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Title: Thiocyanate complexes of the lanthanides, Am and Cm

Abstract

In this work, the synthesis and single crystal structures of Am(III) and Cm(III) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal–thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal–ligand interactions.

Authors:
ORCiD logo [1];  [1];  [1];  [1]
  1. Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
OSTI Identifier:
1633072
Alternate Identifier(s):
OSTI ID: 1597138
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 56; Journal Issue: 17; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, and Stegman, Samantha. Thiocyanate complexes of the lanthanides, Am and Cm. United States: N. p., 2020. Web. https://doi.org/10.1039/c9cc07612c.
Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, & Stegman, Samantha. Thiocyanate complexes of the lanthanides, Am and Cm. United States. https://doi.org/10.1039/c9cc07612c
Wilson, Richard E., Carter, Tyler J., Autillo, Matthieu, and Stegman, Samantha. Tue . "Thiocyanate complexes of the lanthanides, Am and Cm". United States. https://doi.org/10.1039/c9cc07612c. https://www.osti.gov/servlets/purl/1633072.
@article{osti_1633072,
title = {Thiocyanate complexes of the lanthanides, Am and Cm},
author = {Wilson, Richard E. and Carter, Tyler J. and Autillo, Matthieu and Stegman, Samantha},
abstractNote = {In this work, the synthesis and single crystal structures of Am(III) and Cm(III) thiocyanate complexes are reported along with an isostructural series of lanthanide thiocyanate complexes. Because the complexes are isostructural, a comparative study of the metal–thiocyanate bonds was conducted using Raman spectroscopy indicating very similar and electrostatic metal–ligand interactions.},
doi = {10.1039/c9cc07612c},
journal = {ChemComm},
number = 17,
volume = 56,
place = {United States},
year = {2020},
month = {2}
}

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