


                    Zhao, Yuming, Gao, Yue, Li, Guoxing, Wang, Daiwei, Huang, Qingquan, and Wang, Donghai. Tue .  
"Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film".  United States.  https://doi.org/10.1021/acsenergylett.9b00539.  https://www.osti.gov/servlets/purl/1657237.

Copy to clipboard


                    
@article{osti_1657237,

  title        = {Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film},

  author       = {Zhao, Yuming and Gao, Yue and Li, Guoxing and Wang, Daiwei and Huang, Qingquan and Wang, Donghai},

  abstractNote = {The practical application of rechargeable lithium (Li) metal batteries has long been hindered by the unstable Li metal anode with problems like Li dendrite growth, low Coulombic efficiency (CE), and short cycle life. Here, we demonstrate a multifunctional sulfur-containing hybrid Li polysulfidophosphate and poly(2-chloroethyl acrylate) cross-linking film that can provide effective protection for Li metal anode. This film can facilitate Li metal anode generating a stable organic/inorganic hybrid solid electrolyte interphase (SEI) layer containing multiple components such as polymer-tethered organo(poly)sulfide, inorganic Li polysulfidophosphate, Li sulfides, and Li salts. Thanks to this hybrid robust SEI layer, dendrite-free Li deposition and stable cycling of Li metal anode can be achieved (e.g. CE >98.7% over 950 cycles). We demonstrated this Li protection technique enables both the protected Li metal anode and Li-metal-free anode cycling with significantly improved CEs and stability in full cells using LiFePO4 (~2.4 mAh/cm2) cathode.},

  doi          = {10.1021/acsenergylett.9b00539},

  journal      = {ACS Energy Letters},

  number       = 6,

  volume       = 4,

  place        = {United States},

  year         = {Tue Apr 30 00:00:00 EDT 2019},

  month        = {Tue Apr 30 00:00:00 EDT 2019}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acsenergylett.9b00539

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 84 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries
journal, June 2017

Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou
Advanced Materials, Vol. 29, Issue 29
DOI: 10.1002/adma.201700007

Review—Li Metal Anode in Working Lithium-Sulfur Batteries
journal, June 2017

Cheng, Xin-Bing; Huang, Jia-Qi; Zhang, Qiang
Journal of The Electrochemical Society, Vol. 165, Issue 1
DOI: 10.1149/2.0111801jes

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015

Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi
Advanced Science, Vol. 3, Issue 3
DOI: 10.1002/advs.201500213

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
journal, August 1998

Yamaki, Jun-ichi; Tobishima, Shin-ichi; Hayashi, Katsuya
Journal of Power Sources, Vol. 74, Issue 2
DOI: 10.1016/S0378-7753(98)00067-6

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model
journal, January 1979

Peled, E.
Journal of The Electrochemical Society, Vol. 126, Issue 12
DOI: 10.1149/1.2128859

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

Aurbach, D.
Solid State Ionics, Vol. 148, Issue 3-4
DOI: 10.1016/S0167-2738(02)00080-2

In situ analytical techniques for battery interface analysis
journal, January 2018

Tripathi, Alok M.; Su, Wei-Nien; Hwang, Bing Joe
Chemical Society Reviews, Vol. 47, Issue 3
DOI: 10.1039/C7CS00180K

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

Ding, Fei; Xu, Wu; Graff, Gordon L.
Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456
DOI: 10.1021/ja312241y

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives
journal, October 2018

Zhang, Heng; Eshetu, Gebrekidan Gebresilassie; Judez, Xabier
Angewandte Chemie International Edition, Vol. 57, Issue 46
DOI: 10.1002/anie.201712702

Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries
journal, May 2014

Gordin, Mikhail L.; Dai, Fang; Chen, Shuru
ACS Applied Materials & Interfaces, Vol. 6, Issue 11
DOI: 10.1021/am501665s

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes
journal, October 2016

Zhu, Bin; Jin, Yan; Hu, Xiaozhen
Advanced Materials, Vol. 29, Issue 2
DOI: 10.1002/adma.201603755

Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
journal, November 2016

Liu, Wei; Lin, Dingchang; Pei, Allen
Journal of the American Chemical Society, Vol. 138, Issue 47
DOI: 10.1021/jacs.6b08730

An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
journal, December 2015

Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng
Advanced Materials, Vol. 28, Issue 9
DOI: 10.1002/adma.201504526

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang
Advanced Functional Materials, Vol. 27, Issue 10
DOI: 10.1002/adfm.201605989

