skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries

Authors:
; ; ; ORCiD logo; ; ORCiD logo; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1640280
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Name: Journal of Power Sources Journal Volume: 473 Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
Netherlands
Language:
English

Citation Formats

Li, Weikang, Cho, Yoon-Gyo, Yao, Weiliang, Li, Yixuan, Cronk, Ashley, Shimizu, Ryosuke, Schroeder, Marshall A., Fu, Yanbao, Zou, Feng, Battaglia, Vince, Manthiram, Arumugam, Zhang, Minghao, and Meng, Ying Shirley. Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries. Netherlands: N. p., 2020. Web. https://doi.org/10.1016/j.jpowsour.2020.228579.
Li, Weikang, Cho, Yoon-Gyo, Yao, Weiliang, Li, Yixuan, Cronk, Ashley, Shimizu, Ryosuke, Schroeder, Marshall A., Fu, Yanbao, Zou, Feng, Battaglia, Vince, Manthiram, Arumugam, Zhang, Minghao, & Meng, Ying Shirley. Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries. Netherlands. https://doi.org/10.1016/j.jpowsour.2020.228579
Li, Weikang, Cho, Yoon-Gyo, Yao, Weiliang, Li, Yixuan, Cronk, Ashley, Shimizu, Ryosuke, Schroeder, Marshall A., Fu, Yanbao, Zou, Feng, Battaglia, Vince, Manthiram, Arumugam, Zhang, Minghao, and Meng, Ying Shirley. Thu . "Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries". Netherlands. https://doi.org/10.1016/j.jpowsour.2020.228579.
@article{osti_1640280,
title = {Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries},
author = {Li, Weikang and Cho, Yoon-Gyo and Yao, Weiliang and Li, Yixuan and Cronk, Ashley and Shimizu, Ryosuke and Schroeder, Marshall A. and Fu, Yanbao and Zou, Feng and Battaglia, Vince and Manthiram, Arumugam and Zhang, Minghao and Meng, Ying Shirley},
abstractNote = {},
doi = {10.1016/j.jpowsour.2020.228579},
journal = {Journal of Power Sources},
number = C,
volume = 473,
place = {Netherlands},
year = {2020},
month = {10}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.jpowsour.2020.228579

Save / Share:

Works referenced in this record:

Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density
journal, January 2018

  • Wang, Longlong; Chen, Bingbing; Ma, Jun
  • Chemical Society Reviews, Vol. 47, Issue 17
  • DOI: 10.1039/C8CS00322J

Nanoscale Phase Separation, Cation Ordering, and Surface Chemistry in Pristine Li 1.2 Ni 0.2 Mn 0.6 O 2 for Li-Ion Batteries
journal, May 2013

  • Gu, Meng; Genc, Arda; Belharouak, Ilias
  • Chemistry of Materials, Vol. 25, Issue 11
  • DOI: 10.1021/cm4009392

A Bottom-Up Approach to Lithium-Ion Battery Cost Modeling with a Focus on Cathode Active Materials
journal, February 2019

  • Wentker, Marc; Greenwood, Matthew; Leker, Jens
  • Energies, Vol. 12, Issue 3
  • DOI: 10.3390/en12030504

Cobalt in lithium-ion batteries
journal, February 2020


Cobalt-Free Nickel-Rich Positive Electrode Materials with a Core–Shell Structure
journal, November 2019


Is Cobalt Needed in Ni-Rich Positive Electrode Materials for Lithium Ion Batteries?
journal, January 2019

  • Li, Hongyang; Cormier, Marc; Zhang, Ning
  • Journal of The Electrochemical Society, Vol. 166, Issue 4
  • DOI: 10.1149/2.1381902jes

Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014


Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials
journal, April 2018


Design principles for high transition metal capacity in disordered rocksalt Li-ion cathodes
journal, January 2018

  • Kitchaev, Daniil A.; Lun, Zhengyan; Richards, William D.
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE00816G

Simultaneously fabricating homogeneous nanostructured ionic and electronic pathways for layered lithium-rich oxides
journal, October 2018


Performance and design considerations for lithium excess layered oxide positive electrode materials for lithium ion batteries
journal, January 2016

  • Hy, Sunny; Liu, Haodong; Zhang, Minghao
  • Energy & Environmental Science, Vol. 9, Issue 6
  • DOI: 10.1039/C5EE03573B

Comparative study of different crystallographic structure of LiNi0.5Mn1.5O4−δ cathodes with wide operation voltage (2.0–5.0V)
journal, September 2007


A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries
journal, May 2018


Understanding the Capacity Loss in LiNi 0.5 Mn 1.5 O 4 –Li 4 Ti 5 O 12 Lithium-Ion Cells at Ambient and Elevated Temperatures
journal, May 2018

  • Aktekin, Burak; Lacey, Matthew J.; Nordh, Tim
  • The Journal of Physical Chemistry C, Vol. 122, Issue 21
  • DOI: 10.1021/acs.jpcc.8b02204

Higher, Stronger, Better…︁ A Review of 5 Volt Cathode Materials for Advanced Lithium-Ion Batteries
journal, June 2012


Overcoming the Challenges of 5 V Spinel LiNi 0.5 Mn 1.5 O 4 Cathodes with Solid Polymer Electrolytes
journal, October 2019


Thick Electrode Batteries: Principles, Opportunities, and Challenges
journal, July 2019

  • Kuang, Yudi; Chen, Chaoji; Kirsch, Dylan
  • Advanced Energy Materials, Vol. 9, Issue 33
  • DOI: 10.1002/aenm.201901457

