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Title: Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging

Abstract

Conventionally, battery electrodes are rationalized as homogeneous reactors. It proves to be an erroneous interpretation for fast transients, where mass transport limitations amplify underlying heterogeneities. Given the lack of observability of associated fast spatiotemporal dynamics, redox activity in inhomogeneous electrodes is superficially explored. We resort to a physics-based description to examine the extreme fast charging of lithium-ion battery electrodes. Representative inhomogeneity information is extracted from electrode tomograms. We discover such electrodes to undergo preferential intercalation, localized lithium plating and nonuniform heat generation as a result of distributed long- and short-range interactions. The spatial correlations of these events with the underlying inhomogeneity are found to be nonidentical. Investigation of multiple inhomogeneity fields reveals an exponential scaling of plating severity and early onset in contrast to the homogeneous limit. Anode and cathode inhomogeneities couple nonlinearly to grow peculiar electrodeposition patterns. These mechanistic insights annotate the complex functioning of spatially nonuniform electrodes.

Authors:
ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo; ORCiD logo
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office
OSTI Identifier:
1630233
Alternate Identifier(s):
OSTI ID: 1660026
Report Number(s):
NREL/JA-5400-77255
Journal ID: ISSN 1945-7111
Grant/Contract Number:  
AC36-08GO28308
Resource Type:
Published Article
Journal Name:
Journal of the Electrochemical Society (Online)
Additional Journal Information:
Journal Name: Journal of the Electrochemical Society (Online) Journal Volume: 167 Journal Issue: 9; Journal ID: ISSN 1945-7111
Publisher:
IOP Publishing
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; fast charging batteries; lithium-ion batteries; redox reactions

Citation Formats

Mistry, Aashutosh, Usseglio-Viretta, Francois L. E., Colclasure, Andrew, Smith, Kandler, and Mukherjee, Partha P. Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging. United States: N. p., 2020. Web. doi:10.1149/1945-7111/ab8fd7.
Mistry, Aashutosh, Usseglio-Viretta, Francois L. E., Colclasure, Andrew, Smith, Kandler, & Mukherjee, Partha P. Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging. United States. doi:https://doi.org/10.1149/1945-7111/ab8fd7
Mistry, Aashutosh, Usseglio-Viretta, Francois L. E., Colclasure, Andrew, Smith, Kandler, and Mukherjee, Partha P. Wed . "Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging". United States. doi:https://doi.org/10.1149/1945-7111/ab8fd7.
@article{osti_1630233,
title = {Fingerprinting Redox Heterogeneity in Electrodes during Extreme Fast Charging},
author = {Mistry, Aashutosh and Usseglio-Viretta, Francois L. E. and Colclasure, Andrew and Smith, Kandler and Mukherjee, Partha P.},
abstractNote = {Conventionally, battery electrodes are rationalized as homogeneous reactors. It proves to be an erroneous interpretation for fast transients, where mass transport limitations amplify underlying heterogeneities. Given the lack of observability of associated fast spatiotemporal dynamics, redox activity in inhomogeneous electrodes is superficially explored. We resort to a physics-based description to examine the extreme fast charging of lithium-ion battery electrodes. Representative inhomogeneity information is extracted from electrode tomograms. We discover such electrodes to undergo preferential intercalation, localized lithium plating and nonuniform heat generation as a result of distributed long- and short-range interactions. The spatial correlations of these events with the underlying inhomogeneity are found to be nonidentical. Investigation of multiple inhomogeneity fields reveals an exponential scaling of plating severity and early onset in contrast to the homogeneous limit. Anode and cathode inhomogeneities couple nonlinearly to grow peculiar electrodeposition patterns. These mechanistic insights annotate the complex functioning of spatially nonuniform electrodes.},
doi = {10.1149/1945-7111/ab8fd7},
journal = {Journal of the Electrochemical Society (Online)},
number = 9,
volume = 167,
place = {United States},
year = {2020},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
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DOI: https://doi.org/10.1149/1945-7111/ab8fd7

