Controllable solute-diffusion gel-growth of BCHT: an effective approach towards large functional material single crystal synthesis
Abstract
An underutilized, but highly advantageous, method of growing functional-single-crystals, the gel-growth technique, is highlighted. Large nonlinear optical crystals, BCHT, were grown and their dehydration phase-transformation to β-BTC were studied.
- Authors:
-
- Department of Nuclear Engineering, North Carolina State University, Raleigh, USA
- Publication Date:
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1648163
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- CrystEngComm
- Additional Journal Information:
- Journal Name: CrystEngComm Journal Volume: 22 Journal Issue: 36; Journal ID: ISSN 1466-8033
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Hany, Ibrahim, Kanies, Bryant, and Yang, Ge. Controllable solute-diffusion gel-growth of BCHT: an effective approach towards large functional material single crystal synthesis. United Kingdom: N. p., 2020.
Web. doi:10.1039/D0CE00800A.
Hany, Ibrahim, Kanies, Bryant, & Yang, Ge. Controllable solute-diffusion gel-growth of BCHT: an effective approach towards large functional material single crystal synthesis. United Kingdom. https://doi.org/10.1039/D0CE00800A
Hany, Ibrahim, Kanies, Bryant, and Yang, Ge. Mon .
"Controllable solute-diffusion gel-growth of BCHT: an effective approach towards large functional material single crystal synthesis". United Kingdom. https://doi.org/10.1039/D0CE00800A.
@article{osti_1648163,
title = {Controllable solute-diffusion gel-growth of BCHT: an effective approach towards large functional material single crystal synthesis},
author = {Hany, Ibrahim and Kanies, Bryant and Yang, Ge},
abstractNote = {An underutilized, but highly advantageous, method of growing functional-single-crystals, the gel-growth technique, is highlighted. Large nonlinear optical crystals, BCHT, were grown and their dehydration phase-transformation to β-BTC were studied.},
doi = {10.1039/D0CE00800A},
journal = {CrystEngComm},
number = 36,
volume = 22,
place = {United Kingdom},
year = {2020},
month = {9}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/D0CE00800A
https://doi.org/10.1039/D0CE00800A
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Crystal Growth in Gels from the Mechanisms of Crystal Growth to Control of Polymorphism: New Trends on Theoretical and Experimental Aspects
journal, August 2019
- Velásquez-González, Omar; Campos-Escamilla, Camila; Flores-Ibarra, Andrea
- Crystals, Vol. 9, Issue 9
Anion-switchable supramolecular gels for controlling pharmaceutical crystal growth
journal, October 2010
- Foster, Jonathan A.; Piepenbrock, Marc-Oliver M.; Lloyd, Gareth O.
- Nature Chemistry, Vol. 2, Issue 12
Single crystal growth by gel technique and characterization of lithium hydrogen tartrate
journal, February 2015
- Ahmad, Nazir; Ahmad, M. M.; Kotru, P. N.
- Journal of Crystal Growth, Vol. 412
Study of optimum growth condition and characterization of zinc mercury thiocyanate (ZMTC) single crystals in silica gel
journal, December 2007
- Santha Kumari, P. Nisha; Kalainathan, S.; Nambi Raj, N. Arunai
- Materials Research Bulletin, Vol. 42, Issue 12
Crystal structure, vibrational, and optical investigations of semiorganic nonlinear optical crystal: Bi 3 [CS(NH 2 ) 2 ] 9 Cl 9 · 2H 2 O
journal, August 2009
- Krishnakumar, V.; Sheik Saleem, S.; Guru Prasad, L.
- Journal of Raman Spectroscopy, Vol. 40, Issue 8
Crystal growth in gel media
journal, December 1982
- Patel, A. R.; Venkateswara Rao, A.
- Bulletin of Materials Science, Vol. 4, Issue 5
Biomineralization-Inspired Green Synthesis of Zinc Phosphate-Based Nanosheets in Gelatin Hydrogel
journal, August 2016
- Parvinzadeh Gashti, Mazeyar; Helali, Mohammad; Karimi, Samin
- International Journal of Applied Ceramic Technology, Vol. 13, Issue 6
Nucleation kinetics of a new nonlinear optical crystal: Urea–thiourea zinc chloride
journal, March 2011
- Mojumdar, S. C.; Madhurambal, G.; Mariappan, M.
- Journal of Thermal Analysis and Calorimetry, Vol. 104, Issue 3
Diffusion-Controlled Crystallization of Calcium Carbonate in a Hydrogel
journal, December 2019
- Jo, Min-kyung; Oh, Yookyeong; Kim, Hye Ji
- Crystal Growth & Design, Vol. 20, Issue 2
Hydrogel as a miniature hydrogen production reactor to enhance photocatalytic hydrogen evolution activities of CdS and ZnS quantum dots derived from modified gel crystal growth method
journal, October 2019
- Jiang, Zaiyong; Zhang, Xinhan; Yang, Guihua
- Chemical Engineering Journal, Vol. 373
A New Metal-Organic Crystal: Bismuth Thiourea Chloride
journal, June 1998
- Bhat, S. G.; Dharmaprakash, S. M.
- Materials Research Bulletin, Vol. 33, Issue 6
Crystal growth and characterization of a new polymorph of bismuth trithiourea chloride
journal, January 2013
- Li, Ming; Li, R. K.
- CrystEngComm, Vol. 15, Issue 20
Crystal Growth of Calcium Carbonate in Hydrogels as a Model of Biomineralization
journal, May 2012
- Asenath-Smith, Emily; Li, Hanying; Keene, Ellen C.
- Advanced Functional Materials, Vol. 22, Issue 14
Supramolecular gel phase crystallization: orthogonal self-assembly under non-equilibrium conditions
journal, January 2014
- Kumar, D. Krishna; Steed, Jonathan W.
- Chem. Soc. Rev., Vol. 43, Issue 7
Growth and Characterization of ADP Single Crystal
journal, January 2012
- Chaki, Sunil; Deshpande, M. P.; P. Tailor, Jiten
- American Journal of Condensed Matter Physics, Vol. 2, Issue 1
Bis (thiourea) strontium chloride as promising NLO material: An experimental and theoretical study
journal, December 2016
- Rajagopalan, N. R.; Krishnamoorthy, P.; Jayamoorthy, K.
- Karbala International Journal of Modern Science, Vol. 2, Issue 4
Synthesis, Growth, and Characterization of a New Thiourea and Bismuth Chloride Complex with Excellent Nonlinear Optical Properties
journal, April 2018
- Zhang, Liang; Zhou, Lina; Hou, Baohong
- Transactions of Tianjin University, Vol. 24, Issue 6
Investigation on growth and morphology of in vitro generated struvite crystals
journal, January 2019
- Manzoor, Muhammed A. P.; Mujeeburahiman, M.; Duwal, Surya Ram
- Biocatalysis and Agricultural Biotechnology, Vol. 17
Supramolecular gel chemistry: developments over the last decade
journal, January 2011
- Steed, Jonathan W.
- Chem. Commun., Vol. 47, Issue 5
Crystal growth in gels: Principle and applications
journal, July 1988
- Robert, M. C.; Lefaucheux, F.
- Journal of Crystal Growth, Vol. 90, Issue 1-3
Gel Growth of K 2 PbCu(NO 2 ) 6 -Elpasolite Single Crystals
journal, August 2017
- Dong, Lianyang; Besara, Tiglet; Henderson, Alyssa
- Crystal Growth & Design, Vol. 17, Issue 10