skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on August 12, 2021

Title: Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction

Abstract

Ordered intermetallic PtCo synthesized from N-doped graphitic carbon-containing Co presents the high durability with low Pt loading after 30 000 load-simulated cycles in proton exchange membrane fuel cells.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [3];  [4]
  1. Department of Chemical Engineering, Hankyong National University, Anseong-si, Republic of Korea
  2. Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Seoul, Republic of Korea
  3. Clean Energy Research Center, Korea Institute of Science and Technology (KIST), Seoul, Republic of Korea, Division of Energy and Environmental Technology
  4. Center for Electrochemical Engineering, Department of Chemical Engineering, University of South Carolina, Columbia, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1650215
Grant/Contract Number:  
EE0000460
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 38; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Jung, Won Suk, Lee, Woong Hee, Oh, Hyung-Suk, and Popov, Branko N. Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction. United Kingdom: N. p., 2020. Web. https://doi.org/10.1039/D0TA05182A.
Jung, Won Suk, Lee, Woong Hee, Oh, Hyung-Suk, & Popov, Branko N. Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction. United Kingdom. https://doi.org/10.1039/D0TA05182A
Jung, Won Suk, Lee, Woong Hee, Oh, Hyung-Suk, and Popov, Branko N. Tue . "Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction". United Kingdom. https://doi.org/10.1039/D0TA05182A.
@article{osti_1650215,
title = {Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction},
author = {Jung, Won Suk and Lee, Woong Hee and Oh, Hyung-Suk and Popov, Branko N.},
abstractNote = {Ordered intermetallic PtCo synthesized from N-doped graphitic carbon-containing Co presents the high durability with low Pt loading after 30 000 load-simulated cycles in proton exchange membrane fuel cells.},
doi = {10.1039/D0TA05182A},
journal = {Journal of Materials Chemistry. A},
number = 38,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on August 12, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Acetylene black derived hollow carbon nanostructure and its application in lithium–sulfur batteries
journal, January 2013

  • Tang, Jingjing; Yang, Juan; Zhou, Xiangyang
  • RSC Advances, Vol. 3, Issue 38
  • DOI: 10.1039/c3ra42835d

Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts
journal, October 2012

  • Wang, Deli; Xin, Huolin L.; Hovden, Robert
  • Nature Materials, Vol. 12, Issue 1, p. 81-87
  • DOI: 10.1038/nmat3458

EPR Evidence for Co(IV) Species Produced During Water Oxidation at Neutral pH
journal, May 2010

  • McAlpin, J. Gregory; Surendranath, Yogesh; Dincǎ, Mircea
  • Journal of the American Chemical Society, Vol. 132, Issue 20
  • DOI: 10.1021/ja1013344

An XPS study on binary and ternary alloys of transition metals with platinized carbon and its bearing upon oxygen electroreduction in direct methanol fuel cells
journal, May 2001


Changing the Activity of Electrocatalysts for Oxygen Reduction by Tuning the Surface Electronic Structure
journal, April 2006

  • Stamenkovic, Vojislav; Mun, Bongjin Simon; Mayrhofer, Karl J. J.
  • Angewandte Chemie International Edition, Vol. 45, Issue 18
  • DOI: 10.1002/anie.200504386

Highly Active and Durable Co-Doped Pt/CCC Cathode Catalyst for Polymer Electrolyte Membrane Fuel Cells
journal, June 2015


PEM Fuel Cell Durability With Transportation Transient Operation
journal, October 2006

  • Borup, Rod; Davey, John; Garzon, Fernando
  • ECS Transactions, Vol. 3, Issue 1
  • DOI: 10.1149/1.2356206

Comparison between Dealloyed PtCo 3 and PtCu 3 Cathode Catalysts for Proton Exchange Membrane Fuel Cells
journal, September 2012

  • Yu, Zhiqiang; Zhang, Junliang; Liu, Zhongyi
  • The Journal of Physical Chemistry C, Vol. 116, Issue 37
  • DOI: 10.1021/jp306107t

