Photo–thermo Catalytic Oxidation over a TiO2-WO3-Supported Platinum Catalyst

Kang, Leilei; Liu, Xiao Yan; Wang, Aiqin; Li, Lin; Ren, Yujing; Li, Xiaoyu; Pan, Xiaoli; Li, Yuanyuan; Zong, Xu; Liu, Hua; Frenkel, Anatoly I.; Zhang, Tao

doi:10.1002/ange.202001701

Title: Photo–thermo Catalytic Oxidation over a TiO₂-WO₃-Supported Platinum Catalyst

Journal Article · 05 April 2020 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202001701 · OSTI ID:1637654

Kang, Leilei ^[1];

^[1]; Wang, Aiqin ^[1]; Li, Lin ^[1]; Ren, Yujing ^[2]; Li, Xiaoyu ^[2]; Pan, Xiaoli ^[1]; Li, Yuanyuan ^[3]; Zong, Xu ^[1]; Liu, Hua ^[2];

^[4]; Zhang, Tao ^[2]

Chinese Academy of Sciences (CAS), Dalian (China)
Chinese Academy of Sciences (CAS), Dalian (China); Chinese Academy of Sciences (CAS), Beijing (China)
Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)

Photo–thermo catalysis, which integrates photocatalysis on semiconductors with thermocatalysis on supported nonplasmonic metals, has emerged as an attractive approach to improve catalytic performance. However, an understanding of the mechanisms in operation is missing from both the thermo- and photocatalytic perspectives. Deep insights into photo–thermo catalysis are achieved via the catalytic oxidation of propane (C₃H₈) over a Pt/TiO₂-WO₃ catalyst that severely suffers from oxygen poisoning at high O₂/C₃H₈ ratios. After introducing UV/Vis light, the reaction temperature required to achieve 70 % conversion of C₃H₈ lowers to a record-breaking 90 °C from 324 °C and the apparent activation energy drops from 130 kJ mol^-1 to 11 kJ mol^-1. Furthermore, the reaction order of O₂ is -1.4 in dark but reverses to 0.1 under light, thereby suppressing oxygen poisoning of the Pt catalyst. An underlying mechanism is proposed based on direct evidence of the in-situ-captured reaction intermediates.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; FG02-03ER15476

OSTI ID:: 1637654

Alternate ID(s):: OSTI ID: 1631337

Report Number(s):: BNL-216121-2020-JAAM; 1521-3757

Journal Information:: Angewandte Chemie, Vol. 132, Issue 31; ISSN 0044-8249

Publisher:: German Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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