In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing
Abstract
Complementary techniques were applied to characterize the structure property relationships of FDM printed isotactic polypropylene/graphene nanocomposites. Raman spectroscopy indicated that graphene was mostly exfoliated during the nozzle extrusion process. Rheological measurements of the viscosity indicated that the presence of graphene induced shear thinning during extrusion. Azimuthal scans of wide angle x-ray scattering indicate correlated thermal fluctuations of the graphene platelets which stops abruptly at the onset of transcrystallization, or templating of the iPP chains on the graphene. X-ray microbeam SAXS analysis show the formation of ‘shish-kebab’ structures at the core of the unfilled filaments, where the ‘kebab’ component vanishes at the fiber-fiber interface enabling interdiffusion. Weak lamellar structure, and a corresponding decrease in the storage modulus are observed with the addition of 5% graphene. The lamellar structure disappears entirely with the addition of 10% graphene, while the storage modulus is decreased by nearly 50%. Thermal imaging of heat flux dissipation across molded and printed samples shows no orientational effects in pure iPP despite differences in crystal structure. Thermal conductivity increases dramatically in the samples with 10% graphene, and strong orientational effects are observed where the thermal coefficients differ by 180% between samples printed parallel or perpendicular to the heat flux.
- Authors:
-
- Stony Brook Univ., NY (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
- Hebrew Univ. of Jerusalem (Israel)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States); AArgonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Casali Foundation Israel
- OSTI Identifier:
- 1643999
- Alternate Identifier(s):
- OSTI ID: 1774535; OSTI ID: 1777571
- Report Number(s):
- BNL-216194-2020-JAAM
Journal ID: ISSN 0266-3538
- Grant/Contract Number:
- SC0012704; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Composites Science and Technology
- Additional Journal Information:
- Journal Volume: 196; Journal ID: ISSN 0266-3538
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Shmueli, Yuval, Lin, Yu-Chung, Zuo, Xianghao, Guo, Yichen, Lee, Sungsik, Freychet, Guillaume, Zhernenkov, Mikhail, Kim, Taejin, Tannenbaum, Rina, Marom, Gad, Gersappe, Dilip, and Rafailovich, Miriam H. In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing. United States: N. p., 2020.
Web. doi:10.1016/j.compscitech.2020.108227.
Shmueli, Yuval, Lin, Yu-Chung, Zuo, Xianghao, Guo, Yichen, Lee, Sungsik, Freychet, Guillaume, Zhernenkov, Mikhail, Kim, Taejin, Tannenbaum, Rina, Marom, Gad, Gersappe, Dilip, & Rafailovich, Miriam H. In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing. United States. https://doi.org/10.1016/j.compscitech.2020.108227
Shmueli, Yuval, Lin, Yu-Chung, Zuo, Xianghao, Guo, Yichen, Lee, Sungsik, Freychet, Guillaume, Zhernenkov, Mikhail, Kim, Taejin, Tannenbaum, Rina, Marom, Gad, Gersappe, Dilip, and Rafailovich, Miriam H. Fri .
"In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing". United States. https://doi.org/10.1016/j.compscitech.2020.108227. https://www.osti.gov/servlets/purl/1643999.
@article{osti_1643999,
title = {In-situ X-ray scattering study of isotactic polypropylene/graphene nanocomposites under shear during fused deposition modeling 3D printing},
author = {Shmueli, Yuval and Lin, Yu-Chung and Zuo, Xianghao and Guo, Yichen and Lee, Sungsik and Freychet, Guillaume and Zhernenkov, Mikhail and Kim, Taejin and Tannenbaum, Rina and Marom, Gad and Gersappe, Dilip and Rafailovich, Miriam H.},
abstractNote = {Complementary techniques were applied to characterize the structure property relationships of FDM printed isotactic polypropylene/graphene nanocomposites. Raman spectroscopy indicated that graphene was mostly exfoliated during the nozzle extrusion process. Rheological measurements of the viscosity indicated that the presence of graphene induced shear thinning during extrusion. Azimuthal scans of wide angle x-ray scattering indicate correlated thermal fluctuations of the graphene platelets which stops abruptly at the onset of transcrystallization, or templating of the iPP chains on the graphene. X-ray microbeam SAXS analysis show the formation of ‘shish-kebab’ structures at the core of the unfilled filaments, where the ‘kebab’ component vanishes at the fiber-fiber interface enabling interdiffusion. Weak lamellar structure, and a corresponding decrease in the storage modulus are observed with the addition of 5% graphene. The lamellar structure disappears entirely with the addition of 10% graphene, while the storage modulus is decreased by nearly 50%. Thermal imaging of heat flux dissipation across molded and printed samples shows no orientational effects in pure iPP despite differences in crystal structure. Thermal conductivity increases dramatically in the samples with 10% graphene, and strong orientational effects are observed where the thermal coefficients differ by 180% between samples printed parallel or perpendicular to the heat flux.},
doi = {10.1016/j.compscitech.2020.108227},
journal = {Composites Science and Technology},
number = ,
volume = 196,
place = {United States},
year = {Fri May 15 00:00:00 EDT 2020},
month = {Fri May 15 00:00:00 EDT 2020}
}
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Works referenced in this record:
Anisotropic material properties of fused deposition modeling ABS
journal, October 2002
- Ahn, Sung‐Hoon; Montero, Michael; Odell, Dan
- Rapid Prototyping Journal, Vol. 8, Issue 4
Disentanglement effects on welding behaviour of polymer melts during the fused-filament-fabrication method for additive manufacturing
journal, August 2017
- McIlroy, C.; Olmsted, P. D.
