skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects

Abstract

By balancing bimetallic composition-associated ligand and ensemble effects, Ag 15 Pd 85 nanoparticles show enhanced catalytic properties for electrochemical CO 2 reduction.

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [2]; ORCiD logo [2];  [3]; ORCiD logo [1]
  1. Univ. of Virginia, Charlottesville, VA (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
  3. California State Univ., Northridge, CA (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1633604
Alternate Identifier(s):
OSTI ID: 1635043
Report Number(s):
BNL-216048-2020-JAAM
Journal ID: ISSN 2040-3364; NANOHL
Grant/Contract Number:  
SC0012704
Resource Type:
Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Volume: 12; Journal Issue: 26; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Cui, Meiyang, Johnson, Grayson, Zhang, Zhiyong, Li, Shuang, Hwang, Sooyeon, Zhang, Xu, and Zhang, Sen. AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects. United States: N. p., 2020. Web. https://doi.org/10.1039/D0NR03203D.
Cui, Meiyang, Johnson, Grayson, Zhang, Zhiyong, Li, Shuang, Hwang, Sooyeon, Zhang, Xu, & Zhang, Sen. AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects. United States. https://doi.org/10.1039/D0NR03203D
Cui, Meiyang, Johnson, Grayson, Zhang, Zhiyong, Li, Shuang, Hwang, Sooyeon, Zhang, Xu, and Zhang, Sen. Mon . "AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects". United States. https://doi.org/10.1039/D0NR03203D. https://www.osti.gov/servlets/purl/1633604.
@article{osti_1633604,
title = {AgPd nanoparticles for electrocatalytic CO2 reduction: bimetallic composition-dependent ligand and ensemble effects},
author = {Cui, Meiyang and Johnson, Grayson and Zhang, Zhiyong and Li, Shuang and Hwang, Sooyeon and Zhang, Xu and Zhang, Sen},
abstractNote = {By balancing bimetallic composition-associated ligand and ensemble effects, Ag 15 Pd 85 nanoparticles show enhanced catalytic properties for electrochemical CO 2 reduction.},
doi = {10.1039/D0NR03203D},
journal = {Nanoscale},
number = 26,
volume = 12,
place = {United States},
year = {2020},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Prospects of CO2 Utilization via Direct Heterogeneous Electrochemical Reduction
journal, December 2010

  • Whipple, Devin T.; Kenis, Paul J. A.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458
  • DOI: 10.1021/jz1012627

Opportunities and prospects in the chemical recycling of carbon dioxide to fuels
journal, November 2009


Catalysis for the Valorization of Exhaust Carbon: from CO 2 to Chemicals, Materials, and Fuels. Technological Use of CO 2
journal, November 2013

  • Aresta, Michele; Dibenedetto, Angela; Angelini, Antonella
  • Chemical Reviews, Vol. 114, Issue 3
  • DOI: 10.1021/cr4002758

Electrochemical CO 2 Reduction into Chemical Feedstocks: From Mechanistic Electrocatalysis Models to System Design
journal, December 2018

  • Kibria, Md Golam; Edwards, Jonathan P.; Gabardo, Christine M.
  • Advanced Materials, Vol. 31, Issue 31
  • DOI: 10.1002/adma.201807166

Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts
journal, January 2012

  • Schneider, Jacob; Jia, Hongfei; Muckerman, James T.
  • Chem. Soc. Rev., Vol. 41, Issue 6
  • DOI: 10.1039/C1CS15278E

Effects of process conditions and electrode material on reaction pathways for carbon dioxide electroreduction with particular reference to formate formation
journal, December 2003


Rational Design of Bi Nanoparticles for Efficient Electrochemical CO 2 Reduction: The Elucidation of Size and Surface Condition Effects
journal, August 2016


Revealing structural evolution of PbS nanocrystal catalysts in electrochemical CO 2 reduction using in situ synchrotron radiation X-ray diffraction
journal, January 2019

