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Title: Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution

Abstract

A novel, rational design for porous S-vacancy nickel sulfide catalysts with remarkable catalytic performance for alkaline HER.

Authors:
 [1];  [2];  [1];  [1];  [1]; ORCiD logo [1];  [1]; ORCiD logo [3];  [2]
  1. School of Material Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China
  2. Department of Physics and Astronomy, University of California, Irvine, USA
  3. School of Material Science and Engineering, Hebei University of Technology, Tianjin 300130, P. R. China, Department of Physics and Astronomy
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1650693
Grant/Contract Number:  
SC0012704
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 35; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Jia, Dongbo, Han, Lili, Li, Ying, He, Wenjun, Liu, Caichi, Zhang, Jun, Chen, Cong, Liu, Hui, and Xin, Huolin L. Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0TA05594H.
Jia, Dongbo, Han, Lili, Li, Ying, He, Wenjun, Liu, Caichi, Zhang, Jun, Chen, Cong, Liu, Hui, & Xin, Huolin L. Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution. United Kingdom. https://doi.org/10.1039/D0TA05594H
Jia, Dongbo, Han, Lili, Li, Ying, He, Wenjun, Liu, Caichi, Zhang, Jun, Chen, Cong, Liu, Hui, and Xin, Huolin L. Tue . "Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution". United Kingdom. https://doi.org/10.1039/D0TA05594H.
@article{osti_1650693,
title = {Optimizing electron density of nickel sulfide electrocatalysts through sulfur vacancy engineering for alkaline hydrogen evolution},
author = {Jia, Dongbo and Han, Lili and Li, Ying and He, Wenjun and Liu, Caichi and Zhang, Jun and Chen, Cong and Liu, Hui and Xin, Huolin L.},
abstractNote = {A novel, rational design for porous S-vacancy nickel sulfide catalysts with remarkable catalytic performance for alkaline HER.},
doi = {10.1039/D0TA05594H},
journal = {Journal of Materials Chemistry. A},
number = 35,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {9}
}

Journal Article:
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Works referenced in this record:

Electron density modulation of NiCo2S4 nanowires by nitrogen incorporation for highly efficient hydrogen evolution catalysis
journal, April 2018


P-Doped Iron–Nickel Sulfide Nanosheet Arrays for Highly Efficient Overall Water Splitting
journal, July 2019

  • Liu, Caichi; Jia, Dongbo; Hao, Qiuyan
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 31
  • DOI: 10.1021/acsami.9b04528

Activating and optimizing MoS2 basal planes for hydrogen evolution through the formation of strained sulphur vacancies
journal, November 2015

  • Li, Hong; Tsai, Charlie; Koh, Ai Leen
  • Nature Materials, Vol. 15, Issue 1
  • DOI: 10.1038/nmat4465

Ternary NiCo 2 P x Nanowires as pH-Universal Electrocatalysts for Highly Efficient Hydrogen Evolution Reaction
journal, December 2016


Plasma-Engraved Co 3 O 4 Nanosheets with Oxygen Vacancies and High Surface Area for the Oxygen Evolution Reaction
journal, March 2016

  • Xu, Lei; Jiang, Qianqian; Xiao, Zhaohui
  • Angewandte Chemie International Edition, Vol. 55, Issue 17
  • DOI: 10.1002/anie.201600687

Projector augmented-wave method
journal, December 1994


Theoretical and Experimental Insight into the Effect of Nitrogen Doping on Hydrogen Evolution Activity of Ni 3 S 2 in Alkaline Medium
journal, March 2018


From the Sabatier principle to a predictive theory of transition-metal heterogeneous catalysis
journal, August 2015


Tailoring the facets of Ni 3 S 2 as a bifunctional electrocatalyst for high-performance overall water-splitting
journal, January 2019

  • Li, Lingjie; Sun, Caiyun; Shang, Bo
  • Journal of Materials Chemistry A, Vol. 7, Issue 30
  • DOI: 10.1039/C9TA05578A

Electronic factors determining the reactivity of metal surfaces
journal, December 1995


Nickel sulfides for electrocatalytic hydrogen evolution under alkaline conditions: a case study of crystalline NiS, NiS 2 , and Ni 3 S 2 nanoparticles
journal, January 2016

  • Jiang, Nan; Tang, Qing; Sheng, Meili
  • Catalysis Science & Technology, Vol. 6, Issue 4
  • DOI: 10.1039/C5CY01111F

Nickel Vacancies Boost Reconstruction in Nickel Hydroxide Electrocatalyst
journal, May 2018


Selenium vacancy-rich CoSe 2 ultrathin nanomeshes with abundant active sites for electrocatalytic oxygen evolution
journal, January 2019