Influence of Sulfur on the Pyrolysis of CoTMPP as Electrocatalyst for the Oxygen Reduction Reaction
journal, January 2009

  • Herrmann, I.; Kramm, U. I.; Radnik, J.
  • Journal of The Electrochemical Society, Vol. 156, Issue 10, p. B1283-B1292
  • DOI: 10.1149/1.3185852

Investigation of Migrated Platinum Distributions in PEMFC Under Excess H2/O2
journal, August 2009

  • Kim, L.; Chung, Chul Goo; Sung, Young Wook
  • ECS Transactions, Vol. 16, Issue 2
  • DOI: 10.1149/1.2981934

Particle size and alloying effects of Pt-based alloy catalysts for fuel cell applications
journal, August 2000


A Facile Strategy to Pt 3 Ni Nanocrystals with Highly Porous Features as an Enhanced Oxygen Reduction Reaction Catalyst
journal, April 2013


Platinum–Cobalt alloy networks for methanol oxidation electrocatalysis
journal, January 2012

  • Xu, Jiangfeng; Liu, Xinyu; Chen, Yu
  • Journal of Materials Chemistry, Vol. 22, Issue 44
  • DOI: 10.1039/c2jm35649j

Recent advances in activity and durability enhancement of Pt/C catalytic cathode in PEMFC
journal, October 2007


A comparative study of PtCo, PtCr, and PtCoCr catalysts for oxygen electro-reduction reaction
journal, July 2010


Effect of Voltage on Platinum Dissolution
journal, January 2006

  • Wang, Xiaoping; Kumar, Romesh; Myers, Deborah J.
  • Electrochemical and Solid-State Letters, Vol. 9, Issue 5
  • DOI: 10.1149/1.2180536

One-Pot Synthesis of Pt–Pd Bimetallic Nanodendrites with Enhanced Electrocatalytic Activity for Oxygen Reduction Reaction
journal, March 2019


Structure-Activity-Stability Relationships of Pt−Co Alloy Electrocatalysts in Gas-Diffusion Electrode Layers
journal, February 2007

  • Koh, Shirlaine; Leisch, Jennifer; Toney, Michael F.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 9
  • DOI: 10.1021/jp067269a

Low-Temperature Chemical Vapor Deposition Synthesis of Pt-Co Alloyed Nanoparticles with Enhanced Oxygen Reduction Reaction Catalysis
journal, June 2016

  • Choi, Dong Sung; Robertson, Alex W.; Warner, Jamie H.
  • Advanced Materials, Vol. 28, Issue 33
  • DOI: 10.1002/adma.201600469

Nitrogen Doping Effects on Carbon Nanotubes and the Origin of the Enhanced Electrocatalytic Activity of Supported Pt for Proton-Exchange Membrane Fuel Cells
journal, February 2011

  • Chen, Yougui; Wang, Jiajun; Liu, Hao
  • The Journal of Physical Chemistry C, Vol. 115, Issue 9
  • DOI: 10.1021/jp108864y

Controlled synthesis of highly multi-branched Pt-based alloy nanocrystals with high catalytic performance
journal, January 2016

  • Kim, Yena; Kwon, Yongmin; Hong, Jong Wook
  • CrystEngComm, Vol. 18, Issue 13
  • DOI: 10.1039/C6CE00235H

Role of Electronic Property of Pt and Pt Alloys on Electrocatalytic Reduction of Oxygen
journal, January 1998

  • Toda, Takako
  • Journal of The Electrochemical Society, Vol. 145, Issue 12
  • DOI: 10.1149/1.1838934

Synthesis–structure–performance correlation for polyaniline–Me–C non-precious metal cathode catalysts for oxygen reduction in fuel cells
journal, January 2011

  • Wu, Gang; Johnston, Christina M.; Mack, Nathan H.
  • Journal of Materials Chemistry, Vol. 21, Issue 30
  • DOI: 10.1039/c0jm03613g

