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Title: Strictly non-adiabatic quantum control of the acetylene dication using an infrared field

Journal Article · · Journal of Chemical Physics
DOI: https://doi.org/10.1063/5.0007058 · OSTI ID:1632106

We demonstrate the existence of a strictly non-adiabatic control pathway in deprotonation of the acetylene dication. This pathway is identified experimentally by measuring a kinetic energy shift in an ion coincidence experiment. We use a time dependent Schrödinger equation simulation to identify which properties most strongly affect our control. We find that resonant control around conical intersections is limited by the speed of non-adiabatic dynamics.

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515; 1504584
OSTI ID:
1632106
Alternate ID(s):
OSTI ID: 1617752
Journal Information:
Journal of Chemical Physics, Vol. 152, Issue 18; ISSN 0021-9606
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

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Figures / Tables (3)