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Works referenced in this record:

Multiscale Simulation Platform Linking Lithium Ion Battery Electrode Fabrication Process with Performance at the Cell Level
journal, November 2017

  • Ngandjong, Alain C.; Rucci, Alexis; Maiza, Mariem
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 23
  • DOI: 10.1021/acs.jpclett.7b02647

Editors' Choice—Mesoscale Analysis of Conductive Binder Domain Morphology in Lithium-Ion Battery Electrodes
journal, January 2018

  • Trembacki, Bradley L.; Mistry, Aashutosh N.; Noble, David R.
  • Journal of The Electrochemical Society, Vol. 165, Issue 13
  • DOI: 10.1149/2.0981813jes

Analysis of Long-Range Interaction in Lithium-Ion Battery Electrodes
journal, August 2016

  • Mistry, Aashutosh; Juarez-Robles, Daniel; Stein, Malcolm
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3
  • DOI: 10.1115/1.4035198

Transport-Geometry Interactions in Li-Ion Cathode Materials Imaged Using X-ray Nanotomography
journal, January 2017

  • Nelson, George J.; Ausderau, Logan J.; Shin, SeungYoon
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.0261707jes

The low temperature performance of Li-ion batteries
journal, March 2003


Resolving the Discrepancy in Tortuosity Factor Estimation for Li-Ion Battery Electrodes through Micro-Macro Modeling and Experiment
journal, January 2018

  • Usseglio-Viretta, Francois L. E.; Colclasure, Andrew; Mistry, Aashutosh N.
  • Journal of The Electrochemical Society, Vol. 165, Issue 14
  • DOI: 10.1149/2.0731814jes

A Critical Review of Thermal Issues in Lithium-Ion Batteries
journal, January 2011

  • Bandhauer, Todd M.; Garimella, Srinivas; Fuller, Thomas F.
  • Journal of The Electrochemical Society, Vol. 158, Issue 3, p. R1-R25
  • DOI: 10.1149/1.3515880

Generic Model Control for Lithium-Ion Batteries
journal, January 2017

  • Pathak, Manan; Kolluri, Suryanarayana; Subramanian, Venkat R.
  • Journal of The Electrochemical Society, Vol. 164, Issue 6
  • DOI: 10.1149/2.1521704jes

Direct in situ measurements of Li transport in Li-ion battery negative electrodes
journal, January 2010


Fast Charging of Li-Ion Cells: Part I. Using Li/Cu Reference Electrodes to Probe Individual Electrode Potentials
journal, January 2019

  • Rodrigues, Marco-Tulio F.; Kalaga, Kaushik; Trask, Stephen E.
  • Journal of The Electrochemical Society, Vol. 166, Issue 6
  • DOI: 10.1149/2.0401906jes

The 2018 Edward G. Weston Summer Research Fellowship – Summary Report: Curvature Effects in Precipitation Dynamics
journal, January 2018

  • Mistry, Aashutosh
  • The Electrochemical Society Interface, Vol. 27, Issue 4
  • DOI: 10.1149/2.F10184if

Quantifying lithium concentration gradients in the graphite electrode of Li-ion cells using operando energy dispersive X-ray diffraction
journal, January 2019

  • Yao, Koffi P. C.; Okasinski, John S.; Kalaga, Kaushik
  • Energy & Environmental Science, Vol. 12, Issue 2
  • DOI: 10.1039/C8EE02373E

Spatially Resolving Lithiation in Silicon–Graphite Composite Electrodes via in Situ High-Energy X-ray Diffraction Computed Tomography
journal, April 2019


Probing chemical heterogeneity of Li-ion batteries by in operando high energy X-ray diffraction radiography
journal, November 2018


Quantitative and time-resolved detection of lithium plating on graphite anodes in lithium ion batteries
journal, April 2018


Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates
journal, January 2019

  • Jahrman, Evan P.; Pellerin, Lisa A.; Ditter, Alexander S.
  • Journal of The Electrochemical Society, Vol. 166, Issue 12
  • DOI: 10.1149/2.0721912jes

