Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication

Jiang, Jing; Wang, Yu; Jin, Lun; Hsu, Chih-Hao; Zhang, Shuailin; Mao, Jialin; Yin, Wenbin; Li, Tao; Ni, Bo; Su, Zebin; Huang, Jiahao; Wesdemiotis, Chrys; Yue, Kan; Zhang, Wei; Cheng, Stephen Z. D.

doi:10.1021/acsanm.0c00231

Title: Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication

Abstract

Controlled assembly of nanoscale building blocks is a promising approach to obtain functional materials with unique properties. In this paper, we report a way to manipulate the supramolecular structures of giant molecules based on discotic triangle cores and isobutyl polyhedral oligomeric silsesquioxanes (BPOSS) nanoparticles (NPs). It is found that depending upon the number of BPOSS at the periphery of the discotic cores, the packing of these nanoscale components (discotic core and POSS) could be manipulated into either cylindrical or Frank–Kasper (F–K) A15 ($$Pm\overline 3n$$) phases. The formation of these supramolecular nanostructures is mandated by the balance between the stacking of the discotic cores and the steric hindrance effect of the BPOSS NPs. This strategy to manipulate the packing of nanoscale building blocks for different supramolecular nanostructures including the fabrication of cylindrical structures and A15 ($$Pm\overline 3n$$) phases may be extended to other nanoscale building blocks for future development of materials with complex structures as well as tailored functionalities and properties.

Authors:

Jiang, Jing ^[1];

^[1]; Jin, Lun ^[1]; Hsu, Chih-Hao ^[1]; Zhang, Shuailin ^[1];

^[1]; Yin, Wenbin ^[1]; Li, Tao ^[2]; Ni, Bo ^[1]; Su, Zebin ^[1]; Huang, Jiahao ^[1];

^[1]; Yue, Kan ^[3];

^[1];

^[4]

Univ. of Akron, OH (United States)
Argonne National Lab. (ANL), Lemont, IL (United States). Advanced Photon Source (APS); Northern Illinois Univ., DeKalb, IL (United States)
South China Univ. of Technology, Guangzhou (China)
Univ. of Akron, OH (United States); South China Univ. of Technology, Guangzhou (China)

Publication Date:: Tue Feb 11 00:00:00 EST 2020

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Org.:: National Science Foundation (NSF); USDOE Office of Science (SC)

OSTI Identifier:: 1642552

Grant/Contract Number:: AC02-06CH11357; DMR-1408872; CHE-1808115

Resource Type:: Accepted Manuscript

Journal Name:: ACS Applied Nano Materials

Additional Journal Information:: Journal Volume: 3; Journal Issue: 3; Journal ID: ISSN 2574-0970

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Frank-Kasper phase; POSS; nanoparticles; self-assembly; supramolecular chemistry

Citation Formats


                    Jiang, Jing, Wang, Yu, Jin, Lun, Hsu, Chih-Hao, Zhang, Shuailin, Mao, Jialin, Yin, Wenbin, Li, Tao, Ni, Bo, Su, Zebin, Huang, Jiahao, Wesdemiotis, Chrys, Yue, Kan, Zhang, Wei, and Cheng, Stephen Z. D. Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication.  United States: N. p., 2020. 
Web.  doi:10.1021/acsanm.0c00231.

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                    Jiang, Jing, Wang, Yu, Jin, Lun, Hsu, Chih-Hao, Zhang, Shuailin, Mao, Jialin, Yin, Wenbin, Li, Tao, Ni, Bo, Su, Zebin, Huang, Jiahao, Wesdemiotis, Chrys, Yue, Kan, Zhang, Wei, & Cheng, Stephen Z. D. Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication.  United States.  https://doi.org/10.1021/acsanm.0c00231

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                    Jiang, Jing, Wang, Yu, Jin, Lun, Hsu, Chih-Hao, Zhang, Shuailin, Mao, Jialin, Yin, Wenbin, Li, Tao, Ni, Bo, Su, Zebin, Huang, Jiahao, Wesdemiotis, Chrys, Yue, Kan, Zhang, Wei, and Cheng, Stephen Z. D. Tue .  
"Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication".  United States.  https://doi.org/10.1021/acsanm.0c00231.  https://www.osti.gov/servlets/purl/1642552.

