First-order magnetic phase transition in with negligible thermomagnetic hysteresis
Abstract
Magnetic first-order phase transitions are key for the emergence of functionalities of fundamental and applied significance, including magnetic shape memory as well as magnetostrictive and magnetocaloric effects. Such transitions are usually associated with thermomagnetic hysteresis. In this paper we report the observation of a firstorder transition in Pr2In from a paramagnetic to a ferromagnetic state at $$T_C$$ = 57K without a detectable thermomagnetic hysteresis, which is also accompanied by a large magnetocaloric effect. The peculiar electronic structure of Pr2In exhibiting a large density of states near the Fermi energy explains the highly responsive magnetic behavior of the material. The magnetic properties of Pr2In are reported, including observation of another (second-order) magnetic transition at 35 K.
- Authors:
-
[1];
[1];
[2];
[1];
[1];
[1]
- Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
- Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States); State Univ. of New York (SUNY), Buffalo, NY (United States)
- Publication Date:
- Research Org.:
- Ames Lab., Ames, IA (United States); Iowa State Univ., Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
- OSTI Identifier:
- 1631682
- Report Number(s):
- IS-J10,228
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US2201005
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 101; Journal Issue: 22; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE
Citation Formats
Biswas, Anis, Zarkevich, N. A., Pathak, Arjun K., Dolotko, O., Hlova, Ihor Z., Smirnov, A. V., Mudryk, Y., Johnson, D. D., and Pecharsky, V. K. First-order magnetic phase transition in Pr2In with negligible thermomagnetic hysteresis. United States: N. p., 2020.
Web. doi:10.1103/PhysRevB.101.224402.
Biswas, Anis, Zarkevich, N. A., Pathak, Arjun K., Dolotko, O., Hlova, Ihor Z., Smirnov, A. V., Mudryk, Y., Johnson, D. D., & Pecharsky, V. K. First-order magnetic phase transition in Pr2In with negligible thermomagnetic hysteresis. United States. https://doi.org/10.1103/PhysRevB.101.224402
Biswas, Anis, Zarkevich, N. A., Pathak, Arjun K., Dolotko, O., Hlova, Ihor Z., Smirnov, A. V., Mudryk, Y., Johnson, D. D., and Pecharsky, V. K. Mon .
"First-order magnetic phase transition in Pr2In with negligible thermomagnetic hysteresis". United States. https://doi.org/10.1103/PhysRevB.101.224402. https://www.osti.gov/servlets/purl/1631682.
@article{osti_1631682,
title = {First-order magnetic phase transition in Pr2In with negligible thermomagnetic hysteresis},
author = {Biswas, Anis and Zarkevich, N. A. and Pathak, Arjun K. and Dolotko, O. and Hlova, Ihor Z. and Smirnov, A. V. and Mudryk, Y. and Johnson, D. D. and Pecharsky, V. K.},
abstractNote = {Magnetic first-order phase transitions are key for the emergence of functionalities of fundamental and applied significance, including magnetic shape memory as well as magnetostrictive and magnetocaloric effects. Such transitions are usually associated with thermomagnetic hysteresis. In this paper we report the observation of a firstorder transition in Pr2In from a paramagnetic to a ferromagnetic state at $T_C$ = 57K without a detectable thermomagnetic hysteresis, which is also accompanied by a large magnetocaloric effect. The peculiar electronic structure of Pr2In exhibiting a large density of states near the Fermi energy explains the highly responsive magnetic behavior of the material. The magnetic properties of Pr2In are reported, including observation of another (second-order) magnetic transition at 35 K.},
doi = {10.1103/PhysRevB.101.224402},
journal = {Physical Review B},
number = 22,
volume = 101,
place = {United States},
year = {2020},
month = {6}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Magnetocaloric materials for energy efficient cooling
journal, January 2017
- Lyubina, Julia
- Journal of Physics D: Applied Physics, Vol. 50, Issue 5
The crystal structure and lattice constants of R.E.2In and some R.E.5In3 compounds
journal, December 1968
- Palenzona, A.
- Journal of the Less Common Metals, Vol. 16, Issue 4
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Giant magnetocaloric effects by tailoring the phase transitions
journal, April 2010
- Trung, N. T.; Zhang, L.; Caron, L.
- Applied Physics Letters, Vol. 96, Issue 17
A Theory of Metallic Ferro- and Antiferromagnetism on Zener's Model
journal, July 1956
- Kasuya, Tadao
- Progress of Theoretical Physics, Vol. 16, Issue 1
Solution of the Schrödinger Equation in Periodic Lattices with an Application to Metallic Lithium
journal, June 1954
- Kohn, W.; Rostoker, N.
- Physical Review, Vol. 94, Issue 5
Reliable thermodynamic estimators for screening caloric materials
journal, September 2019
- Zarkevich, Nikolai A.; Johnson, Duane D.
