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Title: “Water-in-salt” polymer electrolyte for Li-ion batteries

Abstract

An extended electrochemical stability window of 3.86 V is achieved at 12 mol kg −1 aqueous polymer electrolyte enabled 3 V full cells with an unprecedented high initial CE of 90.50% and average CE of 99.97%.

Authors:
 [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1]; ORCiD logo [1];  [2];  [3]; ORCiD logo [3];  [4];  [4]; ORCiD logo [1]; ORCiD logo [5]
  1. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, USA
  2. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, USA, Department Electrochemistry Branch
  3. Department Electrochemistry Branch, Sensor and Electron Devices Directorate, Power and Energy Division, US Army Research Laboratory, Adelphi
  4. Liox Power, Inc., Pasadena, USA
  5. Department of Chemical and Biomolecular Engineering, University of Maryland, College Park, USA, Department of Chemistry and Biochemistry
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1647272
Grant/Contract Number:  
DEAR0000389
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Name: Energy & Environmental Science Journal Volume: 13 Journal Issue: 9; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Zhang, Jiaxun, Cui, Chunyu, Wang, Peng-Fei, Li, Qin, Chen, Long, Han, Fudong, Jin, Ting, Liu, Sufu, Choudhary, Hema, Raghavan, Srinivasa R., Eidson, Nico, von Cresce, Arthur, Ma, Lin, Uddin, Jasim, Addison, Dan, Yang, Chongyin, and Wang, Chunsheng. “Water-in-salt” polymer electrolyte for Li-ion batteries. United Kingdom: N. p., 2020. Web. doi:10.1039/D0EE01510E.
Zhang, Jiaxun, Cui, Chunyu, Wang, Peng-Fei, Li, Qin, Chen, Long, Han, Fudong, Jin, Ting, Liu, Sufu, Choudhary, Hema, Raghavan, Srinivasa R., Eidson, Nico, von Cresce, Arthur, Ma, Lin, Uddin, Jasim, Addison, Dan, Yang, Chongyin, & Wang, Chunsheng. “Water-in-salt” polymer electrolyte for Li-ion batteries. United Kingdom. https://doi.org/10.1039/D0EE01510E
Zhang, Jiaxun, Cui, Chunyu, Wang, Peng-Fei, Li, Qin, Chen, Long, Han, Fudong, Jin, Ting, Liu, Sufu, Choudhary, Hema, Raghavan, Srinivasa R., Eidson, Nico, von Cresce, Arthur, Ma, Lin, Uddin, Jasim, Addison, Dan, Yang, Chongyin, and Wang, Chunsheng. Wed . "“Water-in-salt” polymer electrolyte for Li-ion batteries". United Kingdom. https://doi.org/10.1039/D0EE01510E.
@article{osti_1647272,
title = {“Water-in-salt” polymer electrolyte for Li-ion batteries},
author = {Zhang, Jiaxun and Cui, Chunyu and Wang, Peng-Fei and Li, Qin and Chen, Long and Han, Fudong and Jin, Ting and Liu, Sufu and Choudhary, Hema and Raghavan, Srinivasa R. and Eidson, Nico and von Cresce, Arthur and Ma, Lin and Uddin, Jasim and Addison, Dan and Yang, Chongyin and Wang, Chunsheng},
abstractNote = {An extended electrochemical stability window of 3.86 V is achieved at 12 mol kg −1 aqueous polymer electrolyte enabled 3 V full cells with an unprecedented high initial CE of 90.50% and average CE of 99.97%.},
doi = {10.1039/D0EE01510E},
journal = {Energy & Environmental Science},
number = 9,
volume = 13,
place = {United Kingdom},
year = {Wed Sep 16 00:00:00 EDT 2020},
month = {Wed Sep 16 00:00:00 EDT 2020}
}

Works referenced in this record:

Double-slit photoelectron interference in strong-field ionization of the neon dimer
journal, January 2019


Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility
journal, May 2017

  • Yang, Chongyin; Suo, Liumin; Borodin, Oleg
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 24
  • DOI: 10.1073/pnas.1703937114

Flexible Aqueous Li-Ion Battery with High Energy and Power Densities
journal, October 2017


XPS Study of group IA carbonates
journal, January 2004


Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite
journal, May 2019


Hydrate-melt electrolytes for high-energy-density aqueous batteries
journal, August 2016


Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes
journal, October 2017


4.0 V Aqueous Li-Ion Batteries
journal, September 2017


Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by “Water-in-Bisalt” Electrolyte
journal, April 2016


Potential dependent capacitance of [EMIM][TFSI], [N 1114 ][TFSI] and [PYR 13 ][TFSI] ionic liquids on glassy carbon
journal, January 2019

  • Klein, Jeffrey M.; Panichi, Evio; Gurkan, Burcu
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 7
  • DOI: 10.1039/C8CP04631J