Electrochemistry-Mechanics Coupling in Intercalation Electrodes
journal, January 2018

  • Kotak, Nihar; Barai, Pallab; Verma, Ankit
  • Journal of The Electrochemical Society, Vol. 165, Issue 5
  • DOI: 10.1149/2.0621805jes

"Water-in-salt" electrolyte enables high-voltage aqueous lithium-ion chemistries
journal, November 2015


Theoretical versus Practical Energy: A Plea for More Transparency in the Energy Calculation of Different Rechargeable Battery Systems
journal, December 2018

  • Betz, Johannes; Bieker, Georg; Meister, Paul
  • Advanced Energy Materials, Vol. 9, Issue 6
  • DOI: 10.1002/aenm.201803170

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


Local Tortuosity Inhomogeneities in a Lithium Battery Composite Electrode
journal, January 2011

  • Kehrwald, Dirk; Shearing, Paul R.; Brandon, Nigel P.
  • Journal of The Electrochemical Society, Vol. 158, Issue 12
  • DOI: 10.1149/2.079112jes

Developments in X-ray tomography characterization for electrochemical devices
journal, December 2019


Challenges and opportunities towards fast-charging battery materials
journal, June 2019


Enabling fast charging – Infrastructure and economic considerations
journal, November 2017


Probing spatial coupling of resistive modes in porous intercalation electrodes through impedance spectroscopy
journal, January 2019

  • Mistry, Aashutosh N.; Mukherjee, Partha P.
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 7
  • DOI: 10.1039/C8CP05109G

Design of Battery Electrodes with Dual-Scale Porosity to Minimize Tortuosity and Maximize Performance
journal, December 2012

  • Bae, Chang-Jun; Erdonmez, Can K.; Halloran, John W.
  • Advanced Materials, Vol. 25, Issue 9
  • DOI: 10.1002/adma.201204055

A review of conduction phenomena in Li-ion batteries
journal, December 2010


Why do batteries fail?
journal, February 2016


Porous-electrode theory with battery applications
journal, January 1975


Measurement of Multiscale Thermal Transport Phenomena in Li-Ion Cells: A Review
journal, August 2016

  • Shah, Krishna; Vishwakarma, Vivek; Jain, Ankur
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3
  • DOI: 10.1115/1.4034413

Three-electrode Coin Cell Preparation and Electrodeposition Analytics for Lithium-ion Batteries
journal, January 2018

  • Minter, Robert D.; Juarez-Robles, Daniel; Fear, Conner
  • Journal of Visualized Experiments, Issue 135
  • DOI: 10.3791/57735

Influence of Conductive Additives and Binder on the Impedance of Lithium-Ion Battery Electrodes: Effect of Morphology
journal, January 2020

  • Hein, Simon; Danner, Timo; Westhoff, Daniel
  • Journal of The Electrochemical Society, Vol. 167, Issue 1
  • DOI: 10.1149/1945-7111/ab6b1d

Direct In Situ Observation and Numerical Simulations of Non-Shrinking-Core Behavior in an MCMB Graphite Composite Electrode
journal, January 2012

  • Harris, Stephen J.; Rahani, Ehsan Kabiri; Shenoy, Vivek B.
  • Journal of The Electrochemical Society, Vol. 159, Issue 9
  • DOI: 10.1149/2.055209jes

Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode
journal, January 2015

  • Bieker, Georg; Winter, Martin; Bieker, Peter
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 14
  • DOI: 10.1039/C4CP05865H

Ageing mechanisms in lithium-ion batteries
journal, September 2005


Fast charging of an electric vehicle lithium-ion battery at the limit of the lithium deposition process
journal, July 2019


Enabling fast charging of lithium-ion batteries through secondary-/dual- pore network: Part II - numerical model
journal, May 2020


Interplay of Operational Parameters on Lithium Deposition in Lithium-Ion Cells: Systematic Measurements with Reconstructed 3-Electrode Pouch Full Cells
journal, January 2016

