CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Maria, Leonor; Bandeira, Nuno A. G.; Marçalo, Joaquim; Santos, Isabel C.; Gibson, John K.

doi:10.1039/c9cc07411b

Title: CO₂ conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Abstract

U( vi ) trans -bis(imido) complexes [U(κ ⁴ {( ^tBu2 ArO) ₂ Me ₂ -cyclam})(NPh)(NPh ^R )] react with CO ₂ to afford U( vi ) trans -[OUNR] ²⁺ complexes with elimination of isocyanates. These are unprecedented examples of CO ₂ cleavage mediated by U( vi ) imido complexes.

Authors:

^[1];

^[2]

Univ. of Lisbon (Portugal)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Thu Dec 05 00:00:00 EST 2019

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1631623

Alternate Identifier(s):: OSTI ID: 1578137

Grant/Contract Number:: AC02-05CH11231; AC02-05CH1123

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 56; Journal Issue: 3; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Maria, Leonor, Bandeira, Nuno A. G., Marçalo, Joaquim, Santos, Isabel C., and Gibson, John K. CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes.  United States: N. p., 2019. 
Web.  doi:10.1039/c9cc07411b.

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                    Maria, Leonor, Bandeira, Nuno A. G., Marçalo, Joaquim, Santos, Isabel C., & Gibson, John K. CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes.  United States.  https://doi.org/10.1039/c9cc07411b

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                    Maria, Leonor, Bandeira, Nuno A. G., Marçalo, Joaquim, Santos, Isabel C., and Gibson, John K. Thu .  
"CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes".  United States.  https://doi.org/10.1039/c9cc07411b.  https://www.osti.gov/servlets/purl/1631623.

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@article{osti_1631623,

  title        = {CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes},

  author       = {Maria, Leonor and Bandeira, Nuno A. G. and Marçalo, Joaquim and Santos, Isabel C. and Gibson, John K.},

  abstractNote = {U( vi ) trans -bis(imido) complexes [U(κ 4 {( tBu2 ArO) 2 Me 2 -cyclam})(NPh)(NPh R )] react with CO 2 to afford U( vi ) trans -[OUNR] 2+ complexes with elimination of isocyanates. These are unprecedented examples of CO 2 cleavage mediated by U( vi ) imido complexes.},

  doi          = {10.1039/c9cc07411b},

  journal      = {ChemComm},

  number       = 3,

  volume       = 56,

  place        = {United States},

  year         = {Thu Dec 05 00:00:00 EST 2019},

  month        = {Thu Dec 05 00:00:00 EST 2019}

}

Copy to clipboard

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dataset (2)

Title: CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Abstract

Citation Formats

Carbon oxygenate transformations by actinide compounds and catalysts journal, January 2017

Metal–ligand multiple bonding in uranium: structure and reactivity journal, January 2010

Generalized Gradient Approximation Made Simple journal, October 1996

A Series of Uranium (IV, V, VI) Tritylimido Complexes, Their Molecular and Electronic Structures and Reactivity with CO 2 journal, November 2014

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Small-Molecule Activation at Uranium(III) journal, April 2013

Synthesis of Imido Analogs of the Uranyl Ion journal, December 2005

Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds journal, August 2014

Exchange of an Imido Ligand in Bis(imido) Complexes of Uranium journal, October 2006

Pendant Arm Functionalized Benzamidinate Titanium Imido Compounds: Experimental and Computational Studies of Their Reactions with CO 2 journal, May 2005

Imido Exchange in Bis(imido) Uranium(VI) Complexes with Aryl Isocyanates journal, March 2008

Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl 2 (R 2 bpy) 2 (R = Me, t Bu) and U(NAr)Cl 2 (tppo) 3 journal, August 2014

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Recent developments in actinide–ligand multiple bonding journal, January 2013

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Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex journal, August 2005

Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U( iii ) complex journal, January 2008

Uranium-mediated reductive conversion of CO2 to CO and carbonate in a single-vessel, closed synthetic cycle journal, January 2012

CO 2 conversion to isocyanate via multiple N–Si bond cleavage at a bulky uranium( iii ) complex journal, January 2015

Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion vs. cycloaddition-insertion journal, January 2009

From Amides to Amidines: Preparations of Imidoylbenzotriazoles and Arylaminoheterocycles journal, February 2001

