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Title: CO2 conversion to phenyl isocyanates by uranium(vi) bis(imido) complexes

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/c9cc07411b · OSTI ID:1631623
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]
  1. Univ. of Lisbon (Portugal)
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
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U( vi ) trans -bis(imido) complexes [U(κ 4 {( tBu2 ArO) 2 Me 2 -cyclam})(NPh)(NPh R )] react with CO 2 to afford U( vi ) trans -[OUNR] 2+ complexes with elimination of isocyanates. These are unprecedented examples of CO 2 cleavage mediated by U( vi ) imido complexes.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-05CH11231; AC02-05CH1123
OSTI ID:
1631623
Alternate ID(s):
OSTI ID: 1578137
Journal Information:
ChemComm, Vol. 56, Issue 3; ISSN 1359-7345
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 14 works
Citation information provided by
Web of Science

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