Decreasing the electronic confinement in layered perovskites through intercalation
Abstract
We show that post-synthetic small-molecule intercalation can significantly reduce the electronic confinement of 2D hybrid perovskites. Using a combined experimental and theoretical approach, we explain structural, optical, and electronic effects of intercalating highly polarizable molecules in layered perovskites designed to stabilize the intercalants. Polarizable molecules in the organic layers substantially alter the optical and electronic properties of the inorganic layers. By calculating the spatially resolved dielectric profiles of the organic and inorganic layers within the hybrid structure, we show that the intercalants afford organic layers that are more polarizable than the inorganic layers. This strategy reduces the confinement of excitons generated in the inorganic layers and affords the lowest exciton binding energy for an n = 1 perovskite of which we are aware. We also demonstrate a method for computationally evaluating the exciton's binding energy by solving the Bethe–Salpeter equation for the exciton, which includes an ab initio determination of the material's dielectric profile across organic and inorganic layers. This new semi-empirical method goes beyond the imprecise phenomenological approximation of abrupt dielectric-constant changes at the organic–inorganic interfaces. This work shows that incorporation of polarizable molecules in the organic layers, through intercalation or covalent attachment, is a viable strategy for tuningmore »
- Authors:
-
[1];
[3];
[2];
[1]
- Stanford Univ., CA (United States)
- Centre National de la Recherche Scientifique (CNRS), Rennes (France)
- Univ. of Rennes (France)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Global Climate and Energy Project (GCEP); Alfred P. Sloan Fellowship; CINES; Grand Equipement National de Calcul Intensif (GENCI); University of Rennes 1; Fondation d'entreprises banque Populaire de l'Ouest
- OSTI Identifier:
- 1624941
- Grant/Contract Number:
- AC02-05CH11231; DMR-1351538; DGE-114747; x2016096724; x2015096724; PEROPHOT 2015
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 3; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry
Citation Formats
Smith, Matthew D., Pedesseau, Laurent, Kepenekian, Mikaël, Smith, Ian C., Katan, Claudine, Even, Jacky, and Karunadasa, Hemamala I. Decreasing the electronic confinement in layered perovskites through intercalation. United States: N. p., 2017.
Web. doi:10.1039/c6sc02848a.
Smith, Matthew D., Pedesseau, Laurent, Kepenekian, Mikaël, Smith, Ian C., Katan, Claudine, Even, Jacky, & Karunadasa, Hemamala I. Decreasing the electronic confinement in layered perovskites through intercalation. United States. https://doi.org/10.1039/c6sc02848a
Smith, Matthew D., Pedesseau, Laurent, Kepenekian, Mikaël, Smith, Ian C., Katan, Claudine, Even, Jacky, and Karunadasa, Hemamala I. Sun .
"Decreasing the electronic confinement in layered perovskites through intercalation". United States. https://doi.org/10.1039/c6sc02848a. https://www.osti.gov/servlets/purl/1624941.
@article{osti_1624941,
title = {Decreasing the electronic confinement in layered perovskites through intercalation},
author = {Smith, Matthew D. and Pedesseau, Laurent and Kepenekian, Mikaël and Smith, Ian C. and Katan, Claudine and Even, Jacky and Karunadasa, Hemamala I.},
abstractNote = {We show that post-synthetic small-molecule intercalation can significantly reduce the electronic confinement of 2D hybrid perovskites. Using a combined experimental and theoretical approach, we explain structural, optical, and electronic effects of intercalating highly polarizable molecules in layered perovskites designed to stabilize the intercalants. Polarizable molecules in the organic layers substantially alter the optical and electronic properties of the inorganic layers. By calculating the spatially resolved dielectric profiles of the organic and inorganic layers within the hybrid structure, we show that the intercalants afford organic layers that are more polarizable than the inorganic layers. This strategy reduces the confinement of excitons generated in the inorganic layers and affords the lowest exciton binding energy for an n = 1 perovskite of which we are aware. We also demonstrate a method for computationally evaluating the exciton's binding energy by solving the Bethe–Salpeter equation for the exciton, which includes an ab initio determination of the material's dielectric profile across organic and inorganic layers. This new semi-empirical method goes beyond the imprecise phenomenological approximation of abrupt dielectric-constant changes at the organic–inorganic interfaces. This work shows that incorporation of polarizable molecules in the organic layers, through intercalation or covalent attachment, is a viable strategy for tuning 2D perovskites towards mimicking the reduced electronic confinement and isotropic light absorption of 3D perovskites while maintaining the greater synthetic tunability of the layered architecture.},
doi = {10.1039/c6sc02848a},
journal = {Chemical Science},
number = 3,
volume = 8,
place = {United States},
year = {Sun Jan 01 00:00:00 EST 2017},
month = {Sun Jan 01 00:00:00 EST 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 90 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Image charges in semiconductor quantum wells: Effect on exciton binding energy
journal, September 1990
- Tran Thoai, D. B.; Zimmermann, R.; Grundmann, M.
