Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries
Abstract
O3-layered metal oxides are promising cathode materials for high-energy Na-ion batteries (SIBs); however, they suffer from fast capacity fade. In this work, we develop a high-performance O3-NaNi0.68Mn0.22Co0.10O2 cathode for SIBs toward practical applications by suppressing the formation of a rock salt layer at the cathode surface with an advanced electrolyte. The cathode can deliver a high specific capacity of ~196 mAh g–1 and demonstrates >80% capacity retention over 1000 cycles. NaNi0.68Mn0.22Co0.10O2–hard carbon full-cells with practical loading (>2.5 mAh cm–2) and lean electrolyte (~40 μL) demonstrate ~82% capacity retention after 450 cycles. A 60 mAh single-layer pouch cell has also been fabricated and demonstrated stable performance. This work represents a significant leap in SIB development and brings new insights to the development of advanced layered metal oxide cathodes for alkaline-ion batteries.
- Authors:
-
[3];
[3];
[4];
[3];
[3];
[5];
[2];
[3]
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washington State Univ., Pullman, WA (United States)
- Beijing Univ. of Technology (China)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Washington State Univ., Pullman, WA (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Electricity (OE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; USDOE Office of Science (SC), Biological and Environmental Research (BER)
- OSTI Identifier:
- 1644016
- Alternate Identifier(s):
- OSTI ID: 1647034
- Report Number(s):
- BNL-216188-2020-JAAM; PNNL-SA-141318
Journal ID: ISSN 2380-8195
- Grant/Contract Number:
- SC0012704; 70247A; 51621003; 2016YFB0700700; AC02-05CH11231; 6951379; AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Energy Letters
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 6; Journal ID: ISSN 2380-8195
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; Layers; Electrodes; Batteries; Phase transitions; Electrolytes; layers, electrodes, batteries, Phase transitions, electrolytes
Citation Formats
Song, Junhua, Wang, Kuan, Zheng, Jianming, Engelhard, Mark H., Xiao, Biwei, Hu, Enyuan, Zhu, Zihua, Wang, Chongmin, Sui, Manling, Lin, Yuehe, Reed, David, Sprenkle, Vincent L., Yan, Pengfei, and Li, Xiaolin. Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries. United States: N. p., 2020.
Web. doi:10.1021/acsenergylett.0c00700.
Song, Junhua, Wang, Kuan, Zheng, Jianming, Engelhard, Mark H., Xiao, Biwei, Hu, Enyuan, Zhu, Zihua, Wang, Chongmin, Sui, Manling, Lin, Yuehe, Reed, David, Sprenkle, Vincent L., Yan, Pengfei, & Li, Xiaolin. Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries. United States. https://doi.org/10.1021/acsenergylett.0c00700
Song, Junhua, Wang, Kuan, Zheng, Jianming, Engelhard, Mark H., Xiao, Biwei, Hu, Enyuan, Zhu, Zihua, Wang, Chongmin, Sui, Manling, Lin, Yuehe, Reed, David, Sprenkle, Vincent L., Yan, Pengfei, and Li, Xiaolin. Tue .
"Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries". United States. https://doi.org/10.1021/acsenergylett.0c00700. https://www.osti.gov/servlets/purl/1644016.
@article{osti_1644016,
title = {Controlling Surface Phase Transition and Chemical Reactivity of O3-Layered Metal Oxide Cathodes for High-Performance Na-Ion Batteries},
author = {Song, Junhua and Wang, Kuan and Zheng, Jianming and Engelhard, Mark H. and Xiao, Biwei and Hu, Enyuan and Zhu, Zihua and Wang, Chongmin and Sui, Manling and Lin, Yuehe and Reed, David and Sprenkle, Vincent L. and Yan, Pengfei and Li, Xiaolin},
abstractNote = {O3-layered metal oxides are promising cathode materials for high-energy Na-ion batteries (SIBs); however, they suffer from fast capacity fade. In this work, we develop a high-performance O3-NaNi0.68Mn0.22Co0.10O2 cathode for SIBs toward practical applications by suppressing the formation of a rock salt layer at the cathode surface with an advanced electrolyte. The cathode can deliver a high specific capacity of ~196 mAh g–1 and demonstrates >80% capacity retention over 1000 cycles. NaNi0.68Mn0.22Co0.10O2–hard carbon full-cells with practical loading (>2.5 mAh cm–2) and lean electrolyte (~40 μL) demonstrate ~82% capacity retention after 450 cycles. A 60 mAh single-layer pouch cell has also been fabricated and demonstrated stable performance. This work represents a significant leap in SIB development and brings new insights to the development of advanced layered metal oxide cathodes for alkaline-ion batteries.},