A Linear, O-Coordinated 1-CO2 Bound to Uranium journal, September 2004

Electronic Structure and Bonding in Actinyl Ions and their Analogs journal, May 2007

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex journal, May 2014

Controlling selectivity in the reductive activation of CO 2 by mixed sandwich uranium( iii ) complexes journal, January 2014

Multimetallic Cooperativity in Uranium-Mediated CO 2 Activation journal, April 2014

Bispentamethylcyclopentadienyl uranium(IV) thiolate compounds. Synthesis and reactions with CO2 and CS2 journal, May 1999

Benchmarking Density Functional Methods against the S66 and S66x8 Datasets for Non-Covalent Interactions journal, November 2011

Synthesis, Characterization, and Reactivity of a Uranium(VI) Carbene Imido Oxo Complex journal, May 2014

Title: CO₂ conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Carbon oxygenate transformations by actinide compounds and catalysts
journal, January 2017

Metal–ligand multiple bonding in uranium: structure and reactivity
journal, January 2010

Generalized Gradient Approximation Made Simple
journal, October 1996

A Series of Uranium (IV, V, VI) Tritylimido Complexes, Their Molecular and Electronic Structures and Reactivity with CO ₂
journal, November 2014

The insertion of carbon dioxide into actinide alkyl and hydride bonds
journal, September 1985

Insertion Reactivity of CO ₂ , PhNCO, Me ₃ CC≡N, and Me ₃ CN≡C with the Uranium−Alkynyl Bonds in (C ₅ Me ₅ ) ₂ U(C≡CPh) ₂
journal, February 2010

Small-Molecule Activation at Uranium(III)
journal, April 2013

Synthesis of Imido Analogs of the Uranyl Ion
journal, December 2005

Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds
journal, August 2014

Exchange of an Imido Ligand in Bis(imido) Complexes of Uranium
journal, October 2006

Pendant Arm Functionalized Benzamidinate Titanium Imido Compounds: Experimental and Computational Studies of Their Reactions with CO ₂
journal, May 2005

Imido Exchange in Bis(imido) Uranium(VI) Complexes with Aryl Isocyanates
journal, March 2008

Preparation and Reactivity of the Versatile Uranium(IV) Imido Complexes U(NAr)Cl ₂ (R ₂ bpy) ₂ (R = Me, ^t Bu) and U(NAr)Cl ₂ (tppo) ₃
journal, August 2014

Managing the Computational Chemistry Big Data Problem: The ioChem-BD Platform
journal, December 2014

Synthesis of ureas from titanium imido complexes using CO ₂ as a C-1 reagent at ambient temperature and pressure
journal, January 2012

Carbon Dioxide Activation with Sterically Pressured Mid- and High-Valent Uranium Complexes
journal, September 2008

Terminal Uranium(V/VI) Nitride Activation of Carbon Dioxide and Carbon Disulfide: Factors Governing Diverse and Well-Defined Cleavage and Redox Reactions
journal, January 2017

Chemistry with ADF
journal, January 2001

Aryl Isocyanate, Carbodiimide, and Isocyanide Prepared from Carbon Dioxide. A Metathetical Group-Transfer Tale Involving a Titanium−Imide Zwitterion
journal, January 2006

Recent developments in actinide–ligand multiple bonding
journal, January 2013

Uranium(III) Redox Chemistry Assisted by a Hemilabile Bis(phenolate) Cyclam Ligand: Uranium–Nitrogen Multiple Bond Formation Comprising a trans -{RN═U(VI)═NR} ²⁺ Complex
journal, September 2015

Carbon Dioxide Reduction and Carbon Monoxide Activation Employing a Reactive Uranium(III) Complex
journal, August 2005

Reductive disproportionation of carbon dioxide to carbonate and squarate products using a mixed-sandwich U( iii ) complex
journal, January 2008

Uranium-mediated reductive conversion of CO2 to CO and carbonate in a single-vessel, closed synthetic cycle
journal, January 2012

CO ₂ conversion to isocyanate via multiple N–Si bond cleavage at a bulky uranium( iii ) complex
journal, January 2015

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journal, January 2009

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journal, February 2001

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journal, September 2004

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journal, May 2007

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journal, May 2014

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journal, January 2014

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journal, April 2014

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