  • Zhang, Zhiyong; Liu, Chang; Brosnahan, John T.
  • Journal of Materials Chemistry A, Vol. 7, Issue 41
  • DOI: 10.1039/C9TA06750G

Shape-Controlled CO 2 Electrochemical Reduction on Nanosized Pd Hydride Cubes and Octahedra
journal, January 2019

  • Zhu, Wenlei; Kattel, Shyam; Jiao, Feng
  • Advanced Energy Materials, Vol. 9, Issue 9
  • DOI: 10.1002/aenm.201802840

Activity Descriptors for CO 2 Electroreduction to Methane on Transition-Metal Catalysts
journal, January 2012

  • Peterson, Andrew A.; Nørskov, Jens K.
  • The Journal of Physical Chemistry Letters, Vol. 3, Issue 2
  • DOI: 10.1021/jz201461p

Bimetallic Composition-Promoted Electrocatalytic Hydrodechlorination Reaction on Silver–Palladium Alloy Nanoparticles
journal, September 2019


Poisoning and deactivation of palladium catalysts
journal, September 2001

  • Albers, Peter; Pietsch, Jörg; Parker, Stewart F.
  • Journal of Molecular Catalysis A: Chemical, Vol. 173, Issue 1-2
  • DOI: 10.1016/S1381-1169(01)00154-6

Pd-Containing Nanostructures for Electrochemical CO 2 Reduction Reaction
journal, January 2018


Size-Dependent Electrocatalytic Reduction of CO 2 over Pd Nanoparticles
journal, March 2015

  • Gao, Dunfeng; Zhou, Hu; Wang, Jing
  • Journal of the American Chemical Society, Vol. 137, Issue 13
  • DOI: 10.1021/jacs.5b00046

Facet design promotes electroreduction of carbon dioxide to carbon monoxide on palladium nanocrystals
journal, February 2019


Tuning the activity and selectivity of electroreduction of CO2 to synthesis gas using bimetallic catalysts
journal, August 2019


Exclusive Formation of Formic Acid from CO 2 Electroreduction by a Tunable Pd-Sn Alloy
journal, August 2017

  • Bai, Xiaofang; Chen, Wei; Zhao, Chengcheng
  • Angewandte Chemie International Edition, Vol. 56, Issue 40
  • DOI: 10.1002/anie.201707098

Ensemble Effect in Bimetallic Electrocatalysts for CO 2 Reduction
journal, September 2019

  • Wang, Yuxuan; Cao, Liang; Libretto, Nicole J.
  • Journal of the American Chemical Society, Vol. 141, Issue 42
  • DOI: 10.1021/jacs.9b05766

Monodisperse AgPd Alloy Nanoparticles and Their Superior Catalysis for the Dehydrogenation of Formic Acid
journal, February 2013

  • Zhang, Sen; Metin, Önder; Su, Dong
  • Angewandte Chemie International Edition, Vol. 52, Issue 13
  • DOI: 10.1002/anie.201300276

Oleylamine-Mediated Synthesis of Pd Nanoparticles for Catalytic Formic Acid Oxidation
journal, April 2009

  • Mazumder, Vismadeb; Sun, Shouheng
  • Journal of the American Chemical Society, Vol. 131, Issue 13
  • DOI: 10.1021/ja9004915

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Projector augmented-wave method
journal, December 1994


Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals
journal, March 1999


Special points for Brillouin-zone integrations
journal, June 1976

  • Monkhorst, Hendrik J.; Pack, James D.
  • Physical Review B, Vol. 13, Issue 12, p. 5188-5192
  • DOI: 10.1103/PhysRevB.13.5188

Density functional calculations on hydrogen in palladium–silver alloys
journal, January 2002


Generalized Synthetic Strategy for Transition-Metal-Doped Brookite-Phase TiO 2 Nanorods
journal, September 2019

  • Zhang, Zhiyong; Wu, Qiyuan; Johnson, Grayson
  • Journal of the American Chemical Society, Vol. 141, Issue 42
  • DOI: 10.1021/jacs.9b06389