  • Waldmann, Thomas; Hogg, Björn-Ingo; Kasper, Michael
  • Journal of The Electrochemical Society, Vol. 163, Issue 7
  • DOI: 10.1149/2.0591607jes

Cooperation between Active Material, Polymeric Binder and Conductive Carbon Additive in Lithium Ion Battery Cathode
journal, February 2012

  • Zheng, Honghe; Yang, Ruizhi; Liu, Gao
  • The Journal of Physical Chemistry C, Vol. 116, Issue 7
  • DOI: 10.1021/jp208428w

Enabling fast charging – A battery technology gap assessment
journal, November 2017


Mechanistic Understanding of the Role of Evaporation in Electrode Processing
journal, January 2017

  • Stein, Malcolm; Mistry, Aashutosh; Mukherjee, Partha P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1271707jes

Mesoscale Effective Property Simulations Incorporating Conductive Binder
journal, January 2017

  • Trembacki, Bradley L.; Noble, David R.; Brunini, Victor E.
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0601711jes

In Situ Observation and Mathematical Modeling of Lithium Distribution within Graphite
journal, January 2017

  • Thomas-Alyea, Karen E.; Jung, Changhoon; Smith, Raymond B.
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0061711jes

On our Limited Understanding of Electrodeposition
journal, January 2019


Quantifying Reaction and Rate Heterogeneity in Battery Electrodes in 3D through Operando X-ray Diffraction Computed Tomography
journal, April 2019

  • Liu, Hao; Kazemiabnavi, Saeed; Grenier, Antonin
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 20
  • DOI: 10.1021/acsami.9b02173

Mathematical Modeling of the Lithium Deposition Overcharge Reaction in Lithium-Ion Batteries Using Carbon-Based Negative Electrodes
journal, January 1999

  • Arora, Pankaj
  • Journal of The Electrochemical Society, Vol. 146, Issue 10
  • DOI: 10.1149/1.1392512

Requirements for Enabling Extreme Fast Charging of High Energy Density Li-Ion Cells while Avoiding Lithium Plating
journal, January 2019

  • Colclasure, Andrew M.; Dunlop, Alison R.; Trask, Stephen E.
  • Journal of The Electrochemical Society, Vol. 166, Issue 8
  • DOI: 10.1149/2.0451908jes

Quantifying Transport, Geometrical, and Morphological Parameters in Li-Ion Cathode Phases Using X-ray Microtomography
journal, May 2019

  • Rajendra, Thushananth; Mistry, Aashutosh N.; Patel, Prehit
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 22
  • DOI: 10.1021/acsami.8b22758

Effects of Various Conductive Additive and Polymeric Binder Contents on the Performance of a Lithium-Ion Composite Cathode
journal, January 2008

  • Liu, G.; Zheng, H.; Kim, S.
  • Journal of The Electrochemical Society, Vol. 155, Issue 12
  • DOI: 10.1149/1.2976031

Modeling of lithium plating and lithium stripping in lithium-ion batteries
journal, February 2019


Symmetry properties of macroscopic transport coefficients in porous media
journal, April 2017

  • Lasseux, D.; Valdés-Parada, F. J.
  • Physics of Fluids, Vol. 29, Issue 4
  • DOI: 10.1063/1.4979907

Stochasticity at Scales Leads to Lithium Intercalation Cascade
journal, March 2020

  • Mistry, Aashutosh; Smith, Kandler; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 12, Issue 14
  • DOI: 10.1021/acsami.9b23155

Tortuosity Anisotropy in Lithium-Ion Battery Electrodes
journal, October 2013

  • Ebner, Martin; Chung, Ding-Wen; García, R. Edwin
  • Advanced Energy Materials, Vol. 4, Issue 5
  • DOI: 10.1002/aenm.201301278

Enabling fast charging – Battery thermal considerations
journal, November 2017


Closed-loop optimization of fast-charging protocols for batteries with machine learning
journal, February 2020


