Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy

Frost, Mungo; Glenzer, Siegfried H.

doi:10.1063/5.0012750

Title: Isotope effects on the high pressure viscosity of liquid water measured by differential dynamic microscopy

Journal Article · 08 June 2020 · Applied Physics Letters

DOI: https://doi.org/10.1063/5.0012750 · OSTI ID:1632858

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SLAC National Accelerator Lab., Menlo Park, CA (United States)

In this paper, differential dynamic microscopy is performed in diamond anvil cells to measure the viscosity of water along the 24 °C isotherm to high-pressure by determination of the tracer diffusion coefficient of monodisperse silica spheres of known diameter and application of the Stokes-Einstein-Sutherland equation. This technique allows liquid samples to be compressed to greater pressure prior to freezing than with other viscometry methods. The highest-pressure measurement was made at 1.67 GPa, considerably deeper into the supercompressed regime than previously reported. The effect of isotopic composition is investigated with samples of normal water, heavy water, and partially deuterated water. When data below 0.25 GPa are excluded a free volume model fits the observed viscosities well yielding a theoretical glass transition density close to that observed in very-high-density amorphous ice. The improved fit above 0.25 GPa coincides with the loss of other anomalous behaviors in liquid water caused by hydrogen bonding and represents a transition to properties closer to those of a simple liquid.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Fusion Energy Sciences (FES)

Grant/Contract Number:: AC02-76SF00515; FWP100182

OSTI ID:: 1632858

Alternate ID(s):: OSTI ID: 1632739

Journal Information:: Applied Physics Letters, Vol. 116, Issue 23; ISSN 0003-6951

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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