Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds
Abstract
The control of thermal expansion is attractive but remains challenging for the studies of negative thermal expansion materials. Here, we report a continuously controllable thermal expansion from negative to positive by means of adjusting the magnetic moment of Fe in Er2(Fe,Co)14B intermetallic compounds. Interestingly, a zero thermal expansion (ZTE) has been achieved in a wide temperature range (ΔT = 355 K), which is larger than most existing ZTE alloys. The spontaneous magnetostriction (ωS) reveals a negative contribution arising from the magneto-volume effect to the controllable thermal expansion. The present study could be suitable for the design of controllable thermal expansion of other alloys related to the magneto-volume effect.
- Authors:
-
- Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering, and Dept. of Physical Chemistry
- Zhengzhou Univ. (China). School of Physics and Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; China Postdoctoral Science Foundation
- OSTI Identifier:
- 1630421
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry Frontiers (Online)
- Additional Journal Information:
- Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 6; Journal Issue: 11; Journal ID: ISSN 2052-1553
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, and Chen, Jun. Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds. United States: N. p., 2019.
Web. doi:10.1039/C9QI00819E.
Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, & Chen, Jun. Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds. United States. https://doi.org/10.1039/C9QI00819E
Qiao, Yongqiang, Song, Yuzhu, Xu, Meng, Gao, Qilong, Ren, Yang, Xing, Xianran, and Chen, Jun. Thu .
"Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds". United States. https://doi.org/10.1039/C9QI00819E. https://www.osti.gov/servlets/purl/1630421.
@article{osti_1630421,
title = {Controllable thermal expansion and magnetic structure in Er 2 (Fe,Co) 14 B intermetallic compounds},
author = {Qiao, Yongqiang and Song, Yuzhu and Xu, Meng and Gao, Qilong and Ren, Yang and Xing, Xianran and Chen, Jun},
abstractNote = {The control of thermal expansion is attractive but remains challenging for the studies of negative thermal expansion materials. Here, we report a continuously controllable thermal expansion from negative to positive by means of adjusting the magnetic moment of Fe in Er2(Fe,Co)14B intermetallic compounds. Interestingly, a zero thermal expansion (ZTE) has been achieved in a wide temperature range (ΔT = 355 K), which is larger than most existing ZTE alloys. The spontaneous magnetostriction (ωS) reveals a negative contribution arising from the magneto-volume effect to the controllable thermal expansion. The present study could be suitable for the design of controllable thermal expansion of other alloys related to the magneto-volume effect.},
doi = {10.1039/C9QI00819E},
journal = {Inorganic Chemistry Frontiers (Online)},
number = 11,
volume = 6,
place = {United States},
year = {2019},
month = {9}
}
Web of Science
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