  • Zhang, Yixin; Zhang, Chao; Guo, Yamei
  • Journal of Materials Chemistry A, Vol. 7, Issue 6
  • DOI: 10.1039/C8TA11407B

Single‐Atom Ru Doping Induced Phase Transition of MoS 2 and S Vacancy for Hydrogen Evolution Reaction
journal, August 2019


Engineering Ni2P-NiSe2 heterostructure interface for highly efficient alkaline hydrogen evolution
journal, March 2020


Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
journal, October 2019


Ni3S2 nanorods/Ni foam composite electrode with low overpotential for electrocatalytic oxygen evolution
journal, January 2013

  • Zhou, Weijia; Wu, Xue-Jun; Cao, Xiehong
  • Energy & Environmental Science, Vol. 6, Issue 10
  • DOI: 10.1039/c3ee41572d

Effects of d -band shape on the surface reactivity of transition-metal alloys
journal, March 2014


Best Practices for Reporting Electrocatalytic Performance of Nanomaterials
journal, September 2018


Trends in the Exchange Current for Hydrogen Evolution
journal, January 2005

  • Nørskov, J. K.; Bligaard, T.; Logadottir, A.
  • Journal of The Electrochemical Society, Vol. 152, Issue 3
  • DOI: 10.1149/1.1856988

Noble metal-free hydrogen evolution catalysts for water splitting
journal, January 2015

  • Zou, Xiaoxin; Zhang, Yu
  • Chemical Society Reviews, Vol. 44, Issue 15
  • DOI: 10.1039/C4CS00448E

Atomic Arrangement in Metal‐Doped NiS 2 Boosts the Hydrogen Evolution Reaction in Alkaline Media
journal, November 2019

  • Yin, Jie; Jin, Jing; Zhang, Hong
  • Angewandte Chemie International Edition, Vol. 58, Issue 51
  • DOI: 10.1002/anie.201911470

Doping-induced structural phase transition in cobalt diselenide enables enhanced hydrogen evolution catalysis
journal, June 2018


Nobel Prize in chemistry 1912 to Sabatier: Organic chemistry or catalysis?
journal, December 2013


The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts
journal, May 2018

  • Zheng, Yao; Jiao, Yan; Vasileff, Anthony
  • Angewandte Chemie International Edition, Vol. 57, Issue 26
  • DOI: 10.1002/anie.201710556

Fluorine-Anion-Modulated Electron Structure of Nickel Sulfide Nanosheet Arrays for Alkaline Hydrogen Evolution
journal, October 2019


Nickel-Based (Photo)Electrocatalysts for Hydrogen Production
journal, January 2018


Molecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution
journal, August 2015

  • Liang, Hai-Wei; Brüller, Sebastian; Dong, Renhao
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8992

Facile synthesis of Co and Ce dual-doped Ni3S2 nanosheets on Ni foam for enhanced oxygen evolution reaction
journal, May 2020


Defect Chemistry of Nonprecious-Metal Electrocatalysts for Oxygen Reactions
journal, May 2017


Identifying the electrocatalytic sites of nickel disulfide in alkaline hydrogen evolution reaction
journal, November 2017


Contributions of Phase, Sulfur Vacancies, and Edges to the Hydrogen Evolution Reaction Catalytic Activity of Porous Molybdenum Disulfide Nanosheets
journal, June 2016

  • Yin, Ying; Han, Jiecai; Zhang, Yumin
  • Journal of the American Chemical Society, Vol. 138, Issue 25
  • DOI: 10.1021/jacs.6b03714

Why gold is the noblest of all the metals
journal, July 1995


Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
journal, January 2015

  • Jiao, Yan; Zheng, Yao; Jaroniec, Mietek
  • Chemical Society Reviews, Vol. 44, Issue 8
  • DOI: 10.1039/C4CS00470A

Nickel-Based Electrocatalysts for Energy-Related Applications: Oxygen Reduction, Oxygen Evolution, and Hydrogen Evolution Reactions
journal, September 2017


Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces
journal, December 2011


Unconventional Nickel Nitride Enriched with Nitrogen Vacancies as a High-Efficiency Electrocatalyst for Hydrogen Evolution
journal, June 2018


Recent Advances on Water‐Splitting Electrocatalysis Mediated by Noble‐Metal‐Based Nanostructured Materials
journal, November 2019

  • Li, Yingjie; Sun, Yingjun; Qin, Yingnan
  • Advanced Energy Materials, Vol. 10, Issue 11
  • DOI: 10.1002/aenm.201903120

(003)-Facet-exposed Ni3S2 nanoporous thin films on nickel foil for efficient water splitting
journal, April 2019


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Role of Hyper-Reduced States in Hydrogen Evolution Reaction at Sulfur Vacancy in MoS 2
journal, April 2018


Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994


Recent progress made in the mechanism comprehension and design of electrocatalysts for alkaline water splitting
journal, January 2019

  • Hu, Congling; Zhang, Lei; Gong, Jinlong
  • Energy & Environmental Science, Vol. 12, Issue 9
  • DOI: 10.1039/C9EE01202H

Engineering oxygen vacancy on NiO nanorod arrays for alkaline hydrogen evolution
journal, January 2018


Single-Atom Vacancy Defect to Trigger High-Efficiency Hydrogen Evolution of MoS 2
journal, January 2020

  • Wang, Xin; Zhang, Yuwei; Si, Haonan
  • Journal of the American Chemical Society, Vol. 142, Issue 9
  • DOI: 10.1021/jacs.9b12113

3D Nitrogen-Anion-Decorated Nickel Sulfides for Highly Efficient Overall Water Splitting
journal, June 2017

  • Chen, Pengzuo; Zhou, Tianpei; Zhang, Mengxing
  • Advanced Materials, Vol. 29, Issue 30
  • DOI: 10.1002/adma.201701584

The Role of Defect Sites in Nanomaterials for Electrocatalytic Energy Conversion
journal, June 2019


A Realizable Renewable Energy Future
journal, July 1999


Hierarchical Nanoassembly of MoS 2 /Co 9 S 8 /Ni 3 S 2 /Ni as a Highly Efficient Electrocatalyst for Overall Water Splitting in a Wide pH Range
journal, May 2019

  • Yang, Yan; Yao, Huiqin; Yu, Zihuan
  • Journal of the American Chemical Society, Vol. 141, Issue 26
  • DOI: 10.1021/jacs.9b04492

Promoting Oxygen Evolution Reactions through Introduction of Oxygen Vacancies to Benchmark NiFe–OOH Catalysts
journal, May 2018


Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution
journal, April 2017

  • Tsai, Charlie; Li, Hong; Park, Sangwook
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15113

Tuning Mixed Nickel Iron Phosphosulfide Nanosheet Electrocatalysts for Enhanced Hydrogen and Oxygen Evolution
journal, November 2017


A Nitrogen Doping Method for CoS 2 Electrocatalysts with Enhanced Water Oxidation Performance
journal, May 2017


Layered Double Hydroxide Nanosheets with Multiple Vacancies Obtained by Dry Exfoliation as Highly Efficient Oxygen Evolution Electrocatalysts
journal, April 2017

  • Wang, Yanyong; Zhang, Yiqiong; Liu, Zhijuan
  • Angewandte Chemie International Edition, Vol. 56, Issue 21
  • DOI: 10.1002/anie.201701477

First-row transition metal dichalcogenide catalysts for hydrogen evolution reaction
journal, January 2013

  • Kong, Desheng; Cha, Judy J.; Wang, Haotian
  • Energy & Environmental Science, Vol. 6, Issue 12
  • DOI: 10.1039/c3ee42413h

Promoting Formation of Oxygen Vacancies in Two-Dimensional Cobalt-Doped Ceria Nanosheets for Efficient Hydrogen Evolution
journal, March 2020

  • Jiang, Shuaihu; Zhang, Ruya; Liu, Hongxian
  • Journal of the American Chemical Society, Vol. 142, Issue 14
  • DOI: 10.1021/jacs.9b13915

Efficient Hydrogen Evolution on Cu Nanodots-Decorated Ni 3 S 2 Nanotubes by Optimizing Atomic Hydrogen Adsorption and Desorption
journal, January 2018

  • Feng, Jin-Xian; Wu, Jin-Qi; Tong, Ye-Xiang
  • Journal of the American Chemical Society, Vol. 140, Issue 2
  • DOI: 10.1021/jacs.7b08521

Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017


Fundamental Concepts in Heterogeneous Catalysis. By Jens K. Nørskov, Felix Studt, Frank Abild-Pedersen and Thomas Bligaard.
journal, July 2015


Enhanced Catalysis of Electrochemical Overall Water Splitting in Alkaline Media by Fe Doping in Ni 3 S 2 Nanosheet Arrays
journal, May 2018


Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
journal, June 2013

  • Popczun, Eric J.; McKone, James R.; Read, Carlos G.
  • Journal of the American Chemical Society, Vol. 135, Issue 25
  • DOI: 10.1021/ja403440e

Low Overpotential in Vacancy-Rich Ultrathin CoSe 2 Nanosheets for Water Oxidation
journal, October 2014

  • Liu, Youwen; Cheng, Hao; Lyu, Mengjie
  • Journal of the American Chemical Society, Vol. 136, Issue 44
  • DOI: 10.1021/ja5085157