Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy
Abstract
In situ X-ray absorbance spectroscopy measurements show that encapsulating cobalt phthalocyanine within coordinating polymers leads to axial ligation of Co and results in enhanced rates for electrocatalytic CO 2 reduction.
- Authors:
-
[1];
[2];
[1];
[1];
[1];
[2];
[3]
- Department of Chemistry, University of Michigan, Ann Arbor, USA
- Department of Chemistry, University of Michigan, Ann Arbor, USA, Biophysics
- Department of Chemistry, University of Michigan, Ann Arbor, USA, Macromolecular Science & Engineering
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1630222
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Name: Dalton Transactions Journal Volume: 49 Journal Issue: 45; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Liu, Yingshuo, Deb, Aniruddha, Leung, Kwan Yee, Nie, Weixuan, Dean, William S., Penner-Hahn, James E., and McCrory, Charles C. L. Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy. United Kingdom: N. p., 2020.
Web. doi:10.1039/D0DT01288B.
Liu, Yingshuo, Deb, Aniruddha, Leung, Kwan Yee, Nie, Weixuan, Dean, William S., Penner-Hahn, James E., & McCrory, Charles C. L. Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy. United Kingdom. https://doi.org/10.1039/D0DT01288B
Liu, Yingshuo, Deb, Aniruddha, Leung, Kwan Yee, Nie, Weixuan, Dean, William S., Penner-Hahn, James E., and McCrory, Charles C. L. Wed .
"Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy". United Kingdom. https://doi.org/10.1039/D0DT01288B.
@article{osti_1630222,
title = {Determining the coordination environment and electronic structure of polymer-encapsulated cobalt phthalocyanine under electrocatalytic CO 2 reduction conditions using in situ X-Ray absorption spectroscopy},
author = {Liu, Yingshuo and Deb, Aniruddha and Leung, Kwan Yee and Nie, Weixuan and Dean, William S. and Penner-Hahn, James E. and McCrory, Charles C. L.},
abstractNote = {In situ X-ray absorbance spectroscopy measurements show that encapsulating cobalt phthalocyanine within coordinating polymers leads to axial ligation of Co and results in enhanced rates for electrocatalytic CO 2 reduction.},
doi = {10.1039/D0DT01288B},
journal = {Dalton Transactions},
number = 45,
volume = 49,
place = {United Kingdom},
year = {2020},
month = {11}
}
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https://doi.org/10.1039/D0DT01288B
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