Electrode scale and electrolyte transport effects on extreme fast charging of lithium-ion cells
journal, March 2020


Abuse behavior of high-power, lithium-ion cells
journal, January 2003


A new approach toward improved low temperature performance of Li-ion battery
journal, November 2002


Modeling the Effects of Electrode Microstructural Heterogeneities on Li-Ion Battery Performance and Lifetime
journal, January 2018

  • Forouzan, Mehdi M.; Mazzeo, Brian A.; Wheeler, Dean R.
  • Journal of The Electrochemical Society, Vol. 165, Issue 10
  • DOI: 10.1149/2.1281809jes

Quantifying Inhomogeneity of Lithium Ion Battery Electrodes and Its Influence on Electrochemical Performance
journal, January 2018

  • Müller, Simon; Eller, Jens; Ebner, Martin
  • Journal of The Electrochemical Society, Vol. 165, Issue 2
  • DOI: 10.1149/2.0311802jes

Measurement of radial thermal conductivity of a cylinder using a time-varying heat flux method
journal, July 2018


Enabling fast charging – Vehicle considerations
journal, November 2017


Inhomogeneous Degradation of Graphite Anodes in Li-Ion Cells: A Postmortem Study Using Glow Discharge Optical Emission Spectroscopy (GD-OES)
journal, September 2016

  • Ghanbari, Niloofar; Waldmann, Thomas; Kasper, Michael
  • The Journal of Physical Chemistry C, Vol. 120, Issue 39
  • DOI: 10.1021/acs.jpcc.6b07117

Review—Electromobility: Batteries or Fuel Cells?
journal, January 2015

  • Gröger, Oliver; Gasteiger, Hubert A.; Suchsland, Jens-Peter
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0211514jes

Electrochemistry Coupled Mesoscale Complexations in Electrodes Lead to Thermo-Electrochemical Extremes
journal, August 2018

  • Mistry, Aashutosh N.; Smith, Kandler; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 34
  • DOI: 10.1021/acsami.8b08993

Quantification of Heterogeneous Degradation in Li‐Ion Batteries
journal, May 2019


Calendering effects on the physical and electrochemical properties of Li[Ni1/3Mn1/3Co1/3]O2 cathode
journal, June 2012


Controllable Electrode Stochasticity Self-Heats Lithium-Ion Batteries at Low Temperatures
journal, July 2019

  • Mistry, Aashutosh; Verma, Ankit; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 30
  • DOI: 10.1021/acsami.9b05468

A look into the voltage plateau signal for detection and quantification of lithium plating in lithium-ion cells
journal, August 2018


Visualization and Quantification of Electrochemical and Mechanical Degradation in Li Ion Batteries
journal, October 2013


In Situ Measurement of Lithium-Ion Cell Internal Temperatures during Extreme Fast Charging
journal, January 2019

  • Huang, Shan; Wu, Xianyang; Cavalheiro, Gabriel M.
  • Journal of The Electrochemical Society, Vol. 166, Issue 14
  • DOI: 10.1149/2.0441914jes

Deconstructing electrode pore network to learn transport distortion
journal, December 2019

  • Mistry, Aashutosh; Mukherjee, Partha P.
  • Physics of Fluids, Vol. 31, Issue 12
  • DOI: 10.1063/1.5124099

Communication—Implications of Local Current Density Variations on Lithium Plating Affected by Cathode Particle Size
journal, January 2019

  • Abboud, Alexander W.; Dufek, Eric J.; Liaw, Boryann
  • Journal of The Electrochemical Society, Vol. 166, Issue 4
  • DOI: 10.1149/2.0711904jes

Impact of Pore Tortuosity on Electrode Kinetics in Lithium Battery Electrodes: Study in Directionally Freeze-Cast LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA)
journal, January 2018

  • Delattre, Benjamin; Amin, Ruhul; Sander, Jonathan
  • Journal of The Electrochemical Society, Vol. 165, Issue 2
  • DOI: 10.1149/2.1321802jes

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Transition of lithium growth mechanisms in liquid electrolytes
journal, January 2016