- Physical Review B, Vol. 42, Issue 9
Preparation and characterization of layered lead halide compounds
journal, March 1991
- Calabrese, J.; Jones, N. L.; Harlow, R. L.
- Journal of the American Chemical Society, Vol. 113, Issue 6, p. 2328-2330
Re-investigation of the crystal structure of CsI 3
journal, January 1955
- Tasman, H. A.; Boswijk, K. H.
- Acta Crystallographica, Vol. 8, Issue 1
Exciton binding energies in organic semiconductors
journal, October 2003
- Knupfer, M.
- Applied Physics A, Vol. 77, Issue 5
Influence of the image charge effect on excitonic energy structure in organic-inorganic multiple quantum well crystals
journal, March 2013
- Takagi, Hidetsugu; Kunugita, Hideyuki; Ema, Kazuhiro
- Physical Review B, Vol. 87, Issue 12
Hybrid functionals based on a screened Coulomb potential
journal, May 2003
- Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
- The Journal of Chemical Physics, Vol. 118, Issue 18
Screened hybrid density functionals applied to solids
journal, April 2006
- Paier, J.; Marsman, M.; Hummer, K.
- The Journal of Chemical Physics, Vol. 124, Issue 15
Effect of dielectric confinement on optical properties of colloidal nanostructures
journal, March 2016
- Rodina, A. V.; Efros, Al. L.
- Journal of Experimental and Theoretical Physics, Vol. 122, Issue 3
Quantum wells with enhanced exciton effects and optical non-linearity
journal, December 1988
- Hanamura, Eiichi; Nagaosa, Naoto; Kumagai, Masami
- Materials Science and Engineering: B, Vol. 1, Issue 3-4
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
Excitons in self-organized semiconductor/insulator superlattices: PbI-based perovskite compounds
journal, May 1995
- Muljarov, E. A.; Tikhodeev, S. G.; Gippius, N. A.
- Physical Review B, Vol. 51, Issue 20
Optical spectroscopy of two-dimensional layered (C_6H_5C_2H_4-NH_3)_2-PbI_4 perovskite
journal, January 2010
- Gauthron, K.; Lauret, J-S.; Doyennette, L.
- Optics Express, Vol. 18, Issue 6
Halogen Bonds in Crystal Engineering: Like Hydrogen Bonds yet Different
journal, May 2014
- Mukherjee, Arijit; Tothadi, Srinu; Desiraju, Gautam R.
- Accounts of Chemical Research, Vol. 47, Issue 8
Electronic and Excitonic Structures of Inorganic–Organic Perovskite-Type Quantum-Well Crystal (C 4 H 9 NH 3 ) 2 PbBr 4
journal, August 2005
- Tanaka, Kenichiro; Takahashi, Takayuki; Kondo, Takashi
- Japanese Journal of Applied Physics, Vol. 44, Issue 8
Self-Assembly of Broadband White-Light Emitters
journal, January 2014
- Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I.
- Journal of the American Chemical Society, Vol. 136, Issue 5
Chemical Approaches to Addressing the Instability and Toxicity of Lead–Halide Perovskite Absorbers
journal, August 2016
- Slavney, Adam H.; Smaha, Rebecca W.; Smith, Ian C.
- Inorganic Chemistry, Vol. 56, Issue 1
Electronic structures of lead iodide based low-dimensional crystals
journal, April 2003
- Umebayashi, T.; Asai, K.; Kondo, T.
- Physical Review B, Vol. 67, Issue 15
Electro-optics of perovskite solar cells
journal, December 2014
- Lin, Qianqian; Armin, Ardalan; Nagiri, Ravi Chandra Raju
- Nature Photonics, Vol. 9, Issue 2
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets
journal, March 1995
- Mitzi, D. B.; Wang, S.; Feild, C. A.