Passivation of Lithium Metal Anode via Hybrid Ionic Liquid Electrolyte toward Stable Li Plating/Stripping
journal, November 2016

Li, Nian-Wu; Yin, Ya-Xia; Li, Jin-Yi
Advanced Science, Vol. 4, Issue 2
DOI: 10.1002/advs.201600400

Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes
journal, October 2017

Adams, Brian D.; Carino, Emily V.; Connell, Justin G.
Nano Energy, Vol. 40
DOI: 10.1016/j.nanoen.2017.09.015

Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid
journal, July 2017

Yang, Chunpeng; Fu, Kun; Zhang, Ying
Advanced Materials, Vol. 29, Issue 36
DOI: 10.1002/adma.201701169

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng
Nature Nanotechnology, Vol. 9, Issue 8
DOI: 10.1038/nnano.2014.152

Li metal coated with amorphous Li3PO4 via magnetron sputtering for stable and long-cycle life lithium metal batteries
journal, February 2017

Wang, Liping; Wang, Qingji; Jia, Weishang
Journal of Power Sources, Vol. 342
DOI: 10.1016/j.jpowsour.2016.11.097

Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode
journal, September 2014

Yan, Kai; Lee, Hyun-Wook; Gao, Teng
Nano Letters, Vol. 14, Issue 10
DOI: 10.1021/nl503125u

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries
journal, October 2017

Gao, Yue; Zhao, Yuming; Li, Yuguang C.
Journal of the American Chemical Society, Vol. 139, Issue 43
DOI: 10.1021/jacs.7b06437

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries
journal, October 2017

Li, Guoxing; Gao, Yue; He, Xin
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/s41467-017-00974-x

Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Interface
journal, September 2018

Gao, Yue; Wang, Daiwei; Li, Yuguang C.
Angewandte Chemie International Edition, Vol. 57, Issue 41
DOI: 10.1002/anie.201807304

Effects of Polymer Coatings on Electrodeposited Lithium Metal
journal, August 2018

Lopez, Jeffrey; Pei, Allen; Oh, Jin Young
Journal of the American Chemical Society, Vol. 140, Issue 37
DOI: 10.1021/jacs.8b06047

A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery
journal, January 2018

Dong, Tiantian; Zhang, Jianjun; Xu, Gaojie
Energy & Environmental Science, Vol. 11, Issue 5
DOI: 10.1039/C7EE03365F

High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating
journal, November 2016

Zheng, Guangyuan; Wang, Chao; Pei, Allen
ACS Energy Letters, Vol. 1, Issue 6
DOI: 10.1021/acsenergylett.6b00456

A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes
journal, January 2018

Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia
Angewandte Chemie International Edition, Vol. 57, Issue 6
DOI: 10.1002/anie.201710806

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries
journal, January 2018

Li, Guoxing; Huang, Qingquan; He, Xin
ACS Nano, Vol. 12, Issue 2
DOI: 10.1021/acsnano.7b08035

Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries
journal, June 2012

Lin, Zhan; Liu, Zengcai; Fu, Wujun
Advanced Functional Materials, Vol. 23, Issue 8
DOI: 10.1002/adfm.201200696

Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries
journal, June 2013

Lin, Zhan; Liu, Zengcai; Fu, Wujun
Angewandte Chemie International Edition, Vol. 52, Issue 29
DOI: 10.1002/anie.201300680

The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015

Li, Weiyang; Yao, Hongbin; Yan, Kai
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms8436

Pre-modified Li3PS4 based interphase for lithium anode towards high-performance Li-S battery
journal, March 2018

Lu, Yang; Gu, Sui; Hong, Xiaoheng
Energy Storage Materials, Vol. 11
DOI: 10.1016/j.ensm.2017.09.007

Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte
journal, April 2017

Wu, Xiaohan; El Kazzi, Mario; Villevieille, Claire
Journal of Electroceramics, Vol. 38, Issue 2-4
DOI: 10.1007/s10832-017-0084-z

Functional Organosulfide Electrolyte Promotes an Alternate Reaction Pathway to Achieve High Performance in Lithium-Sulfur Batteries
journal, February 2016

Chen, Shuru; Dai, Fang; Gordin, Mikhail L.
Angewandte Chemie International Edition, Vol. 55, Issue 13
DOI: 10.1002/anie.201511830

Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries
journal, February 2016

Li, Guoxing; Sun, Jinhua; Hou, Wenpeng
Nature Communications, Vol. 7, Issue 1
DOI: 10.1038/ncomms10601