Nitrogen-Doped Carbon Nanotubes as Platinum Catalyst Supports for Oxygen Reduction Reaction in Proton Exchange Membrane Fuel Cells
journal, November 2010

  • Higgins, Drew C.; Meza, Doralice; Chen, Zhongwei
  • The Journal of Physical Chemistry C, Vol. 114, Issue 50
  • DOI: 10.1021/jp106814j

Importance of Interatomic Spacing in Catalytic Reduction of Oxygen in Phosphoric Acid
journal, January 1983

  • Jalan, V.
  • Journal of The Electrochemical Society, Vol. 130, Issue 11
  • DOI: 10.1149/1.2119574

Enhancement of the Electroreduction of Oxygen on Pt Alloys with Fe, Ni, and Co
journal, January 1999

  • Toda, Takako; Igarashi, Hiroshi; Uchida, Hiroyuki
  • Journal of The Electrochemical Society, Vol. 146, Issue 10, p. 3750-3756
  • DOI: 10.1149/1.1392544

Improving PEM fuel cell catalyst activity and durability using nitrogen-doped carbon supports: observations from model Pt/HOPG systems
journal, January 2009

  • Zhou, Yingke; Pasquarelli, Robert; Holme, Timothy
  • Journal of Materials Chemistry, Vol. 19, Issue 42
  • DOI: 10.1039/b910924b

Dissolution and Migration of Platinum in PEMFCs Investigated for Start/Stop Cycling and High Potential Degradation
journal, February 2011


Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007

  • Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
  • Science, Vol. 315, Issue 5811, p. 493-497
  • DOI: 10.1126/science.1135941

Consumption Rate of Pt under Potential Cycling
journal, January 2007

  • Mitsushima, Shigenori; Kawahara, Shuya; Ota, Ken-ichiro
  • Journal of The Electrochemical Society, Vol. 154, Issue 2
  • DOI: 10.1149/1.2400596

Polyaniline. Preparation of a conducting polymer(IUPAC Technical Report)
journal, January 2002


Raman spectroscopic evaluation of polyacrylonitrile-based carbon nanofibers prepared by electrospinning
journal, January 2004

  • Kim, Chan; Park, Sang-Hee; Cho, Jang-Ik
  • Journal of Raman Spectroscopy, Vol. 35, Issue 11
  • DOI: 10.1002/jrs.1233

Solvothermal Synthesis of Platinum Alloy Nanoparticles for Oxygen Reduction Electrocatalysis
journal, May 2012

  • Carpenter, Michael K.; Moylan, Thomas E.; Kukreja, Ratandeep Singh
  • Journal of the American Chemical Society, Vol. 134, Issue 20
  • DOI: 10.1021/ja300756y

Magnetic anisotropy of L 1 0 FePt and Fe 1 x Mn x Pt
journal, April 2005


Oxygen reduction reaction (ORR) activity and durability of carbon supported PtM (Co, Ni, Cu) alloys: Influence of particle size and non-noble metals
journal, January 2012

  • Jayasayee, Kaushik; Veen, J. A. Rob Van; Manivasagam, Thirugnasambandam G.
  • Applied Catalysis B: Environmental, Vol. 111-112
  • DOI: 10.1016/j.apcatb.2011.11.003

Towards a comprehensive understanding of platinum dissolution in acidic media
journal, January 2014

  • Topalov, Angel A.; Cherevko, Serhiy; Zeradjanin, Aleksandar R.
  • Chem. Sci., Vol. 5, Issue 2
  • DOI: 10.1039/C3SC52411F

Record activity and stability of dealloyed bimetallic catalysts for proton exchange membrane fuel cells
journal, January 2015

  • Han, Binghong; Carlton, Christopher E.; Kongkanand, Anusorn
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE02144D

Oxygen reduction reaction on electrodeposited PtAu alloy catalysts in the presence of phosphoric acid
journal, April 2015


Activity and durability of Pt-Ni nanocage electocatalysts in proton exchange membrane fuel cells
journal, April 2017