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@article{osti_1642552,

  title        = {Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication},

  author       = {Jiang, Jing and Wang, Yu and Jin, Lun and Hsu, Chih-Hao and Zhang, Shuailin and Mao, Jialin and Yin, Wenbin and Li, Tao and Ni, Bo and Su, Zebin and Huang, Jiahao and Wesdemiotis, Chrys and Yue, Kan and Zhang, Wei and Cheng, Stephen Z. D.},

  abstractNote = {Controlled assembly of nanoscale building blocks is a promising approach to obtain functional materials with unique properties. In this paper, we report a way to manipulate the supramolecular structures of giant molecules based on discotic triangle cores and isobutyl polyhedral oligomeric silsesquioxanes (BPOSS) nanoparticles (NPs). It is found that depending upon the number of BPOSS at the periphery of the discotic cores, the packing of these nanoscale components (discotic core and POSS) could be manipulated into either cylindrical or Frank–Kasper (F–K) A15 ($Pm\overline 3n$) phases. The formation of these supramolecular nanostructures is mandated by the balance between the stacking of the discotic cores and the steric hindrance effect of the BPOSS NPs. This strategy to manipulate the packing of nanoscale building blocks for different supramolecular nanostructures including the fabrication of cylindrical structures and A15 ($Pm\overline 3n$) phases may be extended to other nanoscale building blocks for future development of materials with complex structures as well as tailored functionalities and properties.},

  doi          = {10.1021/acsanm.0c00231},

  journal      = {ACS Applied Nano Materials},

  number       = 3,

  volume       = 3,

  place        = {United States},

  year         = {Tue Feb 11 00:00:00 EST 2020},

  month        = {Tue Feb 11 00:00:00 EST 2020}

}

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Topology Controlled Supramolecular Self-Assembly of Octa Triphenylene-Substituted Polyhedral Oligomeric Silsesquioxane Hybrid Supermolecules

Journal Article Miao, J ; Zhu, L - Journal of Physical Chemistry B

A series of liquid crystalline star supermolecules with polyhedral oligomeric silsesquioxane (POSS) as the central scaffold and eight triphenylenes (Tp) as the peripheral arms were synthesized via amidization reactions. The supermolecules were denoted as POSS(Tp){sub 8}. Six POSS(Tp){sub 8} samples were prepared with two alkyl chain lengths in the Tp (C{sub 5} and C{sub 12}) and three spacer lengths (C{sub 2}, C{sub 6}, and C{sub 10}) between the POSS core and the Tp arms. Three samples with C{sub 5}-Tp were amorphous because of too short alkyl chains in the Tp, while the other three samples with C{sub 12}-Tp self-assembled intomore »« less
https://doi.org/10.1021/jp910053e

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Title: Modularly Constructed Polyhedral Oligomeric Silsesquioxane-Based Giant Molecules for Unconventional Nanostructure Fabrication

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journal, May 2012

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journal, January 2016

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journal, February 2019

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journal, February 2001

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journal, March 2006

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journal, December 2009

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journal, November 2009

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journal, August 2010

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journal, January 1998

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journal, January 2015

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journal, December 2016

Dendronized Poly(2-oxazoline) Displays within only Five Monomer Repeat Units Liquid Quasicrystal, A15 and σ Frank–Kasper Phases
journal, November 2018

Discovery of a Frank-Kasper Phase in Sphere-Forming Block Copolymer Melts
journal, October 2010

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journal, November 2014

Thermal processing of diblock copolymer melts mimics metallurgy
journal, May 2017

Inverse Pm3̄n cubic micellar lyotropic phases from zwitterionic triazolium gemini surfactants
journal, January 2013

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journal, March 2018

Counterion-Dependent Access to Low-Symmetry Lyotropic Sphere Packings of Ionic Surfactant Micelles
journal, January 2018

Path-Dependent Preparation of Complex Micelle Packings of a Hydrated Diblock Oligomer
journal, February 2019

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journal, April 2015

Geometry induced sequence of nanoscale Frank–Kasper and quasicrystal mesophases in giant surfactants
journal, November 2016

Identification of a Frank–Kasper Z phase from shape amphiphile self-assembly
journal, September 2019

Rational Design of the First Spherical Supramolecular Dendrimers Self-Organized in a Novel Thermotropic Cubic Liquid-Crystalline Phase and the Determination of Their Shape by X-ray Analysis
journal, February 1997

Direct Visualization of Individual Cylindrical and Spherical Supramolecular Dendrimers
journal, October 1997

Structural Analysis of Cylindrical and Spherical Supramolecular Dendrimers Quantifies the Concept of Monodendron Shape Control by Generation Number
journal, November 1998

