An investigation of the microstructure and ductility of annealed cold-rolled tungsten
Abstract
Tungsten is notoriously brittle metal at room temperature. Furthermore, contrary to most metals, plastic deformation increases ductility and recrystallization decreases ductility of tungsten. The fundamentals that govern this behavior have challenged academia and industry for decades. This paper focuses on understanding the controlling factors of ductility through a systematic investigation of the changes in microstructure and mechanical properties of cold-rolled tungsten that occur during annealing. Cold-rolled tungsten samples were annealed at temperatures up to 1400 °C, and mechanical testing and microstructural analysis was performed before and after annealing. Furthermore, a dislocation mobility model based on the Orowan equation was applied. The mechanisms of deformation are discussed within the context of deformed and annealed microstructures. The high fraction of low angle grain boundaries and high density of edge dislocations were found to be the most important factors for ductility. Although there were gradual changes in microstructure and mechanical properties, the ductility of cold-rolled tungsten was maintained up to 1300 °C. The material recrystallized when annealed above this temperature, had no ductility, and suffered brittle fracture. Microstructural characterizations of the as-rolled material revealed a typical BCC texture, with grains elongated in rolling direction and a large amount of edge dislocations and lowmore »
- Authors:
-
- Univ. of Utah, Salt Lake City, UT (United States)
- Army Research Lab., Aberdeen, MD (United States)
- Univ. of Utah, Salt Lake City, UT (United States); Army Research Lab., Aberdeen, MD (United States)
- Publication Date:
- Research Org.:
- Univ. of Utah, Salt Lake City, UT (United States); Heavystone Lab., LLC, Park City, UT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1611116
- Alternate Identifier(s):
- OSTI ID: 1636963
- Grant/Contract Number:
- SC0008673; SC0017772; DESC0008673; DESC0017772; W15QKN-13-C-0068; W15QKN-15-C-0038; DMR-1121252
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 162; Journal Issue: C; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Materials Science; Metallurgy & Metallurgical Engineering; Tungsten; Ductility; Microstructure; Mechanical properties; Annealing
Citation Formats
Ren, Chai, Fang, Z. Zak, Xu, Lei, Ligda, Jonathan P., Paramore, James D., and Butler, Brady G. An investigation of the microstructure and ductility of annealed cold-rolled tungsten. United States: N. p., 2018.
Web. doi:10.1016/j.actamat.2018.10.002.
Ren, Chai, Fang, Z. Zak, Xu, Lei, Ligda, Jonathan P., Paramore, James D., & Butler, Brady G. An investigation of the microstructure and ductility of annealed cold-rolled tungsten. United States. https://doi.org/10.1016/j.actamat.2018.10.002
Ren, Chai, Fang, Z. Zak, Xu, Lei, Ligda, Jonathan P., Paramore, James D., and Butler, Brady G. Wed .
"An investigation of the microstructure and ductility of annealed cold-rolled tungsten". United States. https://doi.org/10.1016/j.actamat.2018.10.002. https://www.osti.gov/servlets/purl/1611116.
@article{osti_1611116,
title = {An investigation of the microstructure and ductility of annealed cold-rolled tungsten},
author = {Ren, Chai and Fang, Z. Zak and Xu, Lei and Ligda, Jonathan P. and Paramore, James D. and Butler, Brady G.},
abstractNote = {Tungsten is notoriously brittle metal at room temperature. Furthermore, contrary to most metals, plastic deformation increases ductility and recrystallization decreases ductility of tungsten. The fundamentals that govern this behavior have challenged academia and industry for decades. This paper focuses on understanding the controlling factors of ductility through a systematic investigation of the changes in microstructure and mechanical properties of cold-rolled tungsten that occur during annealing. Cold-rolled tungsten samples were annealed at temperatures up to 1400 °C, and mechanical testing and microstructural analysis was performed before and after annealing. Furthermore, a dislocation mobility model based on the Orowan equation was applied. The mechanisms of deformation are discussed within the context of deformed and annealed microstructures. The high fraction of low angle grain boundaries and high density of edge dislocations were found to be the most important factors for ductility. Although there were gradual changes in microstructure and mechanical properties, the ductility of cold-rolled tungsten was maintained up to 1300 °C. The material recrystallized when annealed above this temperature, had no ductility, and suffered brittle fracture. Microstructural characterizations of the as-rolled material revealed a typical BCC texture, with grains elongated in rolling direction and a large amount of edge dislocations and low angle grain boundaries. The level of texturing and the fraction of low angle grain boundaries diminished after recrystallization. It was found that, compared to the recrystallized material, as-rolled tungsten can accommodate over 7 orders of magnitude higher deformation velocity due to the high density of edge dislocations.},
doi = {10.1016/j.actamat.2018.10.002},
journal = {Acta Materialia},
number = C,
volume = 162,
place = {United States},
year = {Wed Oct 10 00:00:00 EDT 2018},
month = {Wed Oct 10 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Anomalous {110} slip in high-purity molybdenum single crystals and its comparison with that in V(a) metals
journal, August 1976
- Matsui, H.; Kimura, H.