Synergistic Effect of Partially Fluorinated Ether and Fluoroethylene Carbonate for High-Voltage Lithium-Ion Batteries with Rapid Chargeability and Dischargeability
journal, December 2017

  • Kim, Choon-Ki; Kim, Koeun; Shin, Kyomin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 50
  • DOI: 10.1021/acsami.7b12352

Lithium Bis(2,2,2-trifluoroethyl)phosphate Li[O 2 P(OCH 2 CF 3 ) 2 ]: A High Voltage Additive for LNMO/Graphite Cells
journal, January 2018

  • Milien, Mickdy S.; Beyer, Hans; Beichel, Witali
  • Journal of The Electrochemical Society, Vol. 165, Issue 11
  • DOI: 10.1149/2.0541811jes

Additives for Cycle Life Improvement of High‐Voltage LNMO‐Based Li‐Ion Cells
journal, October 2019

  • Hofmann, Andreas; Höweling, Andres; Bohn, Nicole
  • ChemElectroChem, Vol. 6, Issue 20
  • DOI: 10.1002/celc.201901120

Electrochemical Cross-Talk Leading to Gas Evolution and Capacity Fade in LiNi 0.5 Mn 1.5 O 4 /Graphite Full-Cells
journal, December 2016

  • Michalak, Barbara; Berkes, Balázs B.; Sommer, Heino
  • The Journal of Physical Chemistry C, Vol. 121, Issue 1
  • DOI: 10.1021/acs.jpcc.6b11184

Lithium malonatoborate additives enabled stable cycling of 5 V lithium metal and lithium ion batteries
journal, October 2017


A High-Voltage and High-Capacity Li 1+ x Ni 0.5 Mn 1.5 O 4 Cathode Material: From Synthesis to Full Lithium-Ion Cells
journal, June 2016

  • Mancini, Marilena; Axmann, Peter; Gabrielli, Giulio
  • ChemSusChem, Vol. 9, Issue 14
  • DOI: 10.1002/cssc.201600365

Lithium Oxalate as Capacity and Cycle-Life Enhancer in LNMO/Graphite and LNMO/SiG Full Cells
journal, January 2018

  • Solchenbach, Sophie; Wetjen, Morten; Pritzl, Daniel
  • Journal of The Electrochemical Society, Vol. 165, Issue 3
  • DOI: 10.1149/2.0611803jes

Graphite//LiNi 0.5 Mn 1.5 O 4 Cells Based on Environmentally Friendly Made-in-Water Electrodes
journal, December 2016

  • De Giorgio, Francesca; Laszczynski, Nina; von Zamory, Jan
  • ChemSusChem, Vol. 10, Issue 2
  • DOI: 10.1002/cssc.201601249

Evidence of loss of active lithium in titanium-doped LiNi0.5Mn1.5O4/graphite cells
journal, January 2015


Tris(pentafluorophenyl)silane as an Electrolyte Additive for 5 V LiNi 0.5 Mn 1.5 O 4 Positive Electrode
journal, January 2016

  • Lee, Tae Jin; Lee, Jeong Beom; Yoon, Taeho
  • Journal of The Electrochemical Society, Vol. 163, Issue 6
  • DOI: 10.1149/2.0501606jes

Fluorinated electrolytes for 5-V Li-ion chemistry: Dramatic enhancement of LiNi0.5Mn1.5O4/graphite cell performance by a lithium reservoir
journal, July 2014


A multifunctional phosphite-containing electrolyte for 5 V-class LiNi 0.5 Mn 1.5 O 4 cathodes with superior electrochemical performance
journal, January 2014

  • Song, Young-Min; Han, Jung-Gu; Park, Soojin
  • J. Mater. Chem. A, Vol. 2, Issue 25
  • DOI: 10.1039/C4TA01129E

GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013


LixNi0.25Mn0.75Oy (0.5 ≤x≤ 2, 2 ≤y≤ 2.75) compounds for high-energy lithium-ion batteries
journal, January 2009

  • Deng, Haixia; Belharouak, Ilias; Sun, Yang-Kook
  • Journal of Materials Chemistry, Vol. 19, Issue 26
  • DOI: 10.1039/b904098f

Principal Factors of Carbon Conductive Agents that Contribute to the Gas Formation in High-Voltage Cathode Systems
journal, January 2015

  • Kajiyama, Akihisa; Masaki, Ryuta; Wakiyama, Tsuyoshi
  • Journal of The Electrochemical Society, Vol. 162, Issue 8
  • DOI: 10.1149/2.0571508jes

Failure mechanisms of LiNi0.5Mn1.5O4 electrode at elevated temperature
journal, October 2012


Effects of cell positive cans and separators on the performance of high-voltage Li-ion batteries
journal, September 2012


Polyacrylonitrile-polyvinylidene fluoride as high-performance composite binder for layered Li-rich oxides
journal, August 2017


Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox
journal, December 2017


Identification of LiNi0.5Mn1.5O4 spinel in layered manganese enriched electrode materials
journal, March 2011

  • Belharouak, Ilias; Koenig, Gary M.; Ma, Jiwei
  • Electrochemistry Communications, Vol. 13, Issue 3, p. 232-236
  • DOI: 10.1016/j.elecom.2010.12.021

How lithium dendrites form in liquid batteries
journal, October 2019


Understanding the capacity fading mechanism in LiNi0.5Mn1.5O4/graphite Li-ion batteries
journal, February 2013