Design and Structural Analysis of the First Spherical Monodendron Self-Organizable in a Cubic Lattice
journal, May 2000

Heat-Shrinking Spherical and Columnar Supramolecular Dendrimers: Their Interconversion and Dependence of Their Shape on Molecular Taper Angle
journal, April 2000

Hollow Spherical Supramolecular Dendrimers
journal, October 2008

Giant Supramolecular Liquid Crystal Lattice
journal, February 2003

Supramolecular dendritic liquid quasicrystals
journal, March 2004

Liquid Quasicrystals
journal, November 2011

A Systematic Framework and Nanoperiodic Concept for Unifying Nanoscience: Hard/Soft Nanoelements, Superatoms, Meta-Atoms, New Emerging Properties, Periodic Property Patterns, and Predictive Mendeleev-like Nanoperiodic Tables
journal, January 2016

Efficiency of Various Lattices from Hard Ball to Soft Ball: Theoretical Study of Thermodynamic Properties of Dendrimer Liquid Crystal from Atomistic Simulation
journal, February 2004

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journal, December 2011

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journal, September 2016

FCC ↔ BCC Phase Transitions in Convex and Concave Hard Particle Systems
journal, September 2019

Soap Froths and Crystal Structures
journal, October 2000

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journal, October 2001

The packing of soft materials: Molecular asymmetry, geometric frustration and optimal lattices in block copolymer melts
journal, October 2006

σ Phase Formed in Conformationally Asymmetric AB-Type Block Copolymers
journal, August 2014

Nonclassical Spherical Packing Phases Self-Assembled from AB-Type Block Copolymers
journal, October 2017

Stability of the A15 phase in diblock copolymer melts
journal, June 2019

Molecular Nanoparticles Are Unique Elements for Macromolecular Science: From “Nanoatoms” to Giant Molecules
journal, January 2014

Manipulation of Self-Assembled Nanostructure Dimensions in Molecular Janus Particles
journal, June 2016

Tunable Affinity and Molecular Architecture Lead to Diverse Self-Assembled Supramolecular Structures in Thin Films
journal, December 2015

Rationally Controlling the Self-Assembly Behavior of Triarmed POSS–Organic Hybrid Macromolecules: From Giant Surfactants to Macroions
journal, June 2017

Toward Controlled Hierarchical Heterogeneities in Giant Molecules with Precisely Arranged Nano Building Blocks
journal, January 2016

Sequence-Mandated, Distinct Assembly of Giant Molecules
journal, October 2017

Multilevel Manipulation of Supramolecular Structures of Giant Molecules via Macromolecular Composition and Sequence
journal, May 2018

Cooperative Supramolecular Polymerization and Amplification of Chirality in C ₃ ‐Symmetrical OPE‐Based Trisamides
journal, May 2011

Hydrogen Bonding Directed Supramolecular Polymerisation of Oligo(Phenylene-Ethynylene)s: Cooperative Mechanism, Core Symmetry Effect and Chiral Amplification
journal, August 2012

Sequential phase transformation of propeller-like C ₃ -symmetric liquid crystals from a helical to ordered to disordered hexagonal columnar structure
journal, January 2015

Increasing the Diameter of Cylindrical and Spherical Supramolecular Dendrimers by Decreasing the Solid Angle of Their Monodendrons via Periphery Functionalization
journal, October 2000

Self-Assembly of Dendritic Crowns into Chiral Supramolecular Spheres
journal, January 2009

Self-Assembly of Dendronized Triphenylenes into Helical Pyramidal Columns and Chiral Spheres
journal, June 2009

Hierarchical Self-Organization of Perylene Bisimides into Supramolecular Spheres and Periodic Arrays Thereof
journal, October 2016

Tetrahedral Arrangements of Perylene Bisimide Columns via Supramolecular Orientational Memory
journal, January 2017

Elucidating the Structure of the Pm $\bar 3$ n Cubic Phase of Supramolecular Dendrimers through the Modification of their Aliphatic to Aromatic Volume Ratio
journal, September 2009

Self-Assembly of Hybrid Dendrons into Doubly Segregated Supramolecular Polyhedral Columns and Vesicles
journal, August 2010

A counter-example to Kelvin's conjecture on minimal surfaces
journal, February 1994

Particle analogs of electrons in colloidal crystals
journal, June 2019

Complex Arrangement of Orthogonal Nanoscale Columns via a Supramolecular Orientational Memory Effect
journal, November 2016

Hierarchical Self-Organization of Chiral Columns from Chiral Supramolecular Spheres
journal, September 2018