- Polymer, Vol. 123
Weld formation during material extrusion additive manufacturing
journal, January 2017
- Seppala, Jonathan E.; Hoon Han, Seung; Hillgartner, Kaitlyn E.
- Soft Matter, Vol. 13, Issue 38
Alignments and network of graphite fillers to improve thermal conductivity of epoxy-based composites
journal, October 2015
- Burger, N.; Laachachi, A.; Mortazavi, B.
- International Journal of Heat and Mass Transfer, Vol. 89
Thermal conductivity of polymer-based composites: Fundamentals and applications
journal, August 2016
- Chen, Hongyu; Ginzburg, Valeriy V.; Yang, Jian
- Progress in Polymer Science, Vol. 59
High thermal conductivity of chain-oriented amorphous polythiophene
journal, March 2014
- Singh, Virendra; Bougher, Thomas L.; Weathers, Annie
- Nature Nanotechnology, Vol. 9, Issue 5
RTA-Treated Carbon Fiber/Copper Core/Shell Hybrid for Thermally Conductive Composites
journal, May 2014
- Yu, Seunggun; Park, Bo-In; Park, Cheolmin
- ACS Applied Materials & Interfaces, Vol. 6, Issue 10
Shear-induced crystallization of isotactic polypropylene within the oriented scaffold of noncrystalline ultrahigh molecular weight polyethylene
journal, September 2005
- Avila-Orta, Carlos A.; Burger, Christian; Somani, Rajesh
- Polymer, Vol. 46, Issue 20
Shear-induced crystallization in isotactic polypropylene containing ultra-high molecular weight polyethylene oriented precursor domains
journal, April 2005
- Dikovsky, Daniel; Marom, Gad; Avila-Orta, Carlos A.
- Polymer, Vol. 46, Issue 9
Shear-Enhanced Crystallization in Isotactic Polypropylene. 1. Correspondence between in Situ Rheo-Optics and ex Situ Structure Determination
journal, November 1999
- Kumaraswamy, Guruswamy; Issaian, Ani M.; Kornfield, Julia A.
- Macromolecules, Vol. 32, Issue 22
Shear-enhanced crystallization in isotactic polypropylenePart 2. Analysis of the formation of the oriented “skin”
journal, December 2000
- Kumaraswamy, G.; Verma, R. K.; Issaian, A. M.
- Polymer, Vol. 41, Issue 25
Shear-Enhanced Crystallization in Isotactic Polypropylene. In-Situ Synchrotron SAXS and WAXD
journal, November 2004
- Kumaraswamy, Guruswamy; Verma, Ravi K.; Kornfield, Julia A.
- Macromolecules, Vol. 37, Issue 24
Combined effect of shear and fibrous fillers on orientation-induced crystallization in discontinuous aramid fiber/isotactic polypropylene composites
journal, January 2008
- Larin, Boris; Avila-Orta, Carlos A.; Somani, Rajesh H.
- Polymer, Vol. 49, Issue 1
Shear-induced crystallization of isotactic polypropylene with different molecular weight distributions: in situ small- and wide-angle X-ray scattering studies
journal, June 2001
- Nogales, A.; Hsiao, B. S.; Somani, R. H.