Programmable Synthesis of Multimetallic Phosphide Nanorods Mediated by Core/Shell Structure Formation and Conversion
journal, April 2020

  • Zhang, Yulu; Li, Na; Zhang, Zhiyong
  • Journal of the American Chemical Society, Vol. 142, Issue 18
  • DOI: 10.1021/jacs.0c02584

PbSe Nanocrystal Solids for n- and p-Channel Thin Film Field-Effect Transistors
journal, October 2005


Rational Synthesis of Ultrathin n-Type Bi2Te3 Nanowires with Enhanced Thermoelectric Properties
journal, November 2011

  • Zhang, Genqiang; Kirk, Benjamin; Jauregui, Luis A.
  • Nano Letters, Vol. 12, Issue 1, p. 56-60
  • DOI: 10.1021/nl202935k

Structural, Optical, and Electrical Properties of PbSe Nanocrystal Solids Treated Thermally or with Simple Amines
journal, May 2008

  • Law, Matt; Luther, Joseph M.; Song, Qing
  • Journal of the American Chemical Society, Vol. 130, Issue 18
  • DOI: 10.1021/ja800040c

Valence-Band Hybridization and Core Level Shifts in Random Ag-Pd Alloys
journal, October 2001


Core-level shifts in fcc random alloys: A first-principles approach
journal, August 2005


Electrocatalytic process of CO selectivity in electrochemical reduction of CO2 at metal electrodes in aqueous media
journal, August 1994

  • Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio
  • Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839
  • DOI: 10.1016/0013-4686(94)85172-7

Electrochemical promotion of catalysis over Pd nanoparticles for CO 2 reduction
journal, January 2017

  • Cai, Fan; Gao, Dunfeng; Zhou, Hu
  • Chemical Science, Vol. 8, Issue 4
  • DOI: 10.1039/C6SC04966D

Competition between Hydrogen Evolution and Carbon Dioxide Reduction on Copper Electrodes in Mildly Acidic Media
journal, May 2017


The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction
journal, March 2018


Switchable CO2 electroreduction via engineering active phases of Pd nanoparticles
journal, April 2017


The Promotional Effect of Gold in Catalysis by Palladium-Gold
journal, October 2005


Ligand and ensemble effects in adsorption on alloy surfaces
journal, January 2001

  • Liu, P.; Nørskov, J. K.
  • Physical Chemistry Chemical Physics, Vol. 3, Issue 17
  • DOI: 10.1039/b103525h

Infrared spectroscopic investigation of CO adsorbed on Pd aggregates deposited on an alumina model support
journal, March 1998


Surface Reactivity of Pd Nanoparticles Supported on Polycrystalline Substrates As Compared to Thin Film Model Catalysts:  Infrared Study of CO Adsorption
journal, March 2004

  • Bertarione, Serena; Scarano, Domenica; Zecchina, Adriano
  • The Journal of Physical Chemistry B, Vol. 108, Issue 11
  • DOI: 10.1021/jp036718t

FT-IR investigation of CO-adsorption on Pd-black and on supported Pd-samples
journal, March 1993


Highly selective hydrodechlorination of 1,2-dichloroethane to ethylene over Ag-Pd/ZrO2 catalysts with trace Pd
journal, June 2016


The interaction of CO with PdAg/Pd(111) surface alloys—A case study of ensemble effects on a bimetallic surface
journal, January 2011

  • Ma, Yunsheng; Diemant, T.; Bansmann, J.
  • Physical Chemistry Chemical Physics, Vol. 13, Issue 22
  • DOI: 10.1039/c1cp00009h

Hydrodechlorination of 1,2-dichloroethane on supported AgPd catalysts
journal, February 2019


Effects of d -band shape on the surface reactivity of transition-metal alloys
journal, March 2014


Localized Magnetic States in Metals
journal, October 1961


Self-Consistent Model of Hydrogen Chemisorption
journal, February 1969


Chemisorption on metals
journal, January 1978