  • Bai, Peng; Li, Ju; Brushett, Fikile R.
  • Energy & Environmental Science, Vol. 9, Issue 10
  • DOI: 10.1039/C6EE01674J

Use of Asymmetric Average Charge- and Average Discharge- Voltages as an Indicator of the Onset of Unwanted Lithium Deposition in Lithium-Ion Cells
journal, January 2018

  • Harlow, J. E.; Glazier, S. L.; Li, Jing
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0011816jes

Extreme Fast Charge Challenges for Lithium-Ion Battery: Variability and Positive Electrode Issues
journal, January 2019

  • Tanim, Tanvir R.; Dufek, Eric J.; Evans, Michael
  • Journal of The Electrochemical Society, Vol. 166, Issue 10
  • DOI: 10.1149/2.0731910jes

A Volume Averaged Approach to the Numerical Modeling of Phase-Transition Intercalation Electrodes Presented for Li x C 6
journal, January 2012

  • Gallagher, Kevin G.; Dees, Dennis W.; Jansen, Andrew N.
  • Journal of The Electrochemical Society, Vol. 159, Issue 12
  • DOI: 10.1149/2.015301jes

Mesoscale Effects of Composition and Calendering in Lithium-Ion Battery Composite Electrodes
journal, March 2020

  • Trembacki, Bradley L.; Noble, David R.; Ferraro, Mark E.
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 17, Issue 4
  • DOI: 10.1115/1.4045973

Effects of Inhomogeneities—Nanoscale to Mesoscale—on the Durability of Li-Ion Batteries
journal, February 2013

  • Harris, Stephen J.; Lu, Peng
  • The Journal of Physical Chemistry C, Vol. 117, Issue 13
  • DOI: 10.1021/jp311431z

Development of low temperature Li-ion electrolytes for NASA and DoD applications
journal, March 2001


Electrolyte Confinement Alters Lithium Electrodeposition
journal, December 2018


Impedance Evolution Characteristics in Lithium-Ion Batteries
journal, January 2017

  • Juarez-Robles, Daniel; Chen, Chien-Fan; Barsukov, Yevgen
  • Journal of The Electrochemical Society, Vol. 164, Issue 4
  • DOI: 10.1149/2.1251704jes

Particles and Polymer Binder Interaction: A Controlling Factor in Lithium-Ion Electrode Performance
journal, January 2012

  • Liu, G.; Zheng, H.; Song, X.
  • Journal of The Electrochemical Society, Vol. 159, Issue 3
  • DOI: 10.1149/2.024203jes

In operando thermal signature probe for lithium-ion batteries
journal, January 2019

  • Mistry, Aashutosh N.; Palle, Hanumanth Reddy; Mukherjee, Partha P.
  • Applied Physics Letters, Vol. 114, Issue 2
  • DOI: 10.1063/1.5082794

Modeling of Galvanostatic Charge and Discharge of the Lithium/Polymer/Insertion Cell
journal, January 1993

  • Doyle, Marc
  • Journal of The Electrochemical Society, Vol. 140, Issue 6
  • DOI: 10.1149/1.2221597

Tortuosity Determination of Battery Electrodes and Separators by Impedance Spectroscopy
journal, January 2016

  • Landesfeind, Johannes; Hattendorff, Johannes; Ehrl, Andreas
  • Journal of The Electrochemical Society, Vol. 163, Issue 7
  • DOI: 10.1149/2.1141607jes

Asymmetric Temperature Modulation for Extreme Fast Charging of Lithium-Ion Batteries
journal, December 2019


In operando monitoring of reaction-diffusion streamlines and uncovering of electrochemo-structural interactions in electrodes
journal, January 2019

  • Zhang, Yanxiang; Yan, Fuyao; Ma, Jingbo
  • Journal of Materials Chemistry A, Vol. 7, Issue 17
  • DOI: 10.1039/C9TA01784D

Investigation of Lithium Plating-Stripping Process in Li-Ion Batteries at Low Temperature Using an Electrochemical Model
journal, January 2018

