skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on June 2, 2021

Title: Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Department of ChemistryOregon State University Corvallis Oregon 97331-4003 United States
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1631493
Grant/Contract Number:  
DE SC0010802
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Name: Chemistry - A European Journal Journal Volume: 26 Journal Issue: 36; Journal ID: ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Xu, Wei, Kozma, Karoly, Sha, Tianxiang, Wu, Yi‐Jen, Nyman, May, and Lerner, Michael M. Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds. Germany: N. p., 2020. Web. doi:10.1002/chem.202000504.
Xu, Wei, Kozma, Karoly, Sha, Tianxiang, Wu, Yi‐Jen, Nyman, May, & Lerner, Michael M. Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds. Germany. doi:https://doi.org/10.1002/chem.202000504
Xu, Wei, Kozma, Karoly, Sha, Tianxiang, Wu, Yi‐Jen, Nyman, May, and Lerner, Michael M. Tue . "Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds". Germany. doi:https://doi.org/10.1002/chem.202000504.
@article{osti_1631493,
title = {Reversible M−M Bonding by Alkaline Earth Metals (Mg, Ca, Sr, Ba) in Graphite Intercalation Compounds},
author = {Xu, Wei and Kozma, Karoly and Sha, Tianxiang and Wu, Yi‐Jen and Nyman, May and Lerner, Michael M.},
abstractNote = {},
doi = {10.1002/chem.202000504},
journal = {Chemistry - A European Journal},
number = 36,
volume = 26,
place = {Germany},
year = {2020},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on June 2, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Stable Adducts of a Dimeric Magnesium(I) Compound
journal, November 2008

  • Green, Shaun P.; Jones, Cameron; Stasch, Andreas
  • Angewandte Chemie, Vol. 120, Issue 47
  • DOI: 10.1002/ange.200803960

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Energy-band structure and charge distribution for BaC6
journal, April 1983

  • Holzwarth, N. A. W.; Divincenzo, D. P.; Tatar, R. C.
  • International Journal of Quantum Chemistry, Vol. 23, Issue 4
  • DOI: 10.1002/qua.560230412

Stable and High‐Power Calcium‐Ion Batteries Enabled by Calcium Intercalation into Graphite
journal, November 2019


Experimental Electron Density Study of the Mg−Mg Bonding Character in a Magnesium(I) Dimer
journal, April 2009

  • Overgaard, Jacob; Jones, Cameron; Stasch, Andreas
  • Journal of the American Chemical Society, Vol. 131, Issue 12
  • DOI: 10.1021/ja900385u

Electrochemical formation of graphite intercalation compound in magnesium chloride-dimethylsulphoxide solution
journal, May 1988


Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite
journal, May 2019


Graphite as a Long‐Life Ca 2+ ‐Intercalation Anode and its Implementation for Rocking‐Chair Type Calcium‐Ion Batteries
journal, October 2019

  • Richard Prabakar, S. J.; Ikhe, Amol Bhairuba; Park, Woon Bae
  • Advanced Science, Vol. 6, Issue 24
  • DOI: 10.1002/advs.201902129

Cointercalation of Mg 2+ Ions into Graphite for Magnesium-Ion Batteries
journal, May 2018


Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries
journal, January 2018


Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents
journal, January 2011

  • Stasch, Andreas; Jones, Cameron
  • Dalton Transactions, Vol. 40, Issue 21
  • DOI: 10.1039/c0dt01831g

Ball milling: a new route for the synthesis of superdense lithium GICs
journal, October 2001


Molecular Magnesium(I) Compounds: From Curiosity to Kudos
journal, March 2008

  • Westerhausen, Matthias
  • Angewandte Chemie International Edition, Vol. 47, Issue 12
  • DOI: 10.1002/anie.200705758

PDFgetX3 : a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions
journal, March 2013


Lithium ion battery applications of molybdenum disulfide (MoS 2 ) nanocomposites
journal, January 2014

  • Stephenson, Tyler; Li, Zhi; Olsen, Brian
  • Energy Environ. Sci., Vol. 7, Issue 1
  • DOI: 10.1039/C3EE42591F

Neutron scattering study of the high-energy graphitic phonons in superconducting CaC 6
journal, July 2010


Neutron-diffraction studies of BaC 6 : c -axis compressibility, carbon carbon bond length, and charge transfer
journal, September 1987


Intercalation behaviour of magnesium into natural graphite using organic electrolyte systems
journal, January 2017

