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Title: Enhanced Friedel-Crafts benzylation activity of bimetallic WSn-KIT-6 catalysts

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Publication Date:
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OSTI Identifier:
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Catalysis
Additional Journal Information:
Journal Name: Journal of Catalysis Journal Volume: 389 Journal Issue: C; Journal ID: ISSN 0021-9517
Country of Publication:
United States

Citation Formats

Maheswari, Rajamanickam, Ramanathan, Anand, Zhu, Hongda, Araújo do Nascimento Araújo, Aline, Chapman, Clint, Tang, Yu, Feng) Tao, Franklin, and Subramaniam, Bala. Enhanced Friedel-Crafts benzylation activity of bimetallic WSn-KIT-6 catalysts. United States: N. p., 2020. Web. doi:10.1016/j.jcat.2020.07.001.
Maheswari, Rajamanickam, Ramanathan, Anand, Zhu, Hongda, Araújo do Nascimento Araújo, Aline, Chapman, Clint, Tang, Yu, Feng) Tao, Franklin, & Subramaniam, Bala. Enhanced Friedel-Crafts benzylation activity of bimetallic WSn-KIT-6 catalysts. United States.
Maheswari, Rajamanickam, Ramanathan, Anand, Zhu, Hongda, Araújo do Nascimento Araújo, Aline, Chapman, Clint, Tang, Yu, Feng) Tao, Franklin, and Subramaniam, Bala. Tue . "Enhanced Friedel-Crafts benzylation activity of bimetallic WSn-KIT-6 catalysts". United States.
title = {Enhanced Friedel-Crafts benzylation activity of bimetallic WSn-KIT-6 catalysts},
author = {Maheswari, Rajamanickam and Ramanathan, Anand and Zhu, Hongda and Araújo do Nascimento Araújo, Aline and Chapman, Clint and Tang, Yu and Feng) Tao, Franklin and Subramaniam, Bala},
abstractNote = {},
doi = {10.1016/j.jcat.2020.07.001},
journal = {Journal of Catalysis},
number = C,
volume = 389,
place = {United States},
year = {2020},
month = {9}

Works referenced in this record:

Preparation and characterization of mesoporous Zr-WOx/SiO2 catalysts for the esterification of 1-butanol with acetic acid
journal, January 2012

  • Kim, Tae Yong; Park, Dae Sung; Choi, Youngbo
  • Journal of Materials Chemistry, Vol. 22, Issue 19
  • DOI: 10.1039/c2jm30904a

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Physisorption of gases, with special reference to the evaluation of surface area and pore size distribution (IUPAC Technical Report)
journal, October 2015

  • Thommes, Matthias; Kaneko, Katsumi; Neimark, Alexander V.
  • Pure and Applied Chemistry, Vol. 87, Issue 9-10
  • DOI: 10.1515/pac-2014-1117

Synthesis and Dehydration Activity of Novel Lewis Acidic Ordered Mesoporous Silicate: Zr-KIT-6
journal, September 2013

  • Pan, Qing; Ramanathan, Anand; Snavely, W. Kirk
  • Industrial & Engineering Chemistry Research, Vol. 52, Issue 44
  • DOI: 10.1021/ie4019484

Heteropoly tungstate supported on tin oxide catalysts for liquid phase benzylation of anisole with benzyl alcohol
journal, August 2010

Heterogeneity of OH groups in NaH-mordenites: Effect of Na/H exchange degree
journal, April 1997

Liquid phase alkylation of anisole by benzyl alcohol catalyzed on alumina-supported niobia
journal, November 2007

  • de la Cruz, Marcus H. C.; Abdel-Rehim, Mona A.; Rocha, Angela S.
  • Catalysis Communications, Vol. 8, Issue 11
  • DOI: 10.1016/j.catcom.2007.01.019

Accessing Realistic Models for the WO 3 –SiO 2 Industrial Catalyst through the Design of Organometallic Precursors
journal, November 2015

Effects of tunable acidity and basicity of Nb-KIT-6 catalysts on ethanol conversion: Experiments and kinetic modeling
journal, February 2017

  • Zhu, Hongda; Chaudhari, Raghunath V.; Subramaniam, Bala
  • AIChE Journal, Vol. 63, Issue 7
  • DOI: 10.1002/aic.15648

Reactions of d0 tungsten alkylidyne complexes with O2 or H2O. Formation of an oxo siloxy complex through unusual silyl migrations
journal, January 2013

  • Morton, Laurel A.; Miao, Maozhong; Callaway, Tabitha M.
  • Chemical Communications, Vol. 49, Issue 83
  • DOI: 10.1039/c3cc46014b

Characterization and activity of novel tin incorporated ordered cubic mesoporous silicate, Sn-KIT-6
journal, March 2016

Structure and properties of tungstated zirconia catalysts for alkane conversion
journal, May 2003

Hollow WO3/SnO2 Hetero-Nanofibers: Controlled Synthesis and High Efficiency of Acetone Vapor Detection
journal, November 2019

Synthesis, Characterization, and Epoxidation Activity of Tungsten-Incorporated SBA-16 (W-SBA-16)
journal, March 2014

  • Maheswari, Rajamanickam; Pachamuthu, Muthusamy P.; Ramanathan, Anand
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 49
  • DOI: 10.1021/ie501784c

Novel zirconium containing cage type silicate (Zr-KIT-5): An efficient Friedel–Crafts alkylation catalyst
journal, October 2015

  • Ramanathan, Anand; Zhu, Hongda; Maheswari, Rajamanickam
  • Chemical Engineering Journal, Vol. 278
  • DOI: 10.1016/j.cej.2014.11.099

