skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on May 21, 2021

Title: Pt–Co truncated octahedral nanocrystals: a class of highly active and durable catalysts toward oxygen reduction

Abstract

Pt–Co truncated octahedral nanocrystals were synthesized and evaluated as a class of highly active and durable catalysts toward oxygen reduction.

Authors:
 [1]; ORCiD logo [2];  [3];  [3];  [4];  [2];  [5];  [2]; ORCiD logo [5]; ORCiD logo [3]; ORCiD logo [6]; ORCiD logo [7]
  1. The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University, Atlanta, USA, State Key Laboratory of Structural Chemistry
  2. School of Chemistry and Biochemistry, Georgia Institute of Technology, Atlanta, USA
  3. Department of Chemical and Biomolecular Engineering, Vanderbilt University, Nashville, USA
  4. The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University, Atlanta, USA
  5. Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, USA
  6. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
  7. The Wallace H. Coulter Department of Biomedical Engineering, Georgia Institute of Technology and Emory University, Atlanta, USA, School of Chemistry and Biochemistry
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1630951
Grant/Contract Number:  
EE-000765
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Nanoscale
Additional Journal Information:
Journal Name: Nanoscale Journal Volume: 12 Journal Issue: 21; Journal ID: ISSN 2040-3364
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Shen, Min, Xie, Minghao, Slack, John, Waldrop, Krysta, Chen, Zitao, Lyu, Zhiheng, Cao, Shaohong, Zhao, Ming, Chi, Miaofang, Pintauro, Peter N., Cao, Rong, and Xia, Younan. Pt–Co truncated octahedral nanocrystals: a class of highly active and durable catalysts toward oxygen reduction. United Kingdom: N. p., 2020. Web. doi:10.1039/D0NR02904A.
Shen, Min, Xie, Minghao, Slack, John, Waldrop, Krysta, Chen, Zitao, Lyu, Zhiheng, Cao, Shaohong, Zhao, Ming, Chi, Miaofang, Pintauro, Peter N., Cao, Rong, & Xia, Younan. Pt–Co truncated octahedral nanocrystals: a class of highly active and durable catalysts toward oxygen reduction. United Kingdom. doi:https://doi.org/10.1039/D0NR02904A
Shen, Min, Xie, Minghao, Slack, John, Waldrop, Krysta, Chen, Zitao, Lyu, Zhiheng, Cao, Shaohong, Zhao, Ming, Chi, Miaofang, Pintauro, Peter N., Cao, Rong, and Xia, Younan. Thu . "Pt–Co truncated octahedral nanocrystals: a class of highly active and durable catalysts toward oxygen reduction". United Kingdom. doi:https://doi.org/10.1039/D0NR02904A.
@article{osti_1630951,
title = {Pt–Co truncated octahedral nanocrystals: a class of highly active and durable catalysts toward oxygen reduction},
author = {Shen, Min and Xie, Minghao and Slack, John and Waldrop, Krysta and Chen, Zitao and Lyu, Zhiheng and Cao, Shaohong and Zhao, Ming and Chi, Miaofang and Pintauro, Peter N. and Cao, Rong and Xia, Younan},
abstractNote = {Pt–Co truncated octahedral nanocrystals were synthesized and evaluated as a class of highly active and durable catalysts toward oxygen reduction.},
doi = {10.1039/D0NR02904A},
journal = {Nanoscale},
number = 21,
volume = 12,
place = {United Kingdom},
year = {2020},
month = {6}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on May 21, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Achievements, challenges and perspectives on cathode catalysts in proton exchange membrane fuel cells for transportation
journal, July 2019


Nickel-catalysed synthesis of 3-chloroanilines and chloro aminopyridines via cross-coupling reactions of aryl and heteroaryl dichlorides with amines
journal, January 2001


Materials for fuel-cell technologies
journal, November 2001

  • Steele, Brian C. H.; Heinzel, Angelika
  • Nature, Vol. 414, Issue 6861, p. 345-352
  • DOI: 10.1038/35104620

Highly Active and Durable Co-Doped Pt/CCC Cathode Catalyst for Polymer Electrolyte Membrane Fuel Cells
journal, June 2015


