Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals

Saiz, C. L.; McGuire, M. A.; Hennadige, S. J.; van Tol, J.; Singamaneni, S. R.

doi:10.1557/adv.2019.241

Title: Electron Spin Resonance Properties of CrI₃ and CrCl₃ Single Crystals

Abstract

Developing functional, cleavable two-dimensional materials for use in next generation devices has recently become a topic of considerable interest due to their unique properties. Of particular interest, transition metal halides CrI₃ and CrCl₃ have shown to be good contenders for tunable and cleavable magnetic materials due to their unique magnetic properties in the monolayer. In this work, electron spin resonance spectroscopy is used to pinpoint the atomic origins and underlying mechanisms of magnetic interactions as a function of temperature (5-500 K) and microwave frequency (9.43, 120 GHz) on CrI₃ and CrCl₃ bulk single crystals. Furthermore, ESR signals from CrI₃ due to Cr³⁺ were observed to decay at 460 K, while ESR signals from CrCl₃ remain up to 500 K. In the case of CrCl₃, the temperature dependences of signal behavior, line width and g-value show characteristic signatures of ferromagnetic fluctuations at around 40 K, near to the antiferromagnetic phase transition at 17 K.

Authors:

^[1];

^[1]; Hennadige, S. J. ^[2]; van Tol, J. ^[3]; Singamaneni, S. R. ^[1]

Univ. of Texas at El Paso, TX (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)

Publication Date:: Tue May 21 00:00:00 EDT 2019

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); University of Texas at El Paso (UTEP), Nuclear Regulatory Commission

OSTI Identifier:: 1651252

Grant/Contract Number:: AC05-00OR22725; 31310018M0019

Resource Type:: Accepted Manuscript

Journal Name:: MRS Advances

Additional Journal Information:: Journal Volume: 4; Journal Issue: 40; Journal ID: ISSN 2059-8521

Publisher:: Materials Research Society (MRS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Saiz, C. L., McGuire, M. A., Hennadige, S. J., van Tol, J., and Singamaneni, S. R. Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals.  United States: N. p., 2019. 
Web.  doi:10.1557/adv.2019.241.

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                    Saiz, C. L., McGuire, M. A., Hennadige, S. J., van Tol, J., & Singamaneni, S. R. Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals.  United States.  https://doi.org/10.1557/adv.2019.241

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                    Saiz, C. L., McGuire, M. A., Hennadige, S. J., van Tol, J., and Singamaneni, S. R. Tue .  
"Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals".  United States.  https://doi.org/10.1557/adv.2019.241.  https://www.osti.gov/servlets/purl/1651252.

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@article{osti_1651252,

  title        = {Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals},

  author       = {Saiz, C. L. and McGuire, M. A. and Hennadige, S. J. and van Tol, J. and Singamaneni, S. R.},

  abstractNote = {Developing functional, cleavable two-dimensional materials for use in next generation devices has recently become a topic of considerable interest due to their unique properties. Of particular interest, transition metal halides CrI3 and CrCl3 have shown to be good contenders for tunable and cleavable magnetic materials due to their unique magnetic properties in the monolayer. In this work, electron spin resonance spectroscopy is used to pinpoint the atomic origins and underlying mechanisms of magnetic interactions as a function of temperature (5-500 K) and microwave frequency (9.43, 120 GHz) on CrI3 and CrCl3 bulk single crystals. Furthermore, ESR signals from CrI3 due to Cr3+ were observed to decay at 460 K, while ESR signals from CrCl3 remain up to 500 K. In the case of CrCl3, the temperature dependences of signal behavior, line width and g-value show characteristic signatures of ferromagnetic fluctuations at around 40 K, near to the antiferromagnetic phase transition at 17 K.},

  doi          = {10.1557/adv.2019.241},

  journal      = {MRS Advances},

  number       = 40,

  volume       = 4,

  place        = {United States},

  year         = {Tue May 21 00:00:00 EDT 2019},

  month        = {Tue May 21 00:00:00 EDT 2019}

}

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Title: Electron Spin Resonance Properties of CrI3 and CrCl3 Single Crystals

Abstract

Citation Formats

Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling journal, May 2018

Disorder-induced phase coexistence in bulk doped manganites and its suppression in nanometer-sized crystals: The case of La 0.9 Ca 0.1 Mn O 3 journal, December 2007

Magnetization, magnetotransport and electron magnetic resonance studies of nanoparticles and nanowires of Pr 0.5 Sr 0.5 MnO 3 journal, March 2009

Magnetization, Resonance, and Optical Properties of the Ferromagnet CrI 3 journal, March 1965

Two-dimensional ESR behaviour of CrCl3 journal, September 1991

Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals journal, April 2017

Electron magnetic resonance studies of magnetic inhomogeneities in crystalline and nanosized powders of La[sub 1−x]Sr[sub x]MnO[sub 3] journal, January 2002

Magnetic Ordering in CrCl3 at the Phase Transition journal, July 1982

Discovery of Intrinsic Ferromagnetism in Two-Dimensional van der Waals Crystals conference, January 2017

Magnetic anisotropy in the ferromagnetic insulating state of La 1 − x Ca x Mn O 3 journal, June 2006

Temperature dependence of the ESR linewidth in the paramagnetic phase (T> T C ) of R 1 − x B x MnO 3 + δ (R=La,Pr; B=Ca,Sr) journal, February 1997

Magnetic, electron magnetic resonance and optical studies of Pr 0.7 Pb 0.3 MnO 3 nanoparticles journal, July 2008

Van der Waals engineering of ferromagnetic semiconductor heterostructures for spin and valleytronics journal, May 2017

Giant tunneling magnetoresistance in spin-filter van der Waals heterostructures journal, May 2018

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Neutron diffraction investigation of antiferromagnetism in CrCl3 journal, April 1961

Very large tunneling magnetoresistance in layered magnetic semiconductor CrI3 journal, June 2018

Robust intrinsic ferromagnetism and half semiconductivity in stable two-dimensional single-layer chromium trihalides journal, January 2015

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EPR line broadening and magnetic phase transitions in antiferromagnetic Fe P 3 O 9 journal, September 1975

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Title: Electron Spin Resonance Properties of CrI₃ and CrCl₃ Single Crystals

Probing magnetism in 2D van der Waals crystalline insulators via electron tunneling
journal, May 2018

Disorder-induced phase coexistence in bulk doped manganites and its suppression in nanometer-sized crystals: The case of ${La}_{0.9} {Ca}_{0.1} Mn O_{3}$
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journal, March 1965

Two-dimensional ESR behaviour of CrCl3
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Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals
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Electron magnetic resonance studies of magnetic inhomogeneities in crystalline and nanosized powders of La[sub 1−x]Sr[sub x]MnO[sub 3]
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Temperature dependence of the ESR linewidth in the paramagnetic phase (T> $T_{C}$ ) of $R_{1 - x}$ $B_{x}$ ${MnO}_{3 + δ}$ (R=La,Pr; B=Ca,Sr)
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On the analysis of broad Dysonian electron paramagnetic resonance spectra
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