- Science, Vol. 267, Issue 5203, p. 1473-1476
Phase transitions in crystalline models of bilayers. 1. Differential scanning calorimetric and x-ray studies of (C12H25NH3)2MCl4 and (NH3C14H29NH3)2MCl4 salts (M = Mn2+, Cd2+, Cu2+)
journal, February 1984
- Needham, G. F.; Willett, R. D.; Franzen, H. F.
- The Journal of Physical Chemistry, Vol. 88, Issue 4
Erratum: “Hybrid functionals based on a screened Coulomb potential” [J. Chem. Phys. 118, 8207 (2003)]
journal, June 2006
- Heyd, Jochen; Scuseria, Gustavo E.; Ernzerhof, Matthias
- The Journal of Chemical Physics, Vol. 124, Issue 21
The Stereochemistry of the Non-radical Halogen Exchange between Active sec-Octyl Iodide and Chlorine 1
journal, December 1954
- Corey, Elias J.; Wechter, William J.
- Journal of the American Chemical Society, Vol. 76, Issue 23
Organic‐inorganic heterostructure electroluminescent device using a layered perovskite semiconductor (C 6 H 5 C 2 H 4 NH 3 ) 2 PbI 4
journal, August 1994
- Era, M.; Morimoto, S.; Tsutsui, T.
- Applied Physics Letters, Vol. 65, Issue 6
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014
- Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
- Angewandte Chemie International Edition, Vol. 53, Issue 42
Coulomb Interaction and Excitons in a Superlattice
journal, September 1984
- Guseinov, R. R.
- physica status solidi (b), Vol. 125, Issue 1
Optical properties of PbI-based perovskite structures
journal, April 1994
- Ishihara, Teruya
- Journal of Luminescence, Vol. 60-61
In Situ X-Ray Observation on the Intercalation of Weak Interaction Molecules into Perovskite-Type Layered Crystals (C 9 H 19 NH 3 ) 2 PbI 4 and (C 10 H 21 NH 3 ) 2 CdCl 4
journal, February 1986
- Dolzhenko, Yuri I.; Inabe, Tamotsu; Maruyama, Yusei
- Bulletin of the Chemical Society of Japan, Vol. 59, Issue 2
PbnI4n+2(2n+2)? ribbons (n = 3, 5) as dimensional reductions of 2D perovskite layers in cystamine cation based hybrids, also incorporating iodine molecules or reversible guest water molecules
journal, January 2007
- Louvain, Nicolas; Bi, Wenhua; Mercier, Nicolas
- Dalton Transactions, Issue 9
Lithium Cycling in a Self-Assembled Copper Chloride–Polyether Hybrid Electrode
journal, June 2014
- Jaffe, Adam; Karunadasa, Hemamala I.
- Inorganic Chemistry, Vol. 53, Issue 13
Preparation and characterization of [H3N(CH2)6NH3]PbI4 and similar compounds with a layered perovskite structure
journal, January 2000
- Mousdis, G. A.; Papavassiliou, G. C.; Raptopoulou, C. P.
- Journal of Materials Chemistry, Vol. 10, Issue 2
Electronic model for self-assembled hybrid organic/perovskite semiconductors: Reverse band edge electronic states ordering and spin-orbit coupling
journal, November 2012
- Even, J.; Pedesseau, L.; Dupertuis, M. -A.
- Physical Review B, Vol. 86, Issue 20
Effect of heteroatoms in the inorganic–organic layered perovskite-type hybrids [(ZC n H 2n NH 3 ) 2 PbI 4 ], n = 2, 3, 4, 5, 6; Z = OH, Br and I; and [(H 3 NC 2 H 4 S 2 C 2 H 4 NH 3 )PbI 4 ]
journal, January 2010
- Lemmerer, Andreas; Billing, David G.
- CrystEngComm, Vol. 12, Issue 4
Synthesis, characterization and phase transitions in the inorganic–organic layered perovskite-type hybrids [(C n H 2 n + 1 NH 3 ) 2 PbI 4 ], n = 4, 5 and 6
journal, September 2007
- Billing, David G.; Lemmerer, Andreas
- Acta Crystallographica Section B Structural Science, Vol. 63, Issue 5
Organic-Based Layered Perovskites of Mixed-Valent Gold(I)/Gold(III) Iodides
journal, June 2003
- Castro-Castro, Laura M.; Guloy, Arnold M.
