Does repeat synthesis in materials chemistry obey a power law?
Abstract
Finding examples where experimental measurements have been repeated is a powerful strategy for assessing reproducibility of scientific data. Here, we collect quantitative data to assess how often synthesis of a newly reported material is repeated in the scientific literature. We present a simple power-law model for the frequency of repeat syntheses and assess the validity of this model using a specific class of materials, metal-organic frameworks (MOFs). Our data suggest that a power law describes the frequency of repeat synthesis of many MOFs but that a small number of “supermaterials” exist that have been replicated many times more than a power law would predict. Our results also hint that there are many repeat syntheses that have been performed but not reported in the literature, which suggests simple steps that could be taken to greatly increase the number of reports of replicate experiments in materials chemistry.
- Authors:
-
[1];
[1]
- Georgia Institute of Technology, Atlanta, GA (United States). School of Chemical & Biomolecular Engineering
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME); Georgia Institute of Technology, Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1625062
- Grant/Contract Number:
- SC0012577
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Volume: 117; Journal Issue: 2; Journal ID: ISSN 0027-8424
- Publisher:
- National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Science & Technology - Other Topics
Citation Formats
Agrawal, Mayank, Han, Rebecca, Herath, Dinushka, and Sholl, David S. Does repeat synthesis in materials chemistry obey a power law?. United States: N. p., 2019.
Web. doi:10.1073/pnas.1918484117.
Agrawal, Mayank, Han, Rebecca, Herath, Dinushka, & Sholl, David S. Does repeat synthesis in materials chemistry obey a power law?. United States. https://doi.org/10.1073/pnas.1918484117
Agrawal, Mayank, Han, Rebecca, Herath, Dinushka, and Sholl, David S. Thu .
"Does repeat synthesis in materials chemistry obey a power law?". United States. https://doi.org/10.1073/pnas.1918484117. https://www.osti.gov/servlets/purl/1625062.
@article{osti_1625062,
title = {Does repeat synthesis in materials chemistry obey a power law?},
author = {Agrawal, Mayank and Han, Rebecca and Herath, Dinushka and Sholl, David S.},
abstractNote = {Finding examples where experimental measurements have been repeated is a powerful strategy for assessing reproducibility of scientific data. Here, we collect quantitative data to assess how often synthesis of a newly reported material is repeated in the scientific literature. We present a simple power-law model for the frequency of repeat syntheses and assess the validity of this model using a specific class of materials, metal-organic frameworks (MOFs). Our data suggest that a power law describes the frequency of repeat synthesis of many MOFs but that a small number of “supermaterials” exist that have been replicated many times more than a power law would predict. Our results also hint that there are many repeat syntheses that have been performed but not reported in the literature, which suggests simple steps that could be taken to greatly increase the number of reports of replicate experiments in materials chemistry.},
doi = {10.1073/pnas.1918484117},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 2,
volume = 117,
place = {United States},
year = {2019},
month = {12}
}
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Fig. 1: Fraction of MOFs whose synthesis has been reported exactly n times among the group of 130 MOFs described in the text. Blue (red) symbols show results for all reports (results when only resynthesis by authors distinct from the original paper are counted). The solid curve shows the powermore »
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