- Journal of Alloys and Compounds, Vol. 802
Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993
- Rodríguez-Carvajal, Juan
- Physica B: Condensed Matter, Vol. 192, Issue 1-2
Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration
journal, May 2020
- Li, Lingwei; Yan, Mi
- Journal of Alloys and Compounds, Vol. 823
Finite Elastic Strain of Cubic Crystals
journal, June 1947
- Birch, Francis
- Physical Review, Vol. 71, Issue 11
Realization of magnetostructural coupling by modifying structural transitions in MnNiSi-CoNiGe system with a wide Curie-temperature window
journal, March 2016
- Liu, Jun; Gong, Yuanyuan; Xu, Guizhou
- Scientific Reports, Vol. 6, Issue 1
The order of the magnetic phase transitions in RCo 2 (R = rare earth) intermetallic compounds
journal, October 2000
- Khmelevskyi, S.; Mohn, P.
- Journal of Physics: Condensed Matter, Vol. 12, Issue 45
The Compressibility of Media under Extreme Pressures
journal, September 1944
- Murnaghan, F. D.
- Proceedings of the National Academy of Sciences, Vol. 30, Issue 9
Itinerant-electron metamagnetic transition and large magnetocaloric effects in compounds and their hydrides
journal, March 2003
- Fujita, A.; Fujieda, S.; Hasegawa, Y.
- Physical Review B, Vol. 67, Issue 10
The influence of quadrupolar interaction on the magnetocaloric effect in PrMg2
journal, August 2007
- von Ranke, P. J.; de Oliveira, N. A.; Mello, C.
- Journal of Alloys and Compounds, Vol. 440, Issue 1-2
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Coupled magnetic, structural, and electronic phase transitions in FeRh
journal, July 2016
- Lewis, L. H.; Marrows, C. H.; Langridge, S.
- Journal of Physics D: Applied Physics, Vol. 49, Issue 32
A first-principles theory of ferromagnetic phase transitions in metals
journal, June 1985
- Gyorffy, B. L.; Pindor, A. J.; Staunton, J.
- Journal of Physics F: Metal Physics, Vol. 15, Issue 6
Superheating and other unusual observations regarding the first order phase transition in Dy
journal, October 1996
- Pecharsky, V. K.; Gschneidner, K. A.; Fort, D.
- Scripta Materialia, Vol. 35, Issue 7
Magnetocaloric Materials
journal, August 2000
- Gschneidner, K. A.; Pecharsky, V. K.
- Annual Review of Materials Science, Vol. 30, Issue 1
On the calculation of the energy of a Bloch wave in a metal
journal, August 1947
- Korringa, J.
- Physica, Vol. 13, Issue 6-7
Unprecedentedly Wide Curie-Temperature Windows as Phase-Transition Design Platform for Tunable Magneto-Multifunctional Materials
journal, May 2015
- Wei, Zhi-Yang; Liu, En-Ke; Li, Yong
- Advanced Electronic Materials, Vol. 1, Issue 7
Designed materials with the giant magnetocaloric effect near room temperature
journal, November 2019
- Biswas, Anis; Pathak, Arjun K.; Zarkevich, Nikolai A.
- Acta Materialia, Vol. 180
Solid state electrotransport purification of dysprosium
journal, August 1995
- Fort, D.; Pecharsky, V. K.; Gschneidner, K. A.
- Journal of Alloys and Compounds, Vol. 226, Issue 1-2
Combinatorial search of thermoelastic shape-memory alloys with extremely small hysteresis width
journal, March 2006
- Cui, Jun; Chu, Yong S.; Famodu, Olugbenga O.
- Nature Materials, Vol. 5, Issue 4
Giant enhancement of the magnetocaloric response in Ni–Co–Mn–Ti by rapid solidification
journal, July 2019
- Neves Bez, Henrique; Pathak, Arjun K.; Biswas, Anis
- Acta Materialia, Vol. 173
Taming the First-Order Transition in Giant Magnetocaloric Materials
journal, February 2014
- Guillou, François; Porcari, Giacomo; Yibole, Hargen
- Advanced Materials, Vol. 26, Issue 17
Best practices in evaluation of the magnetocaloric effect from bulk magnetization measurements
journal, July 2018
- Neves Bez, H.; Yibole, H.; Pathak, A.
- Journal of Magnetism and Magnetic Materials, Vol. 458
Density-Functional Theory for Random Alloys: Total Energy within the Coherent-Potential Approximation
journal, May 1986
- Johnson, D. D.; Nicholson, D. M.; Pinski, F. J.
- Physical Review Letters, Vol. 56, Issue 19
Magnetocaloric effect of rare earth mono-nitrides, TbN and HoN
journal, August 2004
- Yamamoto, Takao A.; Nakagawa, Takashi; Sako, Kengo
- Journal of Alloys and Compounds, Vol. 376, Issue 1-2
Magnetic structure of selected Gd intermetallic alloys from first principles
journal, January 2020
- Petit, L.; Szotek, Z.; Paudyal, D.
