High-speed photographic study of vaporclouds from wet droplets and the subsequent solid particles in an inductively coupled plasma
Abstract
Movies of an inductively coupled plasma (ICP) while nebulizing a concentrated sample of yttrium were recorded using a high-speed camera with short exposure time (10 μs) and fast framing rate (5000 frames per s). Clouds from large droplets can be seen in several successive frames as they travel downstream in the axial channel of the ICP. These droplet clouds are superimposed on the usual spatial structure of red YO, neutral Y atom and blue Y+ emission. As a particular large droplet moves downstream, its red emission cloud evolves into a faint white streak with a surrounding cloud of blue Y+ emission. The streak is attributed to a solid residue from the droplet. The velocity of the droplet and subsequent particle is measured to be 28 m s-1. The general characteristics of the droplet and particle clouds agree well with previous photographic measurements and those by other methods such as laser induced-fluorescence or scattering.
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA), Office of Defense Nuclear Nonproliferation
- OSTI Identifier:
- 1634871
- Alternate Identifier(s):
- OSTI ID: 1633767
- Report Number(s):
- IS-J-10,244
Journal ID: ISSN 0267-9477; JASPE2
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Published Article
- Journal Name:
- Journal of Analytical Atomic Spectrometry
- Additional Journal Information:
- Journal Name: Journal of Analytical Atomic Spectrometry; Journal ID: ISSN 0267-9477
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
High-speed photographic study of vaporclouds from wet droplets and the subsequent solid particles in an inductively coupled plasma. United Kingdom: N. p., 2020.
Web. doi:10.1039/D0JA00210K.
High-speed photographic study of vaporclouds from wet droplets and the subsequent solid particles in an inductively coupled plasma. United Kingdom. https://doi.org/10.1039/D0JA00210K
Wed .
"High-speed photographic study of vaporclouds from wet droplets and the subsequent solid particles in an inductively coupled plasma". United Kingdom. https://doi.org/10.1039/D0JA00210K.
@article{osti_1634871,
title = {High-speed photographic study of vaporclouds from wet droplets and the subsequent solid particles in an inductively coupled plasma},
author = {None, None},
abstractNote = {Movies of an inductively coupled plasma (ICP) while nebulizing a concentrated sample of yttrium were recorded using a high-speed camera with short exposure time (10 μs) and fast framing rate (5000 frames per s). Clouds from large droplets can be seen in several successive frames as they travel downstream in the axial channel of the ICP. These droplet clouds are superimposed on the usual spatial structure of red YO, neutral Y atom and blue Y+ emission. As a particular large droplet moves downstream, its red emission cloud evolves into a faint white streak with a surrounding cloud of blue Y+ emission. The streak is attributed to a solid residue from the droplet. The velocity of the droplet and subsequent particle is measured to be 28 m s-1. The general characteristics of the droplet and particle clouds agree well with previous photographic measurements and those by other methods such as laser induced-fluorescence or scattering.},
doi = {10.1039/D0JA00210K},
journal = {Journal of Analytical Atomic Spectrometry},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}
Free Publicly Available Full Text
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https://doi.org/10.1039/D0JA00210K
https://doi.org/10.1039/D0JA00210K
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Fig. 1: Successive frames from a small section of Video 1. Frame 690 is the first image from this clip. Alternate frames are numbered in the order they were measured. The time interval between frames was 200 μs. A white arrow pointing right denotes the first droplet cloud under discussion.more »
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Works referenced in this record:
High-speed digital photographic study of an inductively coupled plasma during laser ablation: comparison of dried solution aerosols from a microconcentric nebulizer and solid particles from laser ablation
journal, January 2003
- Aeschliman, David B.; Bajic, Stanley J.; Baldwin, David P.
- Journal of Analytical Atomic Spectrometry, Vol. 18, Issue 9
A simple, non-invasive method for the measurement of gas flow velocities in the inductively coupled plasma
journal, January 1989
- Cicerone, Marcus T.; Farnsworth, Paul B.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 44, Issue 9
Characterization of single Au and SiO2 nano- and microparticles by ICP-OES using monodisperse droplets of standard solutions for calibration
journal, January 2010
- Garcia, Carmen C.; Murtazin, Ayrat; Groh, Sebastian
- Journal of Analytical Atomic Spectrometry, Vol. 25, Issue 5
Highly multiparametric analysis by mass cytometry
journal, September 2010
- Ornatsky, Olga; Bandura, Dmitry; Baranov, Vladimir
- Journal of Immunological Methods, Vol. 361, Issue 1-2
Nomenclature system for the low-power argon inductively coupled plasma
journal, October 1980
- Koirtyohann, S. R.; Jones, J. Stephen.; Yates, Dennis A.
- Analytical Chemistry, Vol. 52, Issue 12
Zirconia colloid analysis by single particle inductively coupled plasma–mass spectrometry
journal, August 2004
- Degueldre, C.; Favarger, P. -Y.; Bitea, C.
- Analytica Chimica Acta, Vol. 518, Issue 1-2
Mass Cytometry: Technique for Real Time Single Cell Multitarget Immunoassay Based on Inductively Coupled Plasma Time-of-Flight Mass Spectrometry
journal, August 2009
- Bandura, Dmitry R.; Baranov, Vladimir I.; Ornatsky, Olga I.