Fabrication of Ordered Nanopattern by using ABC Triblock Copolymer with Salt in Toluene
journal, August 2017

Huang, Hailiang; Zhong, Benbin; Zu, Xihong
Nanoscale Research Letters, Vol. 12, Issue 1
DOI: 10.1186/s11671-017-2260-0

Li 2 S 5 -based ternary-salt electrolyte for robust lithium metal anode
journal, April 2016

Zhao, Chen-Zi; Cheng, Xin-Bing; Zhang, Rui
Energy Storage Materials, Vol. 3
DOI: 10.1016/j.ensm.2016.01.007

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries
journal, January 2009

Aurbach, Doron; Pollak, Elad; Elazari, Ran
Journal of The Electrochemical Society, Vol. 156, Issue 8, p. A694-A702
DOI: 10.1149/1.3148721

Stabilizing high sulfur loading Li–S batteries by chemisorption of polysulfide on three-dimensional current collector
journal, December 2016

Wang, Xiwen; Gao, Tao; Han, Fudong
Nano Energy, Vol. 30
DOI: 10.1016/j.nanoen.2016.10.049

Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF ₆ , LiBF ₄ , LiDFOB, LiBOB, and LiTFSI
journal, January 2018

Parimalam, Bharathy S.; Lucht, Brett L.
Journal of The Electrochemical Society, Vol. 165, Issue 2
DOI: 10.1149/2.0901802jes

Works referencing / citing this record:

Porosity‐ and Graphitization‐Controlled Fabrication of Nanoporous Silicon@Carbon for Lithium Storage and Its Conjugation with MXene for Lithium‐Metal Anode
journal, December 2019

An, Yongling; Tian, Yuan; Wei, Hao
Advanced Functional Materials, Vol. 30, Issue 9
DOI: 10.1002/adfm.201908721

Stable lithium metal anodes enabled by inorganic/organic double-layered alloy and polymer coating
journal, January 2019

Zhang, Yuanjun; Wang, Guanyao; Tang, Liang
Journal of Materials Chemistry A, Vol. 7, Issue 44
DOI: 10.1039/c9ta09523c

Similar Records in DOE PAGES and OSTI.GOV collections:

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries

Journal Article Li, Guoxing ; Huang, Qingquan ; He, Xin ; ... - ACS Nano

Lithium–sulfur (Li–S) batteries are promising candidates for high-energy storage devices due to high theoretical capacities of both the sulfur cathode and lithium (Li) metal anode. Considerable efforts have been devoted to improving sulfur cathodes. However, issues associated with Li anodes, such as low Coulombic efficiency (CE) and growth of Li dendrites, remain unsolved due to unstable solid-electrolyte interphase (SEI) and lead to poor capacity retention and a short cycling life of Li–S batteries. In this paper, we demonstrate a facile and effective approach to fabricate a flexible and robust hybrid SEI layer through co-deposition of aromatic-based organosulfides and inorganic Limore »« less
Cited by 115
https://doi.org/10.1021/acsnano.7b08035

Full Text Available
In Situ Formation of Polycyclic Aromatic Hydrocarbons as an Artificial Hybrid Layer for Lithium Metal Anodes

Journal Article Chang, Shaozhong ; Jin, Xin ; He, Qiya ; ... - Nano Letters

Nonuniform Li deposition causes dendrites and low Coulombic efficiency (CE), seriously hindering the practical applications of Li metal. Herein, we developed an artificial solid-state interphase (SEI) with planar polycyclic aromatic hydrocarbons (PAHs) on the surface of Li metal anodes by a facile in situ formation technology. The resultant dihydroxyviolanthron (DHV) layers serve as the protective layer to stabilize the SEI. In addition, the oxygen-containing functional groups in the soft and conformal SEI film can regulate the diffusion and transport of Li ions to homogenize the deposition of Li metal. The artificial SEI significantly improves the CEs and shows superior cyclabilitymore »« less
https://doi.org/10.1021/acs.nanolett.1c03624

Full Text Available
Stable Li metal anode by a polyvinyl alcohol protection layer via modifying solid-electrolyte interphase layer