Nature-Inspired Hydrogels with Soft and Stiff Zones that Exhibit a 100-Fold Difference in Elastic Modulus
journal, September 2018

  • Gharazi, Salimeh; Zarket, Brady C.; DeMella, Kerry C.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 40
  • DOI: 10.1021/acsami.8b14126

The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for “ Water-in-Salt ” electrolytes
journal, January 2018

  • Dubouis, Nicolas; Lemaire, Pierre; Mirvaux, Boris
  • Energy & Environmental Science, Vol. 11, Issue 12
  • DOI: 10.1039/C8EE02456A

Imprintable, Bendable, and Shape-Conformable Polymer Electrolytes for Versatile-Shaped Lithium-Ion Batteries
journal, December 2012

  • Kil, Eun-Hye; Choi, Keun-Ho; Ha, Hyo-Jeong
  • Advanced Materials, Vol. 25, Issue 10
  • DOI: 10.1002/adma.201204182

UV-cured natural polymer-based membrane for biosensor application
journal, January 2000


Performance Degradation and Gassing of Li 4 Ti 5 O 12 /LiMn 2 O 4 Lithium-Ion Cells
journal, January 2012

  • Belharouak, Ilias; Koenig, Gary M.; Tan, Taison
  • Journal of The Electrochemical Society, Vol. 159, Issue 8
  • DOI: 10.1149/2.013208jes

Depth profiles of hydrogen bound water molecule types and their relation to lipid and protein interaction in the human stratum corneum in vivo
journal, January 2016

  • Choe, ChunSik; Lademann, Jürgen; Darvin, Maxim E.
  • The Analyst, Vol. 141, Issue 22
  • DOI: 10.1039/C6AN01717G

How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes
journal, December 2017

  • Suo, Liumin; Oh, Dahyun; Lin, Yuxiao
  • Journal of the American Chemical Society, Vol. 139, Issue 51
  • DOI: 10.1021/jacs.7b10688

Methacrylic-based solid polymer electrolyte membranes for lithium-based batteries by a rapid UV-curing process
journal, April 2011


A 63 m Superconcentrated Aqueous Electrolyte for High-Energy Li-Ion Batteries
journal, February 2020


Impact of Carbon Nanostructures as Additives with Spinel Li 4 Ti 5 O 12 /LiMn 2 O 4 Electrodes for Lithium Ion Battery Technology
journal, October 2017

  • Gangaja, Binitha; Reddy, Kasireddy Siva; Nair, Shantikumar
  • ChemistrySelect, Vol. 2, Issue 30
  • DOI: 10.1002/slct.201702367

The Raman OH stretching bands of liquid water
journal, November 2009


Molecular Dynamics Study of Polymer−Water Interaction in Hydrogels. 1. Hydrogen-Bond Structure
journal, January 1996

  • Tamai, Yoshinori; Tanaka, Hideki; Nakanishi, Koichiro
  • Macromolecules, Vol. 29, Issue 21
  • DOI: 10.1021/ma951635z

Carbon-Nanomaterial-Based Flexible Batteries for Wearable Electronics
journal, January 2019


LiF as an Artificial SEI Layer to Enhance the High-Temperature Cycle Performance of Li 4 Ti 5 O 12
journal, September 2017


Formulation of Blended‐Lithium‐Salt Electrolytes for Lithium Batteries
journal, December 2019

  • Xu, Gaojie; Shangguan, Xuehui; Dong, Shanmu
  • Angewandte Chemie International Edition, Vol. 59, Issue 9
  • DOI: 10.1002/anie.201906494

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015


The use of UV irradiation in polymerization
journal, February 1998


UV-cured methacrylic membranes as novel gel–polymer electrolyte for Li-ion batteries
journal, April 2008


Water in Hydrogels. An NMR Study of Water/Polymer Interactions in Weakly Cross-Linked Chitosan Networks
journal, June 2001

  • Capitani, D.; Crescenzi, V.; Segre, A. L.
  • Macromolecules, Vol. 34, Issue 12
  • DOI: 10.1021/ma002109x

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Ultrafast Responsive Non‐Volatile Flash Photomemory via Spatially Addressable Perovskite/Block Copolymer Composite Film
journal, April 2020

  • Chang, Yu‐Hsiang; Ku, Chia‐Wei; Zhang, Yi‐Hua
  • Advanced Functional Materials, Vol. 30, Issue 21
  • DOI: 10.1002/adfm.202000764

A Flexible Dual-Ion Battery Based on PVDF-HFP-Modified Gel Polymer Electrolyte with Excellent Cycling Performance and Superior Rate Capability
journal, July 2018

  • Chen, Guanghai; Zhang, Fan; Zhou, Zhiming
  • Advanced Energy Materials, Vol. 8, Issue 25
  • DOI: 10.1002/aenm.201801219