Polysulfone shock compressed above the decomposition threshold: Velocimetry and modeling of two-wave structures

Huber, Rachel Colleen; Peterson, Jeffrey Hammett; Coe, Joshua Damon; Dattelbaum, Dana Mcgraw; Gibson, Lloyd Lee; Gustavsen, Richard L.; Lang, J. M.; Sheffield, Stephen A.

doi:10.1063/1.5124252

Title: Polysulfone shock compressed above the decomposition threshold: Velocimetry and modeling of two-wave structures

Journal Article · 10 March 2020 · Journal of Applied Physics

DOI: https://doi.org/10.1063/1.5124252 · OSTI ID:1630852

^[1];

^[1]; Gibson, Lloyd Lee ^[1];

^[1];

^[1]; Sheffield, Stephen A. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Polysulfone was shock loaded to pressures of 14.6–26.2 GPa in a series of gas gun-driven plate-impact experiments measuring material response with embedded electro-magnetic particle velocity gauges and optical velocimetry. The embedded electro-magnetic particle velocity gauges did not show a distinct two-wave structure but did show rounding that suggested a reaction but not a distinct separation of the reactants and product waves. In contrast, the transmission experiments fielded with optical velocimetry, with product pressures ranging from 21.0 to 26.2 GPa, showed well-defined two-wave structures due to shock-driven chemical decomposition of the polymer to products at a higher density. Distinct two-wave structures have not previously been published in literature during polymer compression; here, we observed these two-wave structures at both the polymer/lithium fluoride and polymer/polymethylmethacrylate interfaces. Hydrodynamic simulations of the experiments were performed using a newly constructed SESAME equation of state (EOS) for the polymer, a thermochemical EOS for the decomposition products, and an Arrhenius reaction rate model for the kinetics of the reaction. Finally, simulation results also demonstrated two-wave structures but were unable to quantitatively reproduce either the embedded gauge or optical velocimetry data.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: 89233218CNA000001

OSTI ID:: 1630852

Report Number(s):: LA-UR--19-25132

Journal Information:: Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 10 Vol. 127; ISSN 0021-8979

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Polysulfone shock compressed above the decomposition threshold: Velocimetry and modeling of two-wave structures

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