  • Ren, Dongsheng; Smith, Kandler; Guo, Dongxu
  • Journal of The Electrochemical Society, Vol. 165, Issue 10
  • DOI: 10.1149/2.0661810jes

X-Ray Tomography for Lithium Ion Battery Research: A Practical Guide
journal, July 2017


Dead lithium: mass transport effects on voltage, capacity, and failure of lithium metal anodes
journal, January 2017

  • Chen, Kuan-Hung; Wood, Kevin N.; Kazyak, Eric
  • Journal of Materials Chemistry A, Vol. 5, Issue 23
  • DOI: 10.1039/C7TA00371D

Monitoring the Lithium Concentration across the Thickness of Silicon-Graphite Electrodes during the First (De-)Lithiation
journal, January 2019

  • Wetjen, Morten; Trunk, Markus; Werner, Lukas
  • Journal of The Electrochemical Society, Vol. 166, Issue 8
  • DOI: 10.1149/2.0581908jes

Optimization of Charging Strategy by Prevention of Lithium Deposition on Anodes in high-energy Lithium-ion Batteries – Electrochemical Experiments
journal, October 2015


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

Enabling fast charging – Introduction and overview
journal, November 2017


Sustainable transportation based on electric vehicle concepts: a brief overview
journal, January 2010

  • Eberle, Dr Ulrich; von Helmolt, Dr Rittmar
  • Energy & Environmental Science, Vol. 3, Issue 6
  • DOI: 10.1039/c001674h

Li plating as unwanted side reaction in commercial Li-ion cells – A review
journal, April 2018


Electrode Mesoscale as a Collection of Particles: Coupled Electrochemical and Mechanical Analysis of NMC Cathodes
journal, January 2020

  • Ferraro, Mark E.; Trembacki, Bradley L.; Brunini, Victor E.
  • Journal of The Electrochemical Society, Vol. 167, Issue 1
  • DOI: 10.1149/1945-7111/ab632b

Lithium-ion battery structure that self-heats at low temperatures
journal, January 2016

  • Wang, Chao-Yang; Zhang, Guangsheng; Ge, Shanhai
  • Nature, Vol. 529, Issue 7587
  • DOI: 10.1038/nature16502

Quantitative Characterization of the Surface Evolution for LiNi 0.5 Co 0.2 Mn 0.3 O 2 /Graphite Cell during Long-Term Cycling
journal, March 2017

  • Zheng, Huiyuan; Qu, Qunting; Zhu, Guobin
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 14
  • DOI: 10.1021/acsami.7b00427

Secondary-Phase Stochastics in Lithium-Ion Battery Electrodes
journal, January 2018

  • Mistry, Aashutosh N.; Smith, Kandler; Mukherjee, Partha P.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 7
  • DOI: 10.1021/acsami.7b17771

Visualization of self-heating of an all climate battery by infrared thermography
journal, February 2018


Fast charging of lithium-ion batteries at all temperatures
journal, June 2018

  • Yang, Xiao-Guang; Zhang, Guangsheng; Ge, Shanhai
  • Proceedings of the National Academy of Sciences, Vol. 115, Issue 28
  • DOI: 10.1073/pnas.1807115115

Intercalate Diffusion in Multiphase Electrode Materials and Application to Lithiated Graphite
journal, January 2012

  • Baker, Daniel R.; Verbrugge, Mark W.
  • Journal of The Electrochemical Society, Vol. 159, Issue 8
  • DOI: 10.1149/2.002208jes

Understanding the trilemma of fast charging, energy density and cycle life of lithium-ion batteries
journal, October 2018


High Rate Capability of Li(Ni 1/3 Mn 1/3 Co 1/3 )O 2 Electrode for Li-Ion Batteries
journal, January 2012

  • Wu, Shao-Ling; Zhang, Wei; Song, Xiangyun
  • Journal of The Electrochemical Society, Vol. 159, Issue 4
  • DOI: 10.1149/2.062204jes