- Angewandte Chemie International Edition, Vol. 42, Issue 24
Reduced Band Gap Hybrid Perovskites Resulting from Combined Hydrogen and Halogen Bonding at the Organic−Inorganic Interface
journal, February 2007
- Sourisseau, Sebastien; Louvain, Nicolas; Bi, Wenhua
- Chemistry of Materials, Vol. 19, Issue 3
Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014
- Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
- Journal of the American Chemical Society, Vol. 136, Issue 38
Comparative study on the excitons in lead-halide-based perovskite-type crystals CH3NH3PbBr3 CH3NH3PbI3
journal, September 2003
- Tanaka, Kenichiro; Takahashi, Takayuki; Ban, Takuma
- Solid State Communications, Vol. 127, Issue 9-10, p. 619-623
Photoconductivity and electroluminescence in lead iodide based natural quantum well structures
journal, November 1992
- Hong, X.; Ishihara, T.; Nurmikko, A. V.
- Solid State Communications, Vol. 84, Issue 6
Perovskite as Light Harvester: A Game Changer in Photovoltaics
journal, February 2014
- Kazim, Samrana; Nazeeruddin, Mohammad Khaja; Grätzel, Michael
- Angewandte Chemie International Edition, Vol. 53, Issue 11
Analysis of Multivalley and Multibandgap Absorption and Enhancement of Free Carriers Related to Exciton Screening in Hybrid Perovskites
journal, May 2014
- Even, Jacky; Pedesseau, Laurent; Katan, Claudine
- The Journal of Physical Chemistry C, Vol. 118, Issue 22
Quantum confinement and dielectric profiles of colloidal nanoplatelets of halide inorganic and hybrid organic–inorganic perovskites
journal, January 2016
- Sapori, Daniel; Kepenekian, Mikaël; Pedesseau, Laurent
- Nanoscale, Vol. 8, Issue 12
Dielectric confinement effect on excitons in -based layered semiconductors
journal, March 1992
- Hong, X.; Ishihara, T.; Nurmikko, A. V.
- Physical Review B, Vol. 45, Issue 12
Interplay of spin–orbit coupling and lattice distortion in metal substituted 3D tri-chloride hybrid perovskites
journal, January 2015
- Katan, C.; Pedesseau, L.; Kepenekian, M.
- Journal of Materials Chemistry A, Vol. 3, Issue 17
Synthesis, Single-Crystal Structure and Characterization of (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2
journal, September 2015
- Daub, Michael; Hillebrecht, Harald
- Angewandte Chemie International Edition, Vol. 54, Issue 38
Structurally Tailored Organic−Inorganic Perovskites: Optical Properties and Solution-Processed Channel Materials for Thin-Film Transistors
journal, October 2001
- Mitzi, David B.; Dimitrakopoulos, Christos D.; Kosbar, Laura L.
- Chemistry of Materials, Vol. 13, Issue 10
Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating
journal, June 2005
- Knutson, Jeremy L.; Martin, James D.; Mitzi, David B.
- Inorganic Chemistry, Vol. 44, Issue 13
Reversible and Irreversible Chemisorption in Nonporous-Crystalline Hybrids
journal, December 2013
- Solis-Ibarra, Diego; Karunadasa, Hemamala I.
- Angewandte Chemie International Edition, Vol. 53, Issue 4
Ueber die Einwirkung des Broms auf den Isopropylalkohol und auf das Isopropyljodür
journal, January 1865
- Friedel, C.
- Annalen der Chemie und Pharmacie, Vol. 135, Issue 2
Halogen bonding and other σ-hole interactions: a perspective
journal, January 2013
- Politzer, Peter; Murray, Jane S.; Clark, Timothy
- Physical Chemistry Chemical Physics, Vol. 15, Issue 27
Importance of Spin–Orbit Coupling in Hybrid Organic/Inorganic Perovskites for Photovoltaic Applications
journal, August 2013
- Even, Jacky; Pedesseau, Laurent; Jancu, Jean-Marc
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
Intercalated Organic−Inorganic Perovskites Stabilized by Fluoroaryl−Aryl Interactions
journal, April 2002
- Mitzi, David B.; Medeiros, David R.; Malenfant, Patrick R. L.
