A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes

Desnoyer, Addison N.; Nicolay, Amélie; Ziegler, Micah S.; Torquato, Nicole A.; Tilley, T. Don

doi:10.1002/anie.202004346

Title: A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes

Journal Article · 28 May 2020 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202004346 · OSTI ID:1631476

^[1];

^[1]; Torquato, Nicole A. ^[2];

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Department of Chemistry University of California, Berkeley Berkeley CA 94720-1460 USA, Chemical Sciences Division Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Department of Chemistry University of California, Berkeley Berkeley CA 94720-1460 USA

Abstract Reduction of a dicopper(II) bis(hydroxide) complex with silanes in the presence of external copper or silver cations results in the formation of multinuclear hydride clusters, which were characterized by a variety of NMR spectroscopic experiments and X‐ray crystallography. In particular, the pentanuclear complexes adopt an unusual planar “bow tie” configuration. The copper hydride complexes are efficient catalysts for the dehydrogenation of formic acid to H ₂ and CO ₂ .

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1631476

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 31 Vol. 59; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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