Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy

Liu, Yingshuo; Deb, Aniruddha; Leung, Kwan Yee; Nie, Weixuan; Dean, William S.; Penner-Hahn, James E.; McCrory, Charles C. L.

doi:10.1039/D0DT01288B

Title: Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO ₂ reduction conditions using in situ X-Ray absorption spectroscopy

Journal Article · 25 November 2020 · Dalton Transactions

DOI: https://doi.org/10.1039/D0DT01288B · OSTI ID:1630222

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Department of Chemistry, University of Michigan, Ann Arbor, USA
Department of Chemistry, University of Michigan, Ann Arbor, USA, Biophysics
Department of Chemistry, University of Michigan, Ann Arbor, USA, Macromolecular Science & Engineering

In situ X-ray absorbance spectroscopy measurements show that encapsulating cobalt phthalocyanine within coordinating polymers leads to axial ligation of Co and results in enhanced rates for electrocatalytic CO ₂ reduction.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1630222

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Vol. 49 Journal Issue: 45; ISSN 1477-9226

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO ₂ reduction conditions using in situ X-Ray absorption spectroscopy