doi = {10.1021/acsenergylett.0c00700},
journal = {ACS Energy Letters},
number = 6,
volume = 5,
place = {United States},
year = {Tue Apr 28 00:00:00 EDT 2020},
month = {Tue Apr 28 00:00:00 EDT 2020}
}
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Works referenced in this record:
A cost and resource analysis of sodium-ion batteries
journal, March 2018
- Vaalma, Christoph; Buchholz, Daniel; Weil, Marcel
- Nature Reviews Materials, Vol. 3, Issue 4
Ten years left to redesign lithium-ion batteries
journal, July 2018
- Turcheniuk, Kostiantyn; Bondarev, Dmitry; Singhal, Vinod
- Nature, Vol. 559, Issue 7715
The Scale-up and Commercialization of Nonaqueous Na-Ion Battery Technologies
journal, March 2018
- Bauer, Alexander; Song, Jie; Vail, Sean
- Advanced Energy Materials, Vol. 8, Issue 17
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
A New High-Energy Cathode for a Na-Ion Battery with Ultrahigh Stability
journal, September 2013
- Park, Young-Uk; Seo, Dong-Hwa; Kwon, Hyung-Soon
- Journal of the American Chemical Society, Vol. 135, Issue 37
A 3.8-V earth-abundant sodium battery electrode
journal, July 2014
- Barpanda, Prabeer; Oyama, Gosuke; Nishimura, Shin-ichi
- Nature Communications, Vol. 5, Issue 1
Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries
journal, October 2014
- Lee, Hyun-Wook; Wang, Richard Y.; Pasta, Mauro
- Nature Communications, Vol. 5, Issue 1
Rhombohedral Prussian White as Cathode for Rechargeable Sodium-Ion Batteries
journal, February 2015
- Wang, Long; Song, Jie; Qiao, Ruimin
- Journal of the American Chemical Society, Vol. 137, Issue 7
Anionic Redox Reaction-Induced High-Capacity and Low-Strain Cathode with Suppressed Phase Transition
journal, February 2019
- Rong, Xiaohui; Hu, Enyuan; Lu, Yaxiang
- Joule, Vol. 3, Issue 2
Oxygen redox chemistry without excess alkali-metal ions in Na2/3[Mg0.28Mn0.72]O2
journal, January 2018
- Maitra, Urmimala; House, Robert A.; Somerville, James W.
- Nature Chemistry, Vol. 10, Issue 3
A new O3-type layered oxide cathode with high energy/power density for rechargeable Na batteries
journal, January 2015
- Liu, Haodong; Xu, Jing; Ma, Chuze
- Chemical Communications, Vol. 51, Issue 22
High Energy Density Sodium-Ion Battery with Industrially Feasible and Air-Stable O3-Type Layered Oxide Cathode
journal, October 2017
- Deng, Jianqiu; Luo, Wen-Bin; Lu, Xiao
- Advanced Energy Materials, Vol. 8, Issue 5
Insight into Ca-Substitution Effects on O3-Type NaNi 1/3 Fe 1/3 Mn 1/3 O 2 Cathode Materials for Sodium-Ion Batteries Application
journal, April 2018
- Sun, Liqi; Xie, Yingying; Liao, Xiao-Zhen
- Small, Vol. 14, Issue 21
Radially aligned hierarchical columnar structure as a cathode material for high energy density sodium-ion batteries
journal, April 2015
- Hwang, Jang-Yeon; Oh, Seung-Min; Myung, Seung-Taek
- Nature Communications, Vol. 6, Issue 1
Designing Air-Stable O3-Type Cathode Materials by Combined Structure Modulation for Na-Ion Batteries
journal, June 2017
- Yao, Hu-Rong; Wang, Peng-Fei; Gong, Yue
- Journal of the American Chemical Society, Vol. 139, Issue 25
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode
journal, October 2015
- Mu, Linqin; Xu, Shuyin; Li, Yunming
- Advanced Materials, Vol. 27, Issue 43
Environmentally stable interface of layered oxide cathodes for sodium-ion batteries
journal, July 2017
- Guo, Shaohua; Li, Qi; Liu, Pan
- Nature Communications, Vol. 8, Issue 1
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries
journal, March 2014
- Lin, Feng; Markus, Isaac M.; Nordlund, Dennis
- Nature Communications, Vol. 5, Issue 1
Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries
journal, January 2017
- Yan, Pengfei; Zheng, Jianming; Gu, Meng
- Nature Communications, Vol. 8, Issue 1
Prospect and Reality of Ni-Rich Cathode for Commercialization
journal, November 2017
- Kim, Junhyeok; Lee, Hyomyung; Cha, Hyungyeon
- Advanced Energy Materials, Vol. 8, Issue 6
Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015
- Kubota, Kei; Komaba, Shinichi
- Journal of The Electrochemical Society, Vol. 162, Issue 14
Progress in High-Voltage Cathode Materials for Rechargeable Sodium-Ion Batteries
journal, September 2017
- You, Ya; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 8, Issue 2
Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014
- Xu, Kang
- Chemical Reviews, Vol. 114, Issue 23
Interphases in Sodium-Ion Batteries
journal, March 2018
- Song, Junhua; Xiao, Biwei; Lin, Yuehe