- Materials Science and Engineering, Vol. 24, Issue 2
High temperature fracture experiments on tungsten–rhenium alloys
journal, November 2010
- Wurster, Stefan; Gludovatz, Bernd; Pippan, Reinhard
- International Journal of Refractory Metals and Hard Materials, Vol. 28, Issue 6
Recrystallization, grain growth and the ductile-brittle transition in tungsten sheet
journal, August 1967
- Farrell, K.; Schaffhauser, A. C.; Stiegler, J. O.
- Journal of the Less Common Metals, Vol. 13, Issue 2
Independent slip systems in crystals
journal, May 1963
- Groves, G. W.; Kelly, A.
- Philosophical Magazine, Vol. 8, Issue 89
Plastic flow localization in bulk tungsten with ultrafine microstructure
journal, March 2005
- Wei, Q.; Ramesh, K. T.; Ma, E.
- Applied Physics Letters, Vol. 86, Issue 10
Effect of low-temperature rolling on the tensile behavior of commercially pure tungsten
journal, September 2008
- Wei, Q.; Kecskes, L. J.
- Materials Science and Engineering: A, Vol. 491, Issue 1-2
Atomistic simulations of interactions between the 1 / 2⟨111⟩ edge dislocation and symmetric tilt grain boundaries in tungsten
journal, February 2008
- Cheng, Y.; Mrovec, M.; Gumbsch, P.
- Philosophical Magazine, Vol. 88, Issue 4
Plastic deformation of tungsten single crystals at low temperatures
journal, November 1966
- Argon, A. S.; Maloof, S. R.
- Acta Metallurgica, Vol. 14, Issue 11
Solution softening mechanism of iridium and rhenium in tungsten at room temperature
journal, January 1991
- Luo, A.; Jacobson, D. L.; Shin, K. S.
- International Journal of Refractory Metals and Hard Materials, Vol. 10, Issue 2
AnIn Situ transmission electron microscope deformation study of the slip transfer mechanisms in metals
journal, September 1990
- Lee, T. C.; Robertson, I. M.; Birnbaum, H. K.
- Metallurgical Transactions A, Vol. 21, Issue 9
Fracture toughness of polycrystalline tungsten alloys
journal, November 2010
- Gludovatz, B.; Wurster, S.; Hoffmann, A.
- International Journal of Refractory Metals and Hard Materials, Vol. 28, Issue 6
Ductile versus brittle behaviour of crystals
journal, January 1974
- Rice, James R.; Thomson, Robb
- The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, Vol. 29, Issue 1
The influence of carbon and oxygen in the grain boundary on the brittle-ductile transition temperature of tungsten Bi-crystals
journal, July 1984
- Smiti, E.; Jouffrey, P.; Kobylanski, A.
- Scripta Metallurgica, Vol. 18, Issue 7
Mechanik der plastischen Formänderung von Kristallen
journal, January 1928
- Mises, R. V.
- ZAMM - Zeitschrift für Angewandte Mathematik und Mechanik, Vol. 8, Issue 3
Texture evolution and basic thermal–mechanical properties of pure tungsten under various rolling reductions
journal, January 2016
- Zhang, Xiaoxin; Yan, Qingzhi; Lang, Shaoting
- Journal of Nuclear Materials, Vol. 468
Slip transfer and dislocation nucleation processes in multiphase ordered Ni-Fe-Al alloys
journal, April 1999
- Misra, A.; Gibala, R.
- Metallurgical and Materials Transactions A, Vol. 30, Issue 4
Thermal stability of a highly-deformed warm-rolled tungsten plate in the temperature range 1100–1250 °C
journal, October 2015
- Alfonso, A.; Juul Jensen, D.; Luo, G. -N.
- Fusion Engineering and Design, Vol. 98-99
W–2wt.%Y2O3 composite: Microstructure and mechanical properties
journal, March 2012
- Battabyal, M.; Schäublin, R.; Spätig, P.
- Materials Science and Engineering: A, Vol. 538
Anomalous slip in high-purity niobium single crystals deformed at 77°K in tension
journal, December 1972
- Bolton, C. J.; Taylor, G.
- Philosophical Magazine, Vol. 26, Issue 6
Influence of impurities on the fracture behaviour of tungsten
journal, August 2011
- Gludovatz, B.; Wurster, S.; Weingärtner, T.
- Philosophical Magazine, Vol. 91, Issue 22
The study on low temperature sintering of nano-tungsten powders
journal, December 2016
- Ren, Chai; Fang, Z. Zak; Zhang, Huan
- International Journal of Refractory Metals and Hard Materials, Vol. 61
The Observation and Interpretation of Dislocation Tangles in the Easy Glide Range of Aluminum
journal, May 1962
- Wilsdorf, H. G. F.; Schmitz, J.
- Journal of Applied Physics, Vol. 33, Issue 5
Fracture toughness and microstructural characterization of polycrystalline rolled tungsten
journal, November 2010
- Rupp, D.; Mönig, R.; Gruber, P.