- Inorganic Chemistry, Vol. 41, Issue 8
Interband Optical Transitions in Extremely Anisotropic Semiconductors. I. Bound and Unbound Exciton Absorption
journal, October 1966
- Shinada, Masaki; Sugano, Satoru
- Journal of the Physical Society of Japan, Vol. 21, Issue 10
Understanding Quantum Confinement of Charge Carriers in Layered 2D Hybrid Perovskites
journal, September 2014
- Even, Jacky; Pedesseau, Laurent; Katan, Claudine
- ChemPhysChem, Vol. 15, Issue 17
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
journal, October 2013
- Snaith, Henry J.
- The Journal of Physical Chemistry Letters, Vol. 4, Issue 21, p. 3623-3630
Reversible and Irreversible Chemisorption in Nonporous-Crystalline Hybrids
journal, December 2013
- Solis-Ibarra, Diego; Karunadasa, Hemamala I.
- Angewandte Chemie, Vol. 126, Issue 4
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014
- Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
- Angewandte Chemie, Vol. 126, Issue 42
Synthesis, Single-Crystal Structure and Characterization of (CH 3 NH 3 ) 2 Pb(SCN) 2 I 2
journal, September 2015
- Daub, Michael; Hillebrecht, Harald
- Angewandte Chemie, Vol. 127, Issue 38
Organic-Based Layered Perovskites of Mixed-Valent Gold(I)/Gold(III) Iodides.
journal, September 2003
- Castro-Castro, Laura M.; Guloy, Arnold M.
- ChemInform, Vol. 34, Issue 36
Re-investigation of the crystal structure of CsI 3
journal, December 1955
- Tasman, H. A.; Boswijk, K. H.
- Acta Crystallographica, Vol. 8, Issue 12
Understanding Quantum Confinement of Charge Carriers in Layered 2D Hybrid Perovskites
journal, September 2014
- Even, Jacky; Pedesseau, Laurent; Katan, Claudine
- ChemPhysChem, Vol. 15, Issue 17
Chemical Approaches to Addressing the Instability and Toxicity of Lead–Halide Perovskite Absorbers
journal, August 2016
- Slavney, Adam H.; Smaha, Rebecca W.; Smith, Ian C.
- Inorganic Chemistry, Vol. 56, Issue 1
Halogen Bonds in Crystal Engineering: Like Hydrogen Bonds yet Different
journal, May 2014
- Mukherjee, Arijit; Tothadi, Srinu; Desiraju, Gautam R.
- Accounts of Chemical Research, Vol. 47, Issue 8
Intercalated Organic−Inorganic Perovskites Stabilized by Fluoroaryl−Aryl Interactions
journal, April 2002
- Mitzi, David B.; Medeiros, David R.; Malenfant, Patrick R. L.
- Inorganic Chemistry, Vol. 41, Issue 8
Lithium Cycling in a Self-Assembled Copper Chloride–Polyether Hybrid Electrode
journal, June 2014
- Jaffe, Adam; Karunadasa, Hemamala I.
- Inorganic Chemistry, Vol. 53, Issue 13
Self-Assembly of Broadband White-Light Emitters
journal, January 2014
- Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I.
- Journal of the American Chemical Society, Vol. 136, Issue 5
Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014
- Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
- Journal of the American Chemical Society, Vol. 136, Issue 38
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
PbnI4n+2(2n+2)? ribbons (n = 3, 5) as dimensional reductions of 2D perovskite layers in cystamine cation based hybrids, also incorporating iodine molecules or reversible guest water molecules
journal, January 2007
- Louvain, Nicolas; Bi, Wenhua; Mercier, Nicolas
- Dalton Transactions, Issue 9
Halogen bonding and other σ-hole interactions: a perspective
journal, January 2013
- Politzer, Peter; Murray, Jane S.; Clark, Timothy
- Physical Chemistry Chemical Physics, Vol. 15, Issue 27
Electronic surface states and dielectric self-energy profiles in colloidal nanoscale platelets of CdSe
journal, January 2014
- Even, Jacky; Pedesseau, Laurent; Kepenekian, Mikaël
- Phys. Chem. Chem. Phys., Vol. 16, Issue 45
Screened hybrid density functionals applied to solids
journal, April 2006
- Paier, J.; Marsman, M.; Hummer, K.
- The Journal of Chemical Physics, Vol. 124, Issue 15
Conducting Layered Organic-inorganic Halides Containing <110>-Oriented Perovskite Sheets
journal, March 1995
- Mitzi, D. B.; Wang, S.; Feild, C. A.
