Strictly non-adiabatic quantum control of the acetylene dication using an infrared field
Abstract
We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a time dependent Schrödinger equation simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.
- Authors:
-
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Photon Ultrafast Laser Science and Engineering Inst. (PULSE); Stanford Univ., CA (United States)
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Photon Ultrafast Laser Science and Engineering Inst. (PULSE)
- Stanford PULSE Institute, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1632106
- Alternate Identifier(s):
- OSTI ID: 1617752
- Grant/Contract Number:
- AC02-76SF00515; 1504584
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Chemical Physics
- Additional Journal Information:
- Journal Volume: 152; Journal Issue: 18; Journal ID: ISSN 0021-9606
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Quantum chemical dynamics; Photoionization; Adiabatic process; Potential energy surfaces; Quantum control theory; Stark effect; Deprotonation
Citation Formats
Liekhus-Schmaltz, Chelsea, Zhu, Xiaolei, McCracken, Gregory A., Cryan, James P., Martinez, Todd J., and Bucksbaum, Philip H. Strictly non-adiabatic quantum control of the acetylene dication using an infrared field. United States: N. p., 2020.
Web. doi:10.1063/5.0007058.
Liekhus-Schmaltz, Chelsea, Zhu, Xiaolei, McCracken, Gregory A., Cryan, James P., Martinez, Todd J., & Bucksbaum, Philip H. Strictly non-adiabatic quantum control of the acetylene dication using an infrared field. United States. https://doi.org/10.1063/5.0007058
Liekhus-Schmaltz, Chelsea, Zhu, Xiaolei, McCracken, Gregory A., Cryan, James P., Martinez, Todd J., and Bucksbaum, Philip H. Thu .
"Strictly non-adiabatic quantum control of the acetylene dication using an infrared field". United States. https://doi.org/10.1063/5.0007058. https://www.osti.gov/servlets/purl/1632106.
@article{osti_1632106,
title = {Strictly non-adiabatic quantum control of the acetylene dication using an infrared field},
author = {Liekhus-Schmaltz, Chelsea and Zhu, Xiaolei and McCracken, Gregory A. and Cryan, James P. and Martinez, Todd J. and Bucksbaum, Philip H.},
abstractNote = {We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a time dependent Schrödinger equation simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.},
doi = {10.1063/5.0007058},
journal = {Journal of Chemical Physics},
number = 18,
volume = 152,
place = {United States},
year = {2020},
month = {5}
}
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