DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Deuterium retention in advanced steels for fusion reactor structural application

Journal Article · · Journal of Nuclear Materials

Reduced activation ferritic-martensitic (RAFM) steels, castable nanostructured alloys (CNA), and oxide-dispersion-strengthened (ODS) steels have been developed for the fusion reactor structural application with improved mechanical properties and radiation resistance. However, the hydrogen isotope retention in these steels is not well understood. In this study, 10 keV D2 implantation was performed on six steels, together with pure iron and T91 as references, at room temperature. Subsequent thermal desorption spectroscopy (TDS) measurements were carried out to investigate the deuterium retention. Possible deuterium trapping sites in the studied materials were discussed in coordination with available microstructural information. The results of this study indicated that ODS-steels have the largest deuterium retention, which is almost one order of magnitude higher than that of pure iron, ~6 times of RAFM, and 2–4 times of CNA steels. The difference in nanoparticles and grain/lath boundaries are primarily responsible for the different deuterium retention, while other trapping sites (e.g., vacancy clusters, dislocations, etc.) are present. Deuterium retention increases with increasing sink strength of the studied materials, although they are not linear correlated.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Fusion Energy Sciences (FES)
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1651420
Journal Information:
Journal of Nuclear Materials, Journal Name: Journal of Nuclear Materials Journal Issue: N/A Vol. 516; ISSN 0022-3115
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (27)

The interaction of hydrogen with dislocation in iron journal October 1984
Theory and experimental background on dimensional changes in irradiated alloys journal October 1994
Trapping of hydrogen by substitutional and interstitial impurities in α-iron journal August 1983
Thermal resolution of desorption energy spectra journal September 1962
Stability of MX-type strengthening nanoprecipitates in ferritic steels under thermal aging, stress and ion irradiation journal June 2014
The interaction of dislocations and hydrogen-vacancy complexes and its importance for deformation-induced proto nano-voids formation in α-Fe journal November 2015
New insights into the structure of ODS particles in the ODS-Eurofer alloy journal April 2009
Neutron-induced dpa, transmutations, gas production, and helium embrittlement of fusion materials journal November 2013
Hydrogen effects on tensile properties of EUROFER 97 and ODS-EUROFER steels journal January 2014
Investigation of microstructure changes in ODS-EUROFER after hydrogen loading journal January 2016
Development of new generation reduced activation ferritic-martensitic steels for advanced fusion reactors journal September 2016
Helium sequestration at nanoparticle-matrix interfaces in helium + heavy ion irradiated nanostructured ferritic alloys journal January 2017
Impact of neutron irradiation on thermal helium desorption from iron journal June 2017
Development of castable nanostructured alloys as a new generation RAFM steels journal December 2018
Microstructure and property tailoring of castable nanostructured alloys through thermomechanical treatments journal October 2018
SRIM – The stopping and range of ions in matter (2010)
  • Ziegler, James F.; Ziegler, M. D.; Biersack, J. P.
  • Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 268, Issue 11-12 https://doi.org/10.1016/j.nimb.2010.02.091
journal June 2010
Multiscale modelling of defect kinetics in irradiated iron journal December 2004
Theory of hydrogen solubility in binary iron alloys based on ab initio calculation results journal June 2012
Hydrogen–vacancy interaction in bcc iron: ab initio calculations and thermodynamics journal November 2013
Energetics of small hydrogen–vacancy clusters in bcc iron journal October 2011
Hydrogen–vacancy–dislocation interactions in α -Fe journal December 2016
Interplay between hydrogen and vacancies in α -Fe journal May 2013
Designing Radiation Resistance in Materials for Fusion Energy journal July 2014
Hydrogen trapping in ferritic steel weld metal journal August 2002
Grain-Boundary Diffusion of Hydrogen Atoms in the $\alpha$-Iron [Grain-Boundary Diffusion of Hydrogen Atoms in the $\alpha$-Iron] journal September 2016
Hydrogen–Grain Boundary Interaction in Fe, Fe–C, and Fe–N Systems journal January 2011
Thermal Helium Desorption Spectrometry (THDS) as a Tool for the Study of Vacancies and Self-Interstitials journal January 1987