Structurally Ordered FePt Nanoparticles and Their Enhanced Catalysis for Oxygen Reduction Reaction
journal, April 2010

  • Kim, Jaemin; Lee, Youngmin; Sun, Shouheng
  • Journal of the American Chemical Society, Vol. 132, Issue 14
  • DOI: 10.1021/ja1009629

Synthesis of PtCu3 bimetallic nanoparticles as oxygen reduction catalysts via a sonochemical method
journal, January 2013

  • Gümeci, Cenk; Cearnaigh, D. Ua; Casadonte, Dominick J.
  • Journal of Materials Chemistry A, Vol. 1, Issue 6
  • DOI: 10.1039/c2ta00957a

Gram-scale synthesis of highly active and durable octahedral PtNi nanoparticle catalysts for proton exchange membrane fuel cell
journal, June 2018


Influence of Nitrogen Doping on Oxygen Reduction Electrocatalysis at Carbon Nanofiber Electrodes
journal, March 2005

  • Maldonado, Stephen; Stevenson, Keith J.
  • The Journal of Physical Chemistry B, Vol. 109, Issue 10, p. 4707-4716
  • DOI: 10.1021/jp044442z

Surface Composition Effects in Electrocatalysis:  Kinetics of Oxygen Reduction on Well-Defined Pt 3 Ni and Pt 3 Co Alloy Surfaces
journal, November 2002

  • Stamenković, V.; Schmidt, T. J.; Ross, P. N.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 46
  • DOI: 10.1021/jp021182h

Development of Highly Active and Durable Hybrid Cathode Catalysts for Polymer Electrolyte Membrane Fuel Cells
journal, January 2014

  • Xie, Tianyuan; Jung, Wonsuk; Kim, Taekeun
  • Journal of The Electrochemical Society, Vol. 161, Issue 14
  • DOI: 10.1149/2.0961414jes

Heat-Treated Carbon-Blacks as Supports for Platinum Catalysts
journal, July 1995

  • Coloma, F.; Sepulvedaescribano, A.; Rodriguezreinoso, F.
  • Journal of Catalysis, Vol. 154, Issue 2
  • DOI: 10.1006/jcat.1995.1171

Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
journal, February 2007

  • Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias
  • Nature Materials, Vol. 6, Issue 3, p. 241-247
  • DOI: 10.1038/nmat1840

Pt Nanoparticles Supported on Nitrogen-Doped Porous Carbon Nanospheres as an Electrocatalyst for Fuel Cells †
journal, February 2010

  • Su, Fabing; Tian, Zhiqun; Poh, Chee Kok
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm901542w

Enhanced electrocatalysis of oxygen reduction on platinum alloys in proton exchange membrane fuel cells
journal, October 1993

  • Mukerjee, Sanjeev; Srinivasan, Supramaniam
  • Journal of Electroanalytical Chemistry, Vol. 357, Issue 1-2, p. 201-224
  • DOI: 10.1016/0022-0728(93)80380-Z

Study of the effect of temperature on Pt dissolution in polymer electrolyte membrane fuel cells via accelerated stress tests
journal, January 2014


Nitrogen-doped carbon nanostructures and their composites as catalytic materials for proton exchange membrane fuel cell
journal, February 2008


The role of nanostructure in nitrogen-containing carbon catalysts for the oxygen reduction reaction
journal, April 2006


An XPS study on oxidation states of Pt and its alloys with Co and Cr and its relevance to electroreduction of oxygen
journal, March 2001


One-Pot Synthesis of Pt-Co Alloy Nanowire Assemblies with Tunable Composition and Enhanced Electrocatalytic Properties
journal, January 2015

  • Xia, Bao Yu; Wu, Hao Bin; Li, Nan
  • Angewandte Chemie International Edition, Vol. 54, Issue 12
  • DOI: 10.1002/anie.201411544

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

  • Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S.
  • Nature Chemistry, Vol. 1, Issue 7, p. 552-556
  • DOI: 10.1038/nchem.367