Title: Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy

Journal Article · · Dalton Transactions
DOI: https://doi.org/10.1039/D0DT01288B · OSTI ID:1630222
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry, University of Michigan, Ann Arbor, USA
  2. Department of Chemistry, University of Michigan, Ann Arbor, USA, Biophysics
  3. Department of Chemistry, University of Michigan, Ann Arbor, USA, Macromolecular Science & Engineering
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In situ X-ray absorbance spectroscopy measurements show that encapsulating cobalt phthalocyanine within coordinating polymers leads to axial ligation of Co and results in enhanced rates for electrocatalytic CO 2 reduction.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1630222
Journal Information:
Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 45 Vol. 49; ISSN 1477-9226; ISSN ICHBD9
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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