- Polymer, Vol. 42, Issue 12
Restructuring of confined crystalline morphology in the drawing process of VGCF-iPP nanocomposite filaments
journal, October 2018
- Shalom, Yair; Wachtel, Ellen; Marom, Gad
- Polymer, Vol. 154
Network formation in polymer nanocomposites under shear
journal, January 2011
- Jaber, Eihab; Luo, Haobin; Li, Wentao
- Soft Matter, Vol. 7, Issue 8
In Situ Time-Resolved X-ray Scattering Study of Isotactic Polypropylene in Additive Manufacturing
journal, September 2019
- Shmueli, Yuval; Lin, Yu-Chung; Lee, Sungsik
- ACS Applied Materials & Interfaces, Vol. 11, Issue 40
Preparation and Mechanical Properties of Polypropylene−Clay Hybrids
journal, October 1997
- Kawasumi, Masaya; Hasegawa, Naoki; Kato, Makoto
- Macromolecules, Vol. 30, Issue 20
Mechanical properties of polypropylene composites: A review
journal, December 2011
- Shubhra, Quazi TH; Alam, Akmm; Quaiyyum, Ma
- Journal of Thermoplastic Composite Materials, Vol. 26, Issue 3
Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008
- Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong
- Nano Letters, Vol. 8, Issue 3, p. 902-907
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
Boron Nitride Nanomaterials for Thermal Management Applications
journal, February 2015
- Meziani, Mohammed J.; Song, Wei-Li; Wang, Ping
- ChemPhysChem, Vol. 16, Issue 7
Carbon nanofiller networks- a comparative study of networks formed by branched versus linear carbon nanotubes in thermoplastic polyurethane
journal, June 2019
- Solouki Bonab, Vahab; Maxian, Ondrej; Manas-Zloczower, Ica
- Polymer, Vol. 175
Shear-induced preferential alignment of carbon nanotubes resulted in anisotropic electrical conductivity of polymer composites
journal, November 2006
- Lanticse, Leslie Joy; Tanabe, Yasuhiro; Matsui, Keitaro
- Carbon, Vol. 44, Issue 14
Comparison of filler percolation and mechanical properties in graphene and carbon nanotubes filled epoxy nanocomposites
journal, June 2013
- Martin-Gallego, M.; Bernal, M. M.; Hernandez, M.
- European Polymer Journal, Vol. 49, Issue 6
Rheological Behavior of Filled Polymeric Systems I. Yield Stress and Shear‐Thinning Effects
journal, October 1988
- Poslinski, A. J.; Ryan, M. E.; Gupta, R. K.
- Journal of Rheology, Vol. 32, Issue 7
Conductive polymer composites with carbonic fillers: Shear induced electrical behaviour
journal, March 2018
- Starý, Zdeněk; Krückel, Johannes
- Polymer, Vol. 139
In Operando Monitoring of Dynamic Recovery in 3D-Printed Thermoset Nanocomposites by XPCS
journal, June 2019
- Johnson, Kyle J.; Wiegart, Lutz; Abbott, Andrew C.
- Langmuir, Vol. 35, Issue 26
Simultaneous in Situ X-ray Scattering and Infrared Imaging of Polymer Extrusion in Additive Manufacturing
journal, May 2019
- Shmueli, Yuval; Jiang, Jiaolong; Zhou, Yuchen
- ACS Applied Polymer Materials, Vol. 1, Issue 6
Instrumentation for In situ/Operando X-ray Scattering Studies of Polymer Additive Manufacturing Processes
journal, March 2019
- Wiegart, L.; Doerk, G. S.; Fukuto, M.
- Synchrotron Radiation News, Vol. 32, Issue 2
Synthesis and characterization of graphene: influence of synthesis variables
journal, January 2014
- Lavin-Lopez, M. P.; Valverde, J. L.; Cuevas, M. C.
- Physical Chemistry Chemical Physics, Vol. 16, Issue 7
Melt rheological properties of nylon 6/multi-walled carbon nanotube composites
journal, September 2008
- Wang, Min; Wang, Weizhi; Liu, Tianxi
- Composites Science and Technology, Vol. 68, Issue 12
The spherulitic and lamellar morphology of melt-crystallized isotactic polypropylene
journal, May 1985
- Norton, D. R.; Keller, A.
- Polymer, Vol. 26, Issue 5
The thermo-mechanical response of PP nanocomposites at high graphene loading
journal, July 2015
- Yang, Kai; Endoh, Maya; Trojanowski, Rebecca
- Nanocomposites, Vol. 1, Issue 3
Graphene Nanosheets and Shear Flow Induced Crystallization in Isotactic Polypropylene Nanocomposites
journal, April 2011
- Xu, Jia-Zhuang; Chen, Chen; Wang, Yan
- Macromolecules, Vol. 44, Issue 8
Polypropylene–graphene – a nanocomposite that can be converted into a meta-material at desired frequencies
journal, January 2014
- Perumal Ramasamy, Radha; Yang, Kai; Rafailovich, Miriam H.
- RSC Adv., Vol. 4, Issue 85
Segmental Dynamics of Head-to-Head Polypropylene and Polyisobutylene in Their Blend and Pure Components
journal, September 2005
- Krygier, Ernest; Lin, Guoxing; Mendes, Jessica
- Macromolecules, Vol. 38, Issue 18
Unusual Rheological Behavior of Liquid Polybutadiene Rubber/Clay Nanocomposite Gels: The Role of Polymer−Clay Interaction, Clay Exfoliation, and Clay Orientation and Disorientation
journal, September 2006
- Wang, Xiaoliang; Gao, Yun; Mao, Kanmi
- Macromolecules, Vol. 39, Issue 19