- Physical Review B, Vol. 101, Issue 1
Non-hysteretic first-order phase transition with large latent heat and giant low-field magnetocaloric effect
journal, July 2018
- Guillou, F.; Pathak, A. K.; Paudyal, D.
- Nature Communications, Vol. 9, Issue 1
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Barocaloric effect in the magnetocaloric prototype Gd5Si2Ge2
journal, August 2012
- Yuce, Suheyla; Barrio, Maria; Emre, Baris
- Applied Physics Letters, Vol. 101, Issue 7
Magnetic properties of Ln3In intermetallic compounds
journal, February 1974
- Hutchens, R. D.; Wallace, W. E.; Nereson, N.
- Journal of Solid State Chemistry, Vol. 9, Issue 2
Influence of negative lattice expansion and metamagnetic transition on magnetic entropy change in the compound LaFe11.4Si1.6
journal, June 2001
- Hu, Feng-xia; Shen, Bao-gen; Sun, Ji-rong
- Applied Physics Letters, Vol. 78, Issue 23
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 49, Issue 20, p. 14251-14269
Managing hysteresis of Gd 5 Si 2 Ge 2 by magnetic field cycling
journal, December 2019
- Biswas, Anis; Mudryk, Yaroslav; Pathak, Arjun K.
- Journal of Applied Physics, Vol. 126, Issue 24
On the crystal structure of R.E.5In3 and Y5In3 compounds
journal, July 1974
- Franceschi, Enrico
- Journal of the Less Common Metals, Vol. 37, Issue 1
First order magneto-structural phase transition and associated multi-functional properties in magnetic solids
journal, April 2013
- Roy, Sindhunil Barman
- Journal of Physics: Condensed Matter, Vol. 25, Issue 18
Giant Magnetocaloric Effect in
journal, June 1997
- Pecharsky, V. K.; Gschneidner, Jr., K. A.
- Physical Review Letters, Vol. 78, Issue 23, p. 4494-4497
Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
journal, April 2008
- Perdew, John P.; Ruzsinszky, Adrienn; Csonka, Gábor I.
- Physical Review Letters, Vol. 100, Issue 13
A universal metric for ferroic energy materials
journal, August 2016
- Brück, Ekkes; Yibole, Hargen; Zhang, Lian
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074
High-throughput search for caloric materials: the CaloriCool approach
journal, December 2017
- Zarkevich, N. A.; Johnson, D. D.; Pecharsky, V. K.
- Journal of Physics D: Applied Physics, Vol. 51, Issue 2
Crystal field excitations in the singlet ground state compound Pr3In
journal, May 2007
- Christianson, A. D.; Lawrence, J. M.; Littrell, K. C.
- Journal of Applied Physics, Vol. 101, Issue 9
Indirect exchange for rare earths in metals
journal, May 1972
- Campbell, I. A.
- Journal of Physics F: Metal Physics, Vol. 2, Issue 3
Entropy determinations and magnetocaloric parameters in systems with first-order transitions: Study of MnAs
journal, May 2009
- Tocado, Leticia; Palacios, Elías; Burriel, Ramón
- Journal of Applied Physics, Vol. 105, Issue 9
Manipulation of magnetostructural transition and realization of prominent multifunctional magnetoresponsive properties in NiCoMnIn alloys
journal, March 2019
- Sun, X. M.; Cong, D. Y.; Li, Z.
- Physical Review Materials, Vol. 3, Issue 3
Mastering hysteresis in magnetocaloric materials
journal, August 2016
- Gutfleisch, O.; Gottschall, T.; Fries, M.
- Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2074
Massive Magnetic-Field-Induced Structural Transformation in and the Nature of the Giant Magnetocaloric Effect
journal, November 2003
- Pecharsky, V. K.; Holm, A. P.; Gschneidner, K. A.
- Physical Review Letters, Vol. 91, Issue 19
Green's function multiple-scattering theory with a truncated basis set: An augmented-KKR formalism
journal, November 2014
- Alam, Aftab; Khan, Suffian N.; Smirnov, A. V.
- Physical Review B, Vol. 90, Issue 20
Balancing structural distortions via competing 4f and itinerant interactions: a case of polymorphism in magnetocaloric HoCo 2
journal, January 2016
- Mudryk, Y.; Paudyal, D.; Pathak, A. K.
- Journal of Materials Chemistry C, Vol. 4, Issue 20
Magnetism and magnetocaloric effect in the ternary equiatomic REFeAl (RE = Er and Ho) compounds
journal, October 2015
- Zhang, Yikun; Wilde, Gerhard; Li, Xi
- Intermetallics, Vol. 65
Magnetic and electric hyperfine interactions in the rare-earth indium compounds studied by perturbed angular correlations
journal, March 2005
- Forker, M.; Müßeler, R.; Bedi, S. C.
- Physical Review B, Vol. 71, Issue 9