Journal Article Zhao, Yuming ; Wang, Daiwei ; Gao, Yue ; ... - Nano Energy

Lithium (Li) metal is considered an ideal anode for next-generation high energy Li metal batteries (LMBs) due to its high theoretical specific capacity and low electrochemical potential. However, stable cycling of LMBs has long been restrained by the extremely unstable interfaces between the Li metal anode and liquid electrolyte. In this work, we found that low-cost polyvinyl alcohol (PVA) polymer can be applied as an effective protection layer for Li metal anodes in both ether- and carbonate-based electrolytes. The PVA protection layer will participate in and facilitate formation of a superior PVA-modified solid electrolyte interphase (SEI) layer on Li metal,more »« less
https://doi.org/10.1016/j.nanoen.2019.103893

Full Text Available
Electrolyte design for Li metal-free Li batteries

Journal Article Chen, Ji ; Li, Qin ; Pollard, Travis P. ; ... - Materials Today

Li metal, with the lowest thermodynamically achievable negative electrochemical potential and the highest specific capacity (3860 mAh g^-1), is the ultimate anode choice for Li batteries. However, the highest reported Li plating/stripping Coulombic efficiency (CE) of 99.5% after extensive efforts is still too low for the Li metal-free (all the Li metal in cycling comes from cathode, without anode pre-lithiation) Li metal batteries. The low CE is attributed to both non-uniform Li plating/stripping on the lithiophobic Cu current collector and Li dendrite growth through lithiophilic organic–inorganic solid electrolyte interphase (SEI) formed in carbonate electrolytes. Here, we use a lithiophilic Bismuthmore »« less
https://doi.org/10.1016/j.mattod.2020.04.004

Full Text Available
Uniform High Ionic Conducting Lithium Sulfide Protection Layer for Stable Lithium Metal Anode

Journal Article Chen, Hao ; Pei, Allen ; Lin, Dingchang ; ... - Advanced Energy Materials

Abstract Artificial solid‐electrolyte interphase (SEI) is one of the key approaches in addressing the low reversibility and dendritic growth problems of lithium metal anode, yet its current effect is still insufficient due to insufficient stability. Here, a new principle of “simultaneous high ionic conductivity and homogeneity” is proposed for stabilizing SEI and lithium metal anodes. Fabricated by a facile, environmentally friendly, and low‐cost lithium solid‐sulfur vapor reaction at elevated temperature, a designed lithium sulfide protective layer successfully maintains its protection function during cycling, which is confirmed by both simulations and experiments. Stable dendrite‐free cycling of lithium metal anode is realizedmore »« less
Cited by 272
https://doi.org/10.1002/aenm.201900858

Full Text Available

Similar Records

Title: Stable Li Metal Anode by a Hybrid Lithium Polysulfidophosphate/Polymer Crosslinking Film

Abstract

Citation Formats

Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries journal, June 2017

Review—Li Metal Anode in Working Lithium-Sulfur Batteries journal, June 2017

A Review of Solid Electrolyte Interphases on Lithium Metal Anode journal, November 2015

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte journal, August 1998

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model journal, January 1979

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions journal, June 2002

In situ analytical techniques for battery interface analysis journal, January 2018

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism journal, March 2013

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives journal, October 2018

Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries journal, May 2014

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes journal, October 2016

Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement journal, November 2016

An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes journal, December 2015

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries journal, January 2017

Passivation of Lithium Metal Anode via Hybrid Ionic Liquid Electrolyte toward Stable Li Plating/Stripping journal, November 2016

Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes journal, October 2017

Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid journal, July 2017

Interconnected hollow carbon nanospheres for stable lithium metal anodes journal, July 2014

Li metal coated with amorphous Li3PO4 via magnetron sputtering for stable and long-cycle life lithium metal batteries journal, February 2017

Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode journal, September 2014

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries journal, October 2017

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries journal, October 2017

Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li 10 GeP 2 S 12 Solid Electrolyte Interface journal, September 2018

Effects of Polymer Coatings on Electrodeposited Lithium Metal journal, August 2018

A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery journal, January 2018

High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating journal, November 2016

A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes journal, January 2018

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries journal, January 2018

Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries journal, June 2012

Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries journal, June 2013

The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth journal, June 2015

Pre-modified Li3PS4 based interphase for lithium anode towards high-performance Li-S battery journal, March 2018

Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte journal, April 2017

Functional Organosulfide Electrolyte Promotes an Alternate Reaction Pathway to Achieve High Performance in Lithium-Sulfur Batteries journal, February 2016

Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries journal, February 2016

Fabrication of Ordered Nanopattern by using ABC Triblock Copolymer with Salt in Toluene journal, August 2017

