Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks
Abstract
Unimolecular decomposition pathways are challenging to address in transition-metal catalysis and have previously not been suppressed via incorporation into a solid support. Two robust metal-organic frameworks (IRMOF-10 and bio-MOF-100) are used for the architectural stabilization of a structurally well-defined gold(III) catalyst. The inherent rigidity of these materials is utilized to preclude a unimolecular decomposition pathway—reductive elimination. Through this architectural stabilization strategy, decomposition of the incorporated gold(III) catalyst in the metal-organic frameworks is not observed; in contrast, the homogeneous analog is prone to decomposition in solution. Finally, stabilization of the catalyst in these metal-organic frameworks precludes leaching and enables recyclability, which is crucial for productive heterogeneous catalysis.
- Authors:
-
- Univ. of California, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoSciences Institute at Berkeley, Berkeley, CA (United States)
- Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Institutes of Health (NIH); National Science Foundation (NSF); Ministry of Economic Affairs and Digital Transformation of Spain (MINECO); King Abdulaziz City for Science and Technology
- OSTI Identifier:
- 1633252
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chem
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2451-9294
- Publisher:
- Cell Press, Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., and Toste, F. Dean. Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks. United States: N. p., 2019.
Web. doi:10.1016/j.chempr.2019.10.022.
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., & Toste, F. Dean. Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks. United States. https://doi.org/10.1016/j.chempr.2019.10.022
Lee, John S., Kapustin, Eugene A., Pei, Xiaokun, Llopis, Sebastián, Yaghi, Omar M., and Toste, F. Dean. Mon .
"Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks". United States. https://doi.org/10.1016/j.chempr.2019.10.022. https://www.osti.gov/servlets/purl/1633252.
@article{osti_1633252,
title = {Architectural Stabilization of a Gold(III) Catalyst in Metal-Organic Frameworks},
author = {Lee, John S. and Kapustin, Eugene A. and Pei, Xiaokun and Llopis, Sebastián and Yaghi, Omar M. and Toste, F. Dean},
abstractNote = {Unimolecular decomposition pathways are challenging to address in transition-metal catalysis and have previously not been suppressed via incorporation into a solid support. Two robust metal-organic frameworks (IRMOF-10 and bio-MOF-100) are used for the architectural stabilization of a structurally well-defined gold(III) catalyst. The inherent rigidity of these materials is utilized to preclude a unimolecular decomposition pathway—reductive elimination. Through this architectural stabilization strategy, decomposition of the incorporated gold(III) catalyst in the metal-organic frameworks is not observed; in contrast, the homogeneous analog is prone to decomposition in solution. Finally, stabilization of the catalyst in these metal-organic frameworks precludes leaching and enables recyclability, which is crucial for productive heterogeneous catalysis.},
doi = {10.1016/j.chempr.2019.10.022},
journal = {Chem},
number = 1,
volume = 6,
place = {United States},
year = {2019},
month = {11}
}
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Works referenced in this record:
Mechanically-Induced Chemical Changes in Polymeric Materials
journal, November 2009
- Caruso, Mary M.; Davis, Douglas A.; Shen, Qilong
- Chemical Reviews, Vol. 109, Issue 11
Polymer mechanochemistry: techniques to generate molecular force via elongational flows
journal, January 2013
- May, Preston A.; Moore, Jeffrey S.
- Chemical Society Reviews, Vol. 42, Issue 18
Mechanochemistry: The Mechanical Activation of Covalent Bonds
journal, August 2005
- Beyer, Martin K.; Clausen-Schaumann, Hauke
- Chemical Reviews, Vol. 105, Issue 8
Biasing reaction pathways with mechanical force
journal, March 2007
- Hickenboth, Charles R.; Moore, Jeffrey S.; White, Scott R.
- Nature, Vol. 446, Issue 7134
Mechanochemical unzipping of insulating polyladderene to semiconducting polyacetylene
journal, August 2017
- Chen, Zhixing; Mercer, Jaron A. M.; Zhu, Xiaolei
- Science, Vol. 357, Issue 6350
Stress-Responsive Polymers Containing Cyclobutane Core Mechanophores: Reactivity and Mechanistic Insights
journal, August 2013
- Kean, Zachary S.; Niu, Zhenbin; Hewage, Gihan B.
- Journal of the American Chemical Society, Vol. 135, Issue 36
Proton-Coupled Mechanochemical Transduction: A Mechanogenerated Acid
journal, July 2012
- Diesendruck, Charles E.; Steinberg, Brian D.; Sugai, Naoto
- Journal of the American Chemical Society, Vol. 134, Issue 30
Activating catalysts with mechanical force
journal, April 2009
- Piermattei, Alessio; Karthikeyan, S.; Sijbesma, Rint P.
- Nature Chemistry, Vol. 1, Issue 2
Mechanocatalysis: forcing latent catalysts into action
journal, January 2013
- Groote, Ramon; Jakobs, Robert T. M.; Sijbesma, Rint P.