- Advanced Energy Materials, Vol. 8, Issue 17
Lithium-Pretreated Hard Carbon as High-Performance Sodium-Ion Battery Anodes
journal, July 2018
- Xiao, Biwei; Soto, Fernando A.; Gu, Meng
- Advanced Energy Materials, Vol. 8, Issue 24
Extremely Stable Sodium Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, January 2018
- Zheng, Jianming; Chen, Shuru; Zhao, Wengao
- ACS Energy Letters, Vol. 3, Issue 2
Superconcentrated electrolytes for a high-voltage lithium-ion battery
journal, June 2016
- Wang, Jianhui; Yamada, Yuki; Sodeyama, Keitaro
- Nature Communications, Vol. 7, Issue 1
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries
journal, March 2017
- Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai
- Nature Energy, Vol. 2, Issue 3
Stable cycling of high-voltage lithium metal batteries in ether electrolytes
journal, July 2018
- Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo
- Nature Energy, Vol. 3, Issue 9
High-Voltage Lithium-Metal Batteries Enabled by Localized High-Concentration Electrolytes
journal, March 2018
- Chen, Shuru; Zheng, Jianming; Mei, Donghai
- Advanced Materials, Vol. 30, Issue 21
Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries
journal, July 2018
- Fan, Xiulin; Chen, Long; Borodin, Oleg
- Nature Nanotechnology, Vol. 13, Issue 8
A comprehensive study of the role of transition metals in O3-type layered Na[Ni x Co y Mn z ]O 2 (x = 1/3, 0.5, 0.6, and 0.8) cathodes for sodium-ion batteries
journal, January 2016
- Hwang, Jang-Yeon; Yoon, Chong S.; Belharouak, Ilias
- Journal of Materials Chemistry A, Vol. 4, Issue 46
Nickel-Rich Layered Cathode Materials for Automotive Lithium-Ion Batteries: Achievements and Perspectives
journal, December 2016
- Myung, Seung-Taek; Maglia, Filippo; Park, Kang-Joon
- ACS Energy Letters, Vol. 2, Issue 1
Stabilization of a High-Capacity and High-Power Nickel-Based Cathode for Li-Ion Batteries
journal, April 2018
- Zeng, Xiaoqiao; Zhan, Chun; Lu, Jun
- Chem, Vol. 4, Issue 4
History, Evolution, and Future Status of Energy Storage
journal, May 2012
- Whittingham, M. S.
- Proceedings of the IEEE, Vol. 100, Issue Special Centennial Issue
Ultimate Limits to Intercalation Reactions for Lithium Batteries
journal, October 2014
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 114, Issue 23
Investigation of O3-type Na0.9Ni0.45MnxTi0.55-xO2 (0 ≤ x ≤ 0.55) as positive electrode materials for sodium-ion batteries
journal, April 2017
- Zheng, Lituo; Obrovac, M. N.
- Electrochimica Acta, Vol. 233
Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni 0.4 Mn 0.4 Co 0.2 )O 2 /Graphite Pouch Cells
journal, January 2016
- Xia, Jian; Petibon, Remi; Xiao, A.
- Journal of The Electrochemical Society, Vol. 163, Issue 8
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013
- Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
- Advanced Energy Materials, Vol. 4, Issue 1
Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries
journal, March 2015
- Liu, Wen; Oh, Pilgun; Liu, Xien
- Angewandte Chemie International Edition, Vol. 54, Issue 15
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016
- Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Chemomechanical interplay of layered cathode materials undergoing fast charging in lithium batteries
journal, November 2018
- Xia, Sihao; Mu, Linqin; Xu, Zhengrui
- Nano Energy, Vol. 53
High-Energy Ni-Rich Li[Ni x Co y Mn 1 –x–y ]O 2 Cathodes via Compositional Partitioning for Next-Generation Electric Vehicles
journal, November 2017
- Yoon, Chong S.; Park, Kang-Joon; Kim, Un-Hyuck
- Chemistry of Materials, Vol. 29, Issue 24
Solid–Liquid Interfacial Reaction Trigged Propagation of Phase Transition from Surface into Bulk Lattice of Ni-Rich Layered Cathode
journal, September 2018
- Zou, Lianfeng; Liu, Zhenyu; Zhao, Wengao
- Chemistry of Materials, Vol. 30, Issue 20
The Formation Mechanism of Fluorescent Metal Complexes at the Li x Ni 0.5 Mn 1.5 O 4−δ /Carbonate Ester Electrolyte Interface
journal, March 2015
- Jarry, Angélique; Gottis, Sébastien; Yu, Young-Sang
- Journal of the American Chemical Society, Vol. 137, Issue 10
Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries
journal, June 2018
- Yan, Pengfei; Zheng, Jianming; Liu, Jian
- Nature Energy, Vol. 3, Issue 7
The Effect of Carbon Dioxide on the Cycle Life and Electrolyte Stability of Li-Ion Full Cells Containing Silicon Alloy
journal, January 2017
- Krause, L. J.; Chevrier, V. L.; Jensen, L. D.
- Journal of The Electrochemical Society, Vol. 164, Issue 12