Li 2 S 5 -based ternary-salt electrolyte for robust lithium metal anode journal, April 2016

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries journal, January 2009

Stabilizing high sulfur loading Li–S batteries by chemisorption of polysulfide on three-dimensional current collector journal, December 2016

Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF 6 , LiBF 4 , LiDFOB, LiBOB, and LiTFSI journal, January 2018

Porosity‐ and Graphitization‐Controlled Fabrication of Nanoporous Silicon@Carbon for Lithium Storage and Its Conjugation with MXene for Lithium‐Metal Anode journal, December 2019

Stable lithium metal anodes enabled by inorganic/organic double-layered alloy and polymer coating journal, January 2019

Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries
journal, June 2017

Review—Li Metal Anode in Working Lithium-Sulfur Batteries
journal, June 2017

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015

A consideration of the morphology of electrochemically deposited lithium in an organic electrolyte
journal, August 1998

The Electrochemical Behavior of Alkali and Alkaline Earth Metals in Nonaqueous Battery Systems—The Solid Electrolyte Interphase Model
journal, January 1979

A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions
journal, June 2002

In situ analytical techniques for battery interface analysis
journal, January 2018

Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism
journal, March 2013

Electrolyte Additives for Lithium Metal Anodes and Rechargeable Lithium Metal Batteries: Progress and Perspectives
journal, October 2018

Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium–Sulfur Batteries
journal, May 2014

Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes
journal, October 2016

Stabilizing Lithium Metal Anodes by Uniform Li-Ion Flux Distribution in Nanochannel Confinement
journal, November 2016

An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes
journal, December 2015

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries
journal, January 2017

Passivation of Lithium Metal Anode via Hybrid Ionic Liquid Electrolyte toward Stable Li Plating/Stripping
journal, November 2016

Long term stability of Li-S batteries using high concentration lithium nitrate electrolytes
journal, October 2017

Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid
journal, July 2017

Interconnected hollow carbon nanospheres for stable lithium metal anodes
journal, July 2014

Li metal coated with amorphous Li3PO4 via magnetron sputtering for stable and long-cycle life lithium metal batteries
journal, February 2017

Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode
journal, September 2014

Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries
journal, October 2017

Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries
journal, October 2017

Salt-Based Organic-Inorganic Nanocomposites: Towards A Stable Lithium Metal/Li ₁₀ GeP ₂ S ₁₂ Solid Electrolyte Interface
journal, September 2018

Effects of Polymer Coatings on Electrodeposited Lithium Metal
journal, August 2018

A multifunctional polymer electrolyte enables ultra-long cycle-life in a high-voltage lithium metal battery
journal, January 2018

High-Performance Lithium Metal Negative Electrode with a Soft and Flowable Polymer Coating
journal, November 2016

A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes
journal, January 2018

Self-Formed Hybrid Interphase Layer on Lithium Metal for High-Performance Lithium–Sulfur Batteries
journal, January 2018

Phosphorous Pentasulfide as a Novel Additive for High-Performance Lithium-Sulfur Batteries
journal, June 2012

Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries
journal, June 2013

The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth
journal, June 2015

Pre-modified Li3PS4 based interphase for lithium anode towards high-performance Li-S battery
journal, March 2018

Surface and morphological investigation of the electrode/electrolyte properties in an all-solid-state battery using a Li2S-P2S5 solid electrolyte
journal, April 2017

Functional Organosulfide Electrolyte Promotes an Alternate Reaction Pathway to Achieve High Performance in Lithium-Sulfur Batteries
journal, February 2016

Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries
journal, February 2016

Fabrication of Ordered Nanopattern by using ABC Triblock Copolymer with Salt in Toluene
journal, August 2017

Li 2 S 5 -based ternary-salt electrolyte for robust lithium metal anode
journal, April 2016

On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li–Sulfur Batteries
journal, January 2009

Stabilizing high sulfur loading Li–S batteries by chemisorption of polysulfide on three-dimensional current collector
journal, December 2016

Reduction Reactions of Electrolyte Salts for Lithium Ion Batteries: LiPF ₆ , LiBF ₄ , LiDFOB, LiBOB, and LiTFSI
journal, January 2018

Porosity‐ and Graphitization‐Controlled Fabrication of Nanoporous Silicon@Carbon for Lithium Storage and Its Conjugation with MXene for Lithium‐Metal Anode
journal, December 2019

Stable lithium metal anodes enabled by inorganic/organic double-layered alloy and polymer coating
journal, January 2019