  • God, C.; Bitschnau, B.; Kapper, K.
  • RSC Advances, Vol. 7, Issue 23
  • DOI: 10.1039/C6RA28300D

Nonadiabatic phonons within the doped graphene layers of X C 6 compounds
journal, January 2010

  • Dean, Mark P. M.; Howard, Christopher A.; Saxena, Siddharth S.
  • Physical Review B, Vol. 81, Issue 4
  • DOI: 10.1103/PhysRevB.81.045405

A Dimeric Magnesium(I) Compound as a Facile Two-Center/Two-Electron Reductant
journal, March 2009

  • Bonyhady, Simon J.; Green, Shaun P.; Jones, Cameron
  • Angewandte Chemie International Edition, Vol. 48, Issue 16
  • DOI: 10.1002/anie.200900331

Solid Lithium-Silicon Electrode
journal, January 1976

  • Lai, San-Cheng
  • Journal of The Electrochemical Society, Vol. 123, Issue 8
  • DOI: 10.1149/1.2133033

Multi-ion strategies towards emerging rechargeable batteries with high performance
journal, December 2019


Stable Magnesium(I) Compounds with Mg-Mg Bonds
journal, December 2007


Mapping the Challenges of Magnesium Battery
journal, April 2016

  • Song, Jaehee; Sahadeo, Emily; Noked, Malachi
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 9
  • DOI: 10.1021/acs.jpclett.6b00384

Reviving bulky MoS 2 as an advanced anode for lithium-ion batteries
journal, January 2019

  • Li, Shicai; Liu, Ping; Huang, Xiaobing
  • Journal of Materials Chemistry A, Vol. 7, Issue 18
  • DOI: 10.1039/C9TA01089K

Barium intra-atomic reconfiguration in BaC 6
journal, September 1984


Dependence of Lithium-Silicon Electrode Potential and Lithium Utilization on Reference Electrode Location
journal, January 1980

  • Seefurth, Randall N.
  • Journal of The Electrochemical Society, Vol. 127, Issue 5
  • DOI: 10.1149/1.2129824

Metallic anodes for next generation secondary batteries
journal, January 2013

  • Kim, Hansu; Jeong, Goojin; Kim, Young-Ugk
  • Chemical Society Reviews, Vol. 42, Issue 23
  • DOI: 10.1039/c3cs60177c

Electrochemical behavior of superdense ‘LiC2’ prepared by ball-milling
journal, April 2003


Contribution of X-ray Photoelectron Spectroscopy to the Study of the Electrochemical Reactivity of CoO toward Lithium
journal, March 2004

  • Dedryvère, R.; Laruelle, S.; Grugeon, S.
  • Chemistry of Materials, Vol. 16, Issue 6
  • DOI: 10.1021/cm0311269

New synthesis routes for donor-type graphite intercalation compounds
journal, June 1996


Stable Adducts of a Dimeric Magnesium(I) Compound
journal, November 2008

  • Green, Shaun P.; Jones, Cameron; Stasch, Andreas
  • Angewandte Chemie International Edition, Vol. 47, Issue 47
  • DOI: 10.1002/anie.200803960

A New and Facile Route Using Electride Solutions To Intercalate Alkaline Earth Ions into Graphite
journal, September 2018


Investigation of Lithium Utilization from A Lithium-Silicon Electrode
journal, January 1977

  • Seefurth, Randall N.
  • Journal of The Electrochemical Society, Vol. 124, Issue 8
  • DOI: 10.1149/1.2133529

Effect of the Addition of Bivalent Ions on Electrochemical Lithium-Ion Intercalation at Graphite Electrodes
journal, January 2016

  • Takeuchi, Saya; Kokumai, Ryohei; Nagata, Shingo
  • Journal of The Electrochemical Society, Vol. 163, Issue 8
  • DOI: 10.1149/2.1031608jes

Synthesis and XPS investigation of superdense lithium-graphite intercalation compound, LiC2
journal, July 1996


Confession of a Magnesium Battery
journal, August 2015

  • Bucur, Claudiu B.; Gregory, Thomas; Oliver, Allen G.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 18
  • DOI: 10.1021/acs.jpclett.5b01219

A Dimeric Magnesium(I) Compound as a Facile Two-Center/Two-Electron Reductant
journal, March 2009

  • Bonyhady, Simon J.; Green, Shaun P.; Jones, Cameron
  • Angewandte Chemie, Vol. 121, Issue 16
  • DOI: 10.1002/ange.200900331

Molekulare Magnesium(I)-Verbindungen – mehr als nur eine Laborkuriosität
journal, March 2008