Synthesis of Highly Acidic Catalysts of Tungsten Oxide Supported on Tin Oxide, Titanium Oxide, and Iron Oxide
journal, May 1994

  • Hino, Makoto; Arata, Kazushi
  • Bulletin of the Chemical Society of Japan, Vol. 67, Issue 5
  • DOI: 10.1246/bcsj.67.1472

Synthesis and characterizations of isolated WO4 anchored on mesoporous TiTUD-1 support
journal, April 2017

XAS Study of Amorphous WO 3 Formation from a Peroxo-Tungstate Solution
journal, August 2003

  • Pauporté, T.; Soldo-Olivier, Y.; Faure, R.
  • The Journal of Physical Chemistry B, Vol. 107, Issue 34
  • DOI: 10.1021/jp034279s

Identification of active Zr–WOx clusters on a ZrO2 support for solid acid catalysts
journal, November 2009

  • Zhou, Wu; Ross-Medgaarden, Elizabeth I.; Knowles, William V.
  • Nature Chemistry, Vol. 1, Issue 9
  • DOI: 10.1038/nchem.433

Genesis of Strong Brønsted Acid Sites in WZr-KIT-6 Catalysts and Enhancement of Ethanol Dehydration Activity
journal, April 2018

Biodiesel production from soybean oil transesterification using tin oxide-supported WO3 catalysts
journal, May 2013

Effect of mesoporosity on selective benzylation of aromatics with benzyl alcohol over mesoporous ZSM-5
journal, July 2012

Design of highly efficient Mo and W-promoted SnO 2 solid acids for heterogeneous catalysis: acetalization of bio-glycerol
journal, January 2013

  • Mallesham, Baithy; Sudarsanam, Putla; Raju, Gangadhara
  • Green Chem., Vol. 15, Issue 2
  • DOI: 10.1039/C2GC36152C

Effect of tungsten oxide loading on metathesis activity of ethene and 2-butene over WO3/SiO2 catalysts
journal, June 2009

Tungsten-incorporated cage-type mesoporous silicate: W-KIT-5
journal, July 2013

Niobium incorporated mesoporous silicate, Nb-KIT-6: Synthesis and characterization
journal, May 2014

Synthesis of a new SnO2/mesoporous silica composite with room-temperature photoluminescence
journal, February 2006

Tin–Tungsten Mixed Oxide as Efficient Heterogeneous Catalyst for Conversion of Saccharides to Furan Derivatives
journal, May 2011

  • Yamaguchi, Kazuya; Sakurada, Tomoaki; Ogasawara, Yoshiyuki
  • Chemistry Letters, Vol. 40, Issue 5
  • DOI: 10.1246/cl.2011.542

Characterization of Sn- and Zn-loaded MCM-41 catalysts for nopol synthesis
journal, June 2009

  • Alarcón, Edwin A.; Villa, Aída Luz; Correa, Consuelo Montes de
  • Microporous and Mesoporous Materials, Vol. 122, Issue 1-3
  • DOI: 10.1016/j.micromeso.2009.03.003

Synthesis and characterization of Zirconium incorporated ultra large pore mesoporous silicate, Zr–KIT-6
journal, February 2013

Direct incorporation of tungsten into ultra-large-pore three-dimensional mesoporous silicate framework: W-KIT-6
journal, January 2012

  • Ramanathan, Anand; Subramaniam, Bala; Badloe, Dinesh
  • Journal of Porous Materials, Vol. 19, Issue 6
  • DOI: 10.1007/s10934-011-9553-y

Synthesis of solid superacid of tungsten oxide supported on zirconia and its catalytic action for reactions of butane and pentane
journal, January 1988

  • Hino, Makoto; Arata, Kazushi
  • Journal of the Chemical Society, Chemical Communications, Issue 18
  • DOI: 10.1039/c39880001259

Self-metathesis of 1-butene to propene over SBA-15-supported WO 3
journal, January 2016

  • Chen, Gang; Dong, Mei; Li, Junfen
  • Catalysis Science & Technology, Vol. 6, Issue 14
  • DOI: 10.1039/C6CY00248J

Enhanced Olefin Metathesis Performance of Tungsten and Niobium Incorporated Bimetallic Silicates: Evidence of Synergistic Effects
journal, April 2020

  • Wu, Jian‐Feng; Ramanathan, Anand; Kersting, Reinhard
  • ChemCatChem, Vol. 12, Issue 7
  • DOI: 10.1002/cctc.201902131

Direct Preparation of Thermally Stable Sn-Incorporated SBA-15 Mesoporous Materials in the Self-Generated Acidic Environment
journal, July 2009

  • Chen, Shih-Yuan; Tsai, Huai-De; Chuang, Wei-Tsung
  • The Journal of Physical Chemistry C, Vol. 113, Issue 34
  • DOI: 10.1021/jp9016129

The enhanced activity of Sb after supporting on K10 in the benzylation of benzene using benzyl chloride and benzyl alcohol
journal, February 2001

Synthesis of glycerol carbonate from glycerol and urea over tin-tungsten mixed oxide catalysts
journal, January 2014

One-pot synthesis of mesoporous ZrPW solid acid catalyst for liquid phase benzylation of anisole
journal, January 2014

  • Miao, Zhichao; Song, Huanling; Zhao, Huahua
  • Catal. Sci. Technol., Vol. 4, Issue 3
  • DOI: 10.1039/C3CY00918A

Characterizations of tin (SnO2) doped KIT-5 by direct synthesis
journal, March 2015