A review of the interactions between ceria and H2 and the applications to selective hydrogenation of alkynes

Kammert, James; Moon, Jisue; Wu, Zili

doi:10.1016/s1872-2067(19)63509-6

Title: A review of the interactions between ceria and H2 and the applications to selective hydrogenation of alkynes

Journal Article · 29 January 2020 · Chinese Journal of Catalysis

DOI: https://doi.org/10.1016/s1872-2067(19)63509-6 · OSTI ID:1649383

Kammert, James ^[1]; Moon, Jisue ^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Cerium oxide (ceria) has found a wide variety of applications in catalysis including as a catalyst, a modifier, or a support, largely thanks to its robust redox properties and versatile acid-base function. While it is often utilized for oxidation reactions, ceria has recently attracted intense research interest for its unusual ability to selectively hydrogenate alkynes to alkenes. The intriguing hydrogenation ability of ceria has sparked renewed research efforts to understand how pure ceria works as a hydrogenation catalyst. In this review, recent advances in both experimental and computational studies of ceria are summarized, focusing on the interaction of ceria with H₂ and in hydrogenation reactions. Significant insights from various studies including in situ spectroscopy/microscopy and theoretic modeling of ceria in hydrogen-involved reactions are discussed, which shed light on the origin of the hydrogenation ability of ceria and the reaction mechanisms involved in ceria-catalyzed alkyne hydrogenation. Ways to further improve both the mechanistic understanding and catalytic performance of ceria-based materials for hydrogenation reactions are proposed at the end in the summary and outlook section.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1649383

Journal Information:: Chinese Journal of Catalysis, Journal Name: Chinese Journal of Catalysis Journal Issue: 6 Vol. 41; ISSN 1872-2067

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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An FTIR study of surface ceria hydroxy groups during a redox process with H2 Badri, Ahmed; Binet, Claude; Lavalley, Jean-Claude Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 23 https://doi.org/10.1039/ft9969204669	journal	January 1996
Behaviour of ceria under hydrogen treatment: thermogravimetry and in situ X-ray diffraction study Lamonier, C.; Wrobel, G.; Bonnelle, J. P. Journal of Materials Chemistry, Vol. 4, Issue 12 https://doi.org/10.1039/jm9940401927	journal	January 1994
Hydrogen activation, diffusion, and clustering on CeO ₂ (111): A DFT+ U study Fernández-Torre, Delia; Carrasco, Javier; Ganduglia-Pirovano, M. Verónica The Journal of Chemical Physics, Vol. 141, Issue 1 https://doi.org/10.1063/1.4885546	journal	July 2014
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996

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