Shape-Controlled Synthesis of Pt3Co Nanocrystals with High Electrocatalytic Activity toward Oxygen Reduction
journal, September 2011

  • Choi, Sang-Il; Choi, Ran; Han, Sang Woo
  • Chemistry - A European Journal, Vol. 17, Issue 44
  • DOI: 10.1002/chem.201101138

Electrochemistry and the Future of the Automobile
journal, June 2010

  • Wagner, Frederick T.; Lakshmanan, Balasubramanian; Mathias, Mark F.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 14
  • DOI: 10.1021/jz100553m

A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research
journal, April 2011


Observation of Single Colloidal Platinum Nanocrystal Growth Trajectories
journal, June 2009


Unlocking the door to highly active ORR catalysts for PEMFC applications: polyhedron-engineered Pt-based nanocrystals
journal, January 2018

  • Wang, Yan-Jie; Long, Wenyu; Wang, Lele
  • Energy & Environmental Science, Vol. 11, Issue 2
  • DOI: 10.1039/C7EE02444D

Synthesis and Oxygen Reduction Activity of Shape-Controlled Pt 3 Ni Nanopolyhedra
journal, February 2010

  • Zhang, Jun; Yang, Hongzhou; Fang, Jiye
  • Nano Letters, Vol. 10, Issue 2
  • DOI: 10.1021/nl903717z

Highly durable fuel cell electrodes based on ionomers dispersed in glycerol
journal, January 2014

  • Kim, Y. S.; Welch, C. F.; Mack, N. H.
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 13
  • DOI: 10.1039/C4CP00496E

Development of Method for Synthesis of Pt–Co Cathode Catalysts for PEM Fuel Cells
journal, January 2007

  • Li, Xuguang; Colón-Mercado, Héctor R.; Wu, Gang
  • Electrochemical and Solid-State Letters, Vol. 10, Issue 11
  • DOI: 10.1149/1.2777009

Low-Temperature Chemical Vapor Deposition Synthesis of Pt-Co Alloyed Nanoparticles with Enhanced Oxygen Reduction Reaction Catalysis
journal, June 2016

  • Choi, Dong Sung; Robertson, Alex W.; Warner, Jamie H.
  • Advanced Materials, Vol. 28, Issue 33
  • DOI: 10.1002/adma.201600469

The stability of Pt–M (M=first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells
journal, October 2006


Platinum-Based Oxygen Reduction Electrocatalysts
journal, April 2013

  • Wu, Jianbo; Yang, Hong
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300359w

Platinum-Based Nanostructured Materials: Synthesis, Properties, and Applications
journal, June 2010

  • Chen, Aicheng; Holt-Hindle, Peter
  • Chemical Reviews, Vol. 110, Issue 6
  • DOI: 10.1021/cr9003902

Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces
journal, February 2007

  • Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias
  • Nature Materials, Vol. 6, Issue 3, p. 241-247
  • DOI: 10.1038/nmat1840

Fe Stabilization by Intermetallic L1 0 -FePt and Pt Catalysis Enhancement in L1 0 -FePt/Pt Nanoparticles for Efficient Oxygen Reduction Reaction in Fuel Cells
journal, February 2018

  • Li, Junrui; Xi, Zheng; Pan, Yung-Tin
  • Journal of the American Chemical Society, Vol. 140, Issue 8
  • DOI: 10.1021/jacs.7b12829

Synthesis of FePt Nanocubes and Their Oriented Self-Assembly
journal, June 2006

  • Chen, Min; Kim, Jaemin; Liu, J. P.
  • Journal of the American Chemical Society, Vol. 128, Issue 22
  • DOI: 10.1021/ja061704x

Electrocatalyst approaches and challenges for automotive fuel cells
journal, June 2012


Just a Dream—or Future Reality?
journal, April 2009


A General Approach to the Size- and Shape-Controlled Synthesis of Platinum Nanoparticles and Their Catalytic Reduction of Oxygen
journal, April 2008

  • Wang, Chao; Daimon, Hideo; Onodera, Taigo
  • Angewandte Chemie International Edition, Vol. 47, Issue 19
  • DOI: 10.1002/anie.200800073