- Analytical Chemistry, Vol. 81, Issue 16
Mechanism of desolvation of sample droplets in flame spectrometry
journal, June 1972
- Clampitt, N. C.; Hieftje, G. M.
- Analytical Chemistry, Vol. 44, Issue 7
Unique system for studying flame spectrometric processes
journal, October 1968
- Hieftje, G. M.; Malmstadt, H. V.
- Analytical Chemistry, Vol. 40, Issue 12
Observation of Atom and Ion Clouds Produced from Single Droplets of Sample in Inductively Coupled Plasmas by Optical Emission and Laser-Induced Fluorescence Imaging
journal, May 1997
- Olesik, John W.; Kinzer, Jeffery A.; McGowan, Garrett J.
- Applied Spectroscopy, Vol. 51, Issue 5
Experimental and theoretical investigations about the vaporization of laser-produced aerosols and individual particles inside inductively-coupled plasmas — Implications for the extraction efficiency of ions prior to mass spectrometry
journal, October 2012
- Flamigni, Luca; Koch, Joachim; Günther, Detlef
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 76
Separation and detection of gold nanoparticles with capillary electrophoresis and ICP-MS in single particle mode (CE-SP-ICP-MS)
journal, January 2017
- Franze, Bastian; Strenge, Ingo; Engelhard, Carsten
- Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 8
Inductively coupled plasma-optical emission analytical spectrometry
journal, January 1974
- Scott, Robert H.; Fassel, Velmer A.; Kniseley, Richard N.
- Analytical Chemistry, Vol. 46, Issue 1
Composition and Size-Dependent Extinction Coefficient of Colloidal PbSe Quantum Dots
journal, December 2007
- Moreels, Iwan; Lambert, Karel; De Muynck, David
- Chemistry of Materials, Vol. 19, Issue 25
Investigating the Fate of Individual Sample Droplets in Inductively Coupled Plasmas
journal, May 1997
- Olesik, John W.
- Applied Spectroscopy, Vol. 51, Issue 5
Simulation of droplet heating and desolvation in inductively coupled plasma—part II: coalescence in the plasma
journal, August 2003
- Benson, Craig M.; Zhong, Jiaqiang; Gimelshein, Sergey F.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 58, Issue 8
Computerized simulation of mixed-solute-particle vaporization in an inductively coupled plasma
journal, July 1998
- Horner, Julie A.; Hieftje, Gary M.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 53, Issue 6-8
Elemental mass spectrometry: a powerful tool for an accurate characterisation at elemental level of quantum dots
journal, January 2009
- Montoro Bustos, Antonio R.; Encinar, Jorge Ruiz; Fernández-Argüelles, María T.
- Chemical Communications, Issue 21
Inductively coupled plasma-mass spectrometry: insights through computer modeling
journal, January 2017
- Bogaerts, Annemie; Aghaei, Maryam
- Journal of Analytical Atomic Spectrometry, Vol. 32, Issue 2
High speed photographic study of plasma fluctuations and intact aerosol particles or droplets in inductively coupled plasma mass spectrometry
journal, January 1991
- Winge, Royce K.; Crain, J. S.; Houk, R. S.
- Journal of Analytical Atomic Spectrometry, Vol. 6, Issue 8
Investigation of sample introduction- and plasma-related matrix effects in inductively coupled plasma spectrometry applying single analyte droplet and particle injection
journal, January 2012
- Murtazin, Ayrat; Groh, Sebastian; Niemax, Kay
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 67
High Speed Photographic Study of Wet Droplets and Solid Particles in the Inductively Coupled Plasma
journal, January 1997
- Houk, R. S.; Winge, Royce K.; Chen, Xiaoshan
- Journal of Analytical Atomic Spectrometry, Vol. 12, Issue 10
A dynamic model for the elucidation of a mechanism of analyte transformation in an inductively coupled plasma
journal, August 1988
- Li, K. P.; Dowling, M.; Fogg, T.
- Analytical Chemistry, Vol. 60, Issue 15
Behavior of Bacteria in the Inductively Coupled Plasma: Atomization and Production of Atomic Ions for Mass Spectrometry
journal, March 2005
- Li, Fumin; Armstrong, Daniel W.; Houk, R. S.
- Analytical Chemistry, Vol. 77, Issue 5
A critical review of single particle inductively coupled plasma mass spectrometry – A step towards an ideal method for nanomaterial characterization
journal, January 2020
- Mozhayeva, Darya; Engelhard, Carsten
- Journal of Analytical Atomic Spectrometry
Spatiotemporal characteristics of the inductively coupled plasma
journal, January 1988
- Winge, Royce K.; Eckels, David E.; DeKalb, Edward L.
- Journal of Analytical Atomic Spectrometry, Vol. 3, Issue 6
Impact of the Particle Diameter on Ion Cloud Formation from Gold Nanoparticles in ICPMS
journal, July 2018
- Fuchs, Joshua; Aghaei, Maryam; Schachel, Tilo D.
- Analytical Chemistry, Vol. 90, Issue 17
Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.