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Title: Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy

Abstract

In this paper, differential dynamic microscopy is performed in diamond anvil cells to measure the viscosity of water along the 24 °C isotherm to high-pressure by determination of the tracer diffusion coefficient of monodisperse silica spheres of known diameter and application of the Stokes-Einstein-Sutherland equation. This technique allows liquid samples to be compressed to greater pressure prior to freezing than with other viscometry methods. The highest-pressure measurement was made at 1.67 GPa, considerably deeper into the supercompressed regime than previously reported. The effect of isotopic composition is investigated with samples of normal water, heavy water, and partially deuterated water. When data below 0.25 GPa are excluded a free volume model fits the observed viscosities well yielding a theoretical glass transition density close to that observed in very-high-density amorphous ice. The improved fit above 0.25 GPa coincides with the loss of other anomalous behaviors in liquid water caused by hydrogen bonding and represents a transition to properties closer to those of a simple liquid.

Authors:
ORCiD logo [1]; ORCiD logo [1]
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  1. SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Research Org.:
SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Fusion Energy Sciences (FES)
OSTI Identifier:
1632858
Alternate Identifier(s):
OSTI ID: 1632739
Grant/Contract Number:  
AC02-76SF00515; FWP100182
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 116; Journal Issue: 23; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS

Citation Formats

Frost, Mungo, and Glenzer, Siegfried H. Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy. United States: N. p., 2020. Web. doi:10.1063/5.0012750.
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Frost, Mungo, & Glenzer, Siegfried H. Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy. United States. https://doi.org/10.1063/5.0012750
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Frost, Mungo, and Glenzer, Siegfried H. Mon . "Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy". United States. https://doi.org/10.1063/5.0012750. https://www.osti.gov/servlets/purl/1632858.
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@article{osti_1632858,
title = {Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy},
author = {Frost, Mungo and Glenzer, Siegfried H.},
abstractNote = {In this paper, differential dynamic microscopy is performed in diamond anvil cells to measure the viscosity of water along the 24 °C isotherm to high-pressure by determination of the tracer diffusion coefficient of monodisperse silica spheres of known diameter and application of the Stokes-Einstein-Sutherland equation. This technique allows liquid samples to be compressed to greater pressure prior to freezing than with other viscometry methods. The highest-pressure measurement was made at 1.67 GPa, considerably deeper into the supercompressed regime than previously reported. The effect of isotopic composition is investigated with samples of normal water, heavy water, and partially deuterated water. When data below 0.25 GPa are excluded a free volume model fits the observed viscosities well yielding a theoretical glass transition density close to that observed in very-high-density amorphous ice. The improved fit above 0.25 GPa coincides with the loss of other anomalous behaviors in liquid water caused by hydrogen bonding and represents a transition to properties closer to those of a simple liquid.},
doi = {10.1063/5.0012750},
journal = {Applied Physics Letters},
number = 23,
volume = 116,
place = {United States},
year = {2020},
month = {6}
}
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https://doi.org/10.1063/5.0012750
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