Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds

Qiao, Yongqiang; Song, Yuzhu; Xu, Meng; Gao, Qilong; Ren, Yang; Xing, Xianran; Chen, Jun

doi:10.1039/C9QI00819E

Title: Controllable thermal expansion and magnetic structure in Er ₂ (Fe,Co) ₁₄ B intermetallic compounds

Abstract

The control of thermal expansion is attractive but remains challenging for the studies of negative thermal expansion materials. Here, we report a continuously controllable thermal expansion from negative to positive by means of adjusting the magnetic moment of Fe in Er₂(Fe,Co)₁₄B intermetallic compounds. Interestingly, a zero thermal expansion (ZTE) has been achieved in a wide temperature range (ΔT = 355 K), which is larger than most existing ZTE alloys. The spontaneous magnetostriction (ω_S) reveals a negative contribution arising from the magneto-volume effect to the controllable thermal expansion. The present study could be suitable for the design of controllable thermal expansion of other alloys related to the magneto-volume effect.

Authors:

Qiao, Yongqiang ^[1]; Song, Yuzhu ^[1]; Xu, Meng ^[1]; Gao, Qilong ^[2]; Ren, Yang ^[3]; Xing, Xianran ^[1];

^[1]

Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering, and Dept. of Physical Chemistry
Zhengzhou Univ. (China). School of Physics and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: 2019-09-19

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; China Postdoctoral Science Foundation

OSTI Identifier:: 1630421

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry Frontiers (Online)

Additional Journal Information:: Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 6; Journal Issue: 11; Journal ID: ISSN 2052-1553

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, and Chen, Jun. Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds.  United States: N. p., 2019. 
Web.  doi:10.1039/C9QI00819E.

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                    Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, & Chen, Jun. Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds.  United States.  https://doi.org/10.1039/C9QI00819E

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                    Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, and Chen, Jun. Thu .  
"Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds".  United States.  https://doi.org/10.1039/C9QI00819E.  https://www.osti.gov/servlets/purl/1630421.

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@article{osti_1630421,

  title        = {Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds},

  author       = {Qiao, Yongqiang and Song, Yuzhu and Xu, Meng and Gao, Qilong and Ren, Yang and Xing, Xianran and Chen, Jun},

  abstractNote = {The control of thermal expansion is attractive but remains challenging for the studies of negative thermal expansion materials. Here, we report a continuously controllable thermal expansion from negative to positive by means of adjusting the magnetic moment of Fe in Er2(Fe,Co)14B intermetallic compounds. Interestingly, a zero thermal expansion (ZTE) has been achieved in a wide temperature range (ΔT = 355 K), which is larger than most existing ZTE alloys. The spontaneous magnetostriction (ωS) reveals a negative contribution arising from the magneto-volume effect to the controllable thermal expansion. The present study could be suitable for the design of controllable thermal expansion of other alloys related to the magneto-volume effect.},

  doi          = {10.1039/C9QI00819E},

  journal      = {Inorganic Chemistry Frontiers (Online)},

  number       = 11,

  volume       = 6,

  place        = {United States},

  year         = {2019},

  month        = {9}

}

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Title: Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds

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Negative thermal expansion in Ge-free antiperovskite manganese nitrides: Tin-doping effect
journal, January 2008

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF ₃
journal, November 2010

Opposite Thermal Expansion in Isostructural Noncollinear Antiferromagnetic Compounds of Mn ₃ A (A = Ge and Sn)
journal, September 2018

Tunable thermal expansion in framework materials through redox intercalation
journal, February 2017

Colossal negative thermal expansion induced by magnetic phase competition on frustrated lattices in Laves phase compound (Hf,Ta) ${Fe}_{2}$
journal, June 2016

Tuning the range, magnitude, and sign of the thermal expansion in intermetallic Mn $_{3}$ (Zn, $M$ ) $_{x}$ N( $M$ $=$ Ag, Ge)
journal, June 2012

Zero Thermal Expansion in Magnetic and Metallic Tb(Co,Fe) ₂ Intermetallic Compounds
journal, January 2018

Synthesis and thermal expansion of ZrO2/ZrW2O8 composites
journal, November 2005

Neutron‐diffraction and Mössbauer effect study of the preferential silicon site occupation and magnetic structure of Nd ₂ Fe _{14− x} Si _x B
journal, December 1993

Guest-Dependent Negative Thermal Expansion in Nanoporous Prussian Blue Analogues M ^II Pt ^IV (CN) ₆ · x {H ₂ O} (0 ≤ x ≤ 2; M = Zn, Cd)
journal, December 2005

Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds
journal, July 2013

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

Single crystal neutron diffraction investigations of the crystal and magnetic structures of R2Fe14B (R=Y, Nd, Ho, Er)
journal, April 2001

Invar effect in R2Fe14B compounds (R  La, Ce, Nd, Sm, Gd, Er)
journal, April 1986

Influence of Co substitution on magnetoelastic properties of Er2Fe14−xCoxB (x=1, 3 and 5) intermetallic compounds
journal, July 2009

Good comprehensive performance of Laves phase Hf1-Ta Fe2 as negative thermal expansion materials
journal, December 2018

Magnetic behavior and anomalous thermal expansion of Nd ₂ (Fe _{1− x} Mn _x ) ₁ ₄ B
journal, November 1988