- Polymer Chemistry, Vol. 4, Issue 18
Maleimide–thiol adducts stabilized through stretching
journal, February 2019
- Huang, Wenmao; Wu, Xin; Gao, Xiang
- Nature Chemistry, Vol. 11, Issue 4
Equilibration of the Oxidative Addition Product of Tetrakis(triphenylphosphine)palladium and Electron-Rich Aryl Halides Leads to Product Scrambling in the Stille Reaction
journal, January 1995
- Segelstein, B. E.; Butler, T. W.; Chenard, B. L.
- The Journal of Organic Chemistry, Vol. 60, Issue 1
Phosphonium Formation by Facile Carbon–Phosphorus Reductive Elimination from Gold(III)
journal, January 2016
- Kawai, Hiroyuki; Wolf, William J.; DiPasquale, Antonio G.
- Journal of the American Chemical Society, Vol. 138, Issue 2
Migratory Insertion of Carbenes into Au(III)–C Bonds
journal, December 2017
- Zhukhovitskiy, Aleksandr V.; Kobylianskii, Ilia J.; Wu, Chung-Yeh
- Journal of the American Chemical Society, Vol. 140, Issue 1
Understanding the reactivity of [WNAr(CH2tBu)2(CHtBu)] (Ar=2,6-iPrC6H3) with silica partially dehydroxylated at low temperatures through a combined use of molecular and surface organometallic chemistry
journal, December 2006
- Rhers, Bouchra; Quadrelli, Elsje Alessandra; Baudouin, Anne
- Journal of Organometallic Chemistry, Vol. 691, Issue 24-25
Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations
journal, February 2016
- Zhang, Teng; Manna, Kuntal; Lin, Wenbin
- Journal of the American Chemical Society, Vol. 138, Issue 9
Plasmon-Enhanced Photocatalytic CO 2 Conversion within Metal–Organic Frameworks under Visible Light
journal, December 2016
- Choi, Kyung Min; Kim, Dohyung; Rungtaweevoranit, Bunyarat
- Journal of the American Chemical Society, Vol. 139, Issue 1
Coordinative alignment of molecules in chiral metal-organic frameworks
journal, August 2016
- Lee, S.; Kapustin, E. A.; Yaghi, O. M.
- Science, Vol. 353, Issue 6301
Molecular Retrofitting Adapts a Metal–Organic Framework to Extreme Pressure
journal, June 2017
- Kapustin, Eugene A.; Lee, Seungkyu; Alshammari, Ahmad S.
- ACS Central Science, Vol. 3, Issue 6
Sequential Linker Installation: Precise Placement of Functional Groups in Multivariate Metal–Organic Frameworks
journal, March 2015
- Yuan, Shuai; Lu, Weigang; Chen, Ying-Pin
- Journal of the American Chemical Society, Vol. 137, Issue 9
Metal–organic framework materials as catalysts
journal, January 2009
- Lee, JeongYong; Farha, Omar K.; Roberts, John
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1450-1459
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis
journal, September 2011
- Yoon, Minyoung; Srirambalaji, Renganathan; Kim, Kimoon
- Chemical Reviews, Vol. 112, Issue 2, p. 1196-1231
Metal–organic frameworks for artificial photosynthesis and photocatalysis
journal, January 2014
- Zhang, Teng; Lin, Wenbin
- Chem. Soc. Rev., Vol. 43, Issue 16
Enantioselective catalysis with homochiral metal–organic frameworks
journal, January 2009
- Ma, Liqing; Abney, Carter; Lin, Wenbin
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1248-1256
Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework
journal, January 2012
- An, Jihyun; Farha, Omar K.; Hupp, Joseph T.
- Nature Communications, Vol. 3, Issue 1
Stable gold(III) catalysts by oxidative addition of a carbon–carbon bond
journal, January 2015
- Wu, Chung-Yeh; Horibe, Takahiro; Jacobsen, Christian Borch
- Nature, Vol. 517, Issue 7535
Gold(I)-Catalyzed Enantioselective Ring Expansion of Allenylcyclopropanols
journal, June 2009
- Kleinbeck, Florian; Toste, F. Dean
- Journal of the American Chemical Society, Vol. 131, Issue 26
Gold for the Generation and Control of Fluxional Barbaralyl Cations
journal, November 2012
- McGonigal, Paul R.; de León, Claudia; Wang, Yahui
- Angewandte Chemie International Edition, Vol. 51, Issue 52
Polymer-Bound Chiral Gold-Based Complexes as Efficient Heterogeneous Catalysts for Enantioselectivity Tunable Cycloaddition
journal, November 2015
- Chen, Mingjin; Zhang, Zhan-Ming; Yu, Zhunzhun
- ACS Catalysis, Vol. 5, Issue 12
Well-Defined Chiral Gold(III) Complex Catalyzed Direct Enantioconvergent Kinetic Resolution of 1,5-Enynes
journal, August 2017
- Bohan, Patrick T.; Toste, F. Dean
- Journal of the American Chemical Society, Vol. 139, Issue 32