Shape-Controlled Synthesis of Pt Nanocrystals: The Role of Metal Carbonyls
journal, December 2012

  • Kang, Yijin; Pyo, Jun Beom; Ye, Xingchen
  • ACS Nano, Vol. 7, Issue 1
  • DOI: 10.1021/nn3048439

Pt Nanocrystals:  Shape Control and Langmuir−Blodgett Monolayer Formation
journal, January 2005

  • Song, Hyunjoon; Kim, Franklin; Connor, Stephen
  • The Journal of Physical Chemistry B, Vol. 109, Issue 1
  • DOI: 10.1021/jp0464775

Synthesis and Characterization of 9 nm Pt–Ni Octahedra with a Record High Activity of 3.3 A/mg Pt for the Oxygen Reduction Reaction
journal, June 2013

  • Choi, Sang-Il; Xie, Shuifen; Shao, Minhua
  • Nano Letters, Vol. 13, Issue 7
  • DOI: 10.1021/nl401881z

Nucleation and Growth Mechanism of Ni x Pt 1-x Nanoparticles
journal, December 2008

  • Ahrenstorf, Kirsten; Heller, Hauke; Kornowski, Andreas
  • Advanced Functional Materials, Vol. 18, Issue 23
  • DOI: 10.1002/adfm.200800642

Advanced Platinum Alloy Electrocatalysts for the Oxygen Reduction Reaction
journal, April 2012

  • Wang, Chao; Markovic, Nenad M.; Stamenkovic, Vojislav R.
  • ACS Catalysis, Vol. 2, Issue 5
  • DOI: 10.1021/cs3000792

Surface engineering of hierarchical platinum-cobalt nanowires for efficient electrocatalysis
journal, June 2016

  • Bu, Lingzheng; Guo, Shaojun; Zhang, Xu
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms11850

Recoverable Performance Loss Due to Membrane Chemical Degradation in PEM Fuel Cells
journal, January 2012

  • Zhang, Jingxin; Litteer, Brian A.; Coms, Frank D.
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.063207jes

The Role of Platinum in Proton Exchange Membrane Fuel Cells
journal, October 2013


Role of Structural and Electronic Properties of Pt and Pt Alloys on Electrocatalysis of Oxygen Reduction
journal, January 1995

  • Mukerjee, Sanjeev; Srinivasan, Supramaniam; Soriaga, Manuel P.
  • Journal of The Electrochemical Society, Vol. 142, Issue 5, p. 1409-1422
  • DOI: 10.1149/1.2048590

Shape and Composition-Controlled Platinum Alloy Nanocrystals Using Carbon Monoxide as Reducing Agent
journal, February 2011

  • Wu, Jianbo; Gross, Adam; Yang, Hong
  • Nano Letters, Vol. 11, Issue 2
  • DOI: 10.1021/nl104094p

Polyol Synthesis of Platinum Nanostructures: Control of Morphology through the Manipulation of Reduction Kinetics
journal, April 2005

  • Chen, Jingyi; Herricks, Thurston; Xia, Younan
  • Angewandte Chemie International Edition, Vol. 44, Issue 17
  • DOI: 10.1002/anie.200462668

Enhancing by Weakening: Electrooxidation of Methanol on Pt3Co and Pt Nanocubes
journal, August 2010

  • Yang, Hongzhou; Zhang, Jun; Sun, Kai
  • Angewandte Chemie International Edition, Vol. 49, Issue 38
  • DOI: 10.1002/anie.201002888

Alloys of platinum and early transition metals as oxygen reduction electrocatalysts
journal, September 2009

  • Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S.
  • Nature Chemistry, Vol. 1, Issue 7, p. 552-556
  • DOI: 10.1038/nchem.367

Improved Oxygen Reduction Activity on Pt3Ni(111) via Increased Surface Site Availability
journal, January 2007

  • Stamenkovic, V. R.; Fowler, B.; Mun, B. S.
  • Science, Vol. 315, Issue 5811, p. 493-497
  • DOI: 10.1126/science.1135941