- International Journal of Refractory Metals and Hard Materials, Vol. 28, Issue 6
Slip planes in bcc transition metals
journal, June 2013
- Weinberger, C. R.; Boyce, B. L.; Battaile, C. C.
- International Materials Reviews, Vol. 58, Issue 5
Microstructure and impact properties of ultra-fine grained tungsten alloys dispersed with TiC
journal, May 1999
- Kitsunai, Yuji; Kurishita, Hiroaki; Kayano, Hideo
- Journal of Nuclear Materials, Vol. 271-272
Multiscale modeling of plastic deformation of molybdenum and tungsten: I. Atomistic studies of the core structure and glide of 1/2〈111〉 screw dislocations at 0K
journal, November 2008
- Gröger, R.; Bailey, A. G.; Vitek, V.
- Acta Materialia, Vol. 56, Issue 19
Recrystallization kinetics of warm-rolled tungsten in the temperature range 1150–1350 °C
journal, December 2014
- Alfonso, A.; Juul Jensen, D.; Luo, G. -N.
- Journal of Nuclear Materials, Vol. 455, Issue 1-3
Microstructure and mechanical properties of super-strong nanocrystalline tungsten processed by high-pressure torsion
journal, September 2006
- Wei, Q.; Zhang, H.; Schuster, B.
- Acta Materialia, Vol. 54, Issue 15
Crack propagation in single crystals of tungsten
journal, November 1965
- Hull, D.; Beardmore, P.; Valintine, A. P.
- The Philosophical Magazine: A Journal of Theoretical Experimental and Applied Physics, Vol. 12, Issue 119
The motion of edge dislocations in body-centered cubic metals
journal, July 1998
- Duesbery, M. S.; Xu, W.
- Scripta Materialia, Vol. 39, Issue 3
Ductilisation of tungsten (W): On the shift of the brittle-to-ductile transition (BDT) to lower temperatures through cold rolling
journal, January 2016
- Reiser, Jens; Hoffmann, Jan; Jäntsch, Ute
- International Journal of Refractory Metals and Hard Materials, Vol. 54
Recrystallization and grain growth induced by ELMs-like transient heat loads in deformed tungsten samples
journal, November 2014
- Suslova, A.; El-Atwani, O.; Sagapuram, D.
- Scientific Reports, Vol. 4, Issue 1
Some surprising features of the plastic deformation of body-centered cubic metals and alloys
journal, July 1983
- Christian, J. W.
- Metallurgical Transactions A, Vol. 14, Issue 7
A study on the sintering of ultrafine grained tungsten with Ti-based additives
journal, June 2017
- Ren, Chai; Koopman, Mark; Zak Fang, Z.
- International Journal of Refractory Metals and Hard Materials, Vol. 65
Cleavage Anisotropy in Tungsten Single Crystals
journal, May 1996
- Riedle, Joachim; Gumbsch, Peter; Fischmeister, Hellmut F.
- Physical Review Letters, Vol. 76, Issue 19
A phenomenological dislocation mobility law for bcc metals
journal, October 2016
- Po, Giacomo; Cui, Yinan; Rivera, David
- Acta Materialia, Vol. 119
Plastic Flow and Fracture of B2 NiAl-based Intermetallic Alloys Containing a Ductile Second Phase.
journal, January 1991
- Noebe, R. D.; Misra, A.; Gibala, R.
- ISIJ International, Vol. 31, Issue 10
Microstructure and tensile properties of tungsten at elevated temperatures
journal, January 2016
- Shen, Tielong; Dai, Yong; Lee, Yongjoong
- Journal of Nuclear Materials, Vol. 468
Mesoscopic Simulation of Dislocation Activity at Crack Tips
journal, January 1998
- Hartmaier, A.; Gumbsch, P.
- MRS Proceedings, Vol. 539
Modelling plastic zones and the brittle-ductile transition
journal, October 1997
- Hirsch, P. B.; Roberts, S. G.
- Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences, Vol. 355, Issue 1731
Dislocation-mediated strain hardening in tungsten: Thermo-mechanical plasticity theory and experimental validation
journal, December 2015
- Terentyev, Dmitry; Xiao, Xiazi; Dubinko, A.
- Journal of the Mechanics and Physics of Solids, Vol. 85
Microstructures and recrystallization behavior of severely hot-deformed tungsten
journal, March 2009
- Mathaudhu, S. N.; deRosset, A. J.; Hartwig, K. T.
- Materials Science and Engineering: A, Vol. 503, Issue 1-2
Ductilisation of tungsten (W) through cold-rolling: R-curve behaviour
journal, August 2016
- Reiser, Jens; Wurster, Stefan; Hoffmann, Jan
- International Journal of Refractory Metals and Hard Materials, Vol. 58
Works referencing / citing this record:
Recent advances in characterising irradiation damage in tungsten for fusion power
journal, November 2019
- Das, Suchandrima
- SN Applied Sciences, Vol. 1, Issue 12
Manufacturing of tungsten and tungsten composites for fusion application via different routes
journal, March 2019
- Wu, Yucheng
- Tungsten, Vol. 1, Issue 1