Annihilator dimers enhance triplet fusion upconversion

Pun, Andrew B.; Sanders, Samuel N.; Sfeir, Matthew Y.; Campos, Luis M.; Congreve, Daniel N.

doi:10.1039/c8sc03725f

Title: Annihilator dimers enhance triplet fusion upconversion

Journal Article · 01 January 2019 · Chemical Science

DOI: https://doi.org/10.1039/c8sc03725f · OSTI ID:1624967

^[1]; Sanders, Samuel N. ^[2];

^[3]; Campos, Luis M. ^[1];

^[2]

Department of Chemistry; Columbia University; New York; USA
Rowland Institute at Harvard University; Cambridge; USA
Photonics Initiative; Advanced Science Research Center; City University of New York; New York; USA

Optical upconversion is a net process by which two low energy photons are converted into one higher energy photon. There is vast potential to exploit upconversion in applications ranging from solar energy and biological imaging to data storage and photocatalysis. Here, we link two upconverting chromophores together to synthesize a series of novel tetracene dimers for use as annihilators. When compared with the monomer annihilator, TIPS–tetracene, the dimers yield a strong enhancement in the triplet fusion process, also known as triplet–triplet annihilation, as demonstrated via a large increase in upconversion efficiency and an order of magnitude reduction of the threshold power for maximum yield. Along with the ongoing rapid improvements to sensitizer materials, the dimerization improvements demonstrated here open the way to a wide variety of emerging upconversion applications.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704: DGE 16-44869; DMR 1351293

OSTI ID:: 1624967

Journal Information:: Chemical Science, Vol. 10, Issue 14; ISSN 2041-6520

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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