Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds

Qiao, Yongqiang; Song, Yuzhu; Xu, Meng; Gao, Qilong; Ren, Yang; Xing, Xianran; Chen, Jun

doi:10.1039/C9QI00819E

Title: Controllable thermal expansion and magnetic structure in Er ₂ (Fe,Co) ₁₄ B intermetallic compounds

Journal Article · 19 September 2019 · Inorganic Chemistry Frontiers (Online)

DOI: https://doi.org/10.1039/C9QI00819E · OSTI ID:1630421

Qiao, Yongqiang ^[1]; Song, Yuzhu ^[1]; Xu, Meng ^[1]; Gao, Qilong ^[2]; Ren, Yang ^[3]; Xing, Xianran ^[1];

^[1]

Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering, and Dept. of Physical Chemistry
Zhengzhou Univ. (China). School of Physics and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States)

The control of thermal expansion is attractive but remains challenging for the studies of negative thermal expansion materials. Here, we report a continuously controllable thermal expansion from negative to positive by means of adjusting the magnetic moment of Fe in Er₂(Fe,Co)₁₄B intermetallic compounds. Interestingly, a zero thermal expansion (ZTE) has been achieved in a wide temperature range (ΔT = 355 K), which is larger than most existing ZTE alloys. The spontaneous magnetostriction (ω_S) reveals a negative contribution arising from the magneto-volume effect to the controllable thermal expansion. The present study could be suitable for the design of controllable thermal expansion of other alloys related to the magneto-volume effect.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; China Postdoctoral Science Foundation

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1630421

Journal Information:: Inorganic Chemistry Frontiers (Online), Vol. 6, Issue 11; ISSN 2052-1553

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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