- Science, Vol. 267, Issue 5203, p. 1473-1476
Optical spectroscopy of two-dimensional layered $(C_{6}H_{5}C_{2}H_{4}-NH_{3})_{2}-PbI_{4}$ perovskite
text, January 2009
- Gauthron, K.; Lauret, J. S.; Doyennette, L.
- arXiv
Works referencing / citing this record:
Effect of High Dipole Moment Cation on Layered 2D Organic–Inorganic Halide Perovskite Solar Cells
journal, December 2018
- Tan, Shunquan; Zhou, Ning; Chen, Yihua
- Advanced Energy Materials
Thousand‐fold Conductivity Increase in 2D Perovskites by Polydiacetylene Incorporation and Doping
journal, September 2018
- Ortiz‐Cervantes, Carmen; Román‐Román, Priscila I.; Vazquez‐Chavez, Josué
- Angewandte Chemie, Vol. 130, Issue 42
Thousand-fold Conductivity Increase in 2D Perovskites by Polydiacetylene Incorporation and Doping
journal, September 2018
- Ortiz-Cervantes, Carmen; Román-Román, Priscila I.; Vazquez-Chavez, Josué
- Angewandte Chemie International Edition, Vol. 57, Issue 42
Extremely reduced dielectric confinement in two-dimensional hybrid perovskites with large polar organics
journal, November 2018
- Cheng, Bin; Li, Ting-You; Maity, Partha
- Communications Physics, Vol. 1, Issue 1
Towards 2D layered hybrid perovskites with enhanced functionality: introducing charge-transfer complexes via self-assembly
journal, January 2019
- Van Gompel, Wouter T. M.; Herckens, Roald; Van Hecke, Kristof
- Chemical Communications, Vol. 55, Issue 17
Tuning optical/electrical properties of 2D/3D perovskite by the inclusion of aromatic cation
journal, January 2018
- Rodríguez-Romero, Jesús; Clasen Hames, Bruno; Galar, Pavel
- Physical Chemistry Chemical Physics, Vol. 20, Issue 48
Melting temperature suppression of layered hybrid lead halide perovskites via organic ammonium cation branching
journal, January 2019
- Li, Tianyang; Dunlap-Shohl, Wiley A.; Reinheimer, Eric W.
- Chemical Science, Vol. 10, Issue 4
First-principles insights into tin-based two-dimensional hybrid halide perovskites for photovoltaics
journal, January 2018
- Wang, Zhenyu; Ganose, Alex M.; Niu, Chunming
- Journal of Materials Chemistry A, Vol. 6, Issue 14
First-principles characterization of two-dimensional (CH 3 (CH 2 ) 3 NH 3 ) 2 (CH 3 NH 3 ) n−1 Ge n I 3n+1 perovskite
journal, January 2018
- Wu, Liyuan; Lu, Pengfei; Li, Yuheng
- Journal of Materials Chemistry A, Vol. 6, Issue 47
Realization of “warm” white light via halide substitution in polar two-dimensional hybrid perovskites (2meptH 2 )PbCl x Br 4−x
journal, January 2018
- Wang, Sasa; Yao, Yunpeng; Wu, Zhenyue
- Journal of Materials Chemistry C, Vol. 6, Issue 45
Influence of organic cation planarity on structural templating in hybrid metal-halides
journal, January 2019
- Oswald, Iain W. H.; Ahn, Hyochul; Neilson, James R.
- Dalton Transactions, Vol. 48, Issue 43
Achieving high performance poly(vinylidene fluoride) dielectric composites via in situ polymerization of polypyrrole nanoparticles on hydroxylated BaTiO 3 particles
journal, January 2019
- Xie, Xu; He, Zhen-zhen; Qi, Xiao-dong
- Chemical Science, Vol. 10, Issue 35
Recent developments in emerging two-dimensional materials and their applications
journal, January 2020
- Khan, Karim; Tareen, Ayesha Khan; Aslam, Muhammad
- Journal of Materials Chemistry C, Vol. 8, Issue 2
Dimensional reduction of the small-bandgap double perovskite Cs 2 AgTlBr 6
journal, January 2020
- Connor, Bridget A.; Biega, Raisa-Ioana; Leppert, Linn
- Chemical Science
Computational screening of methylammonium based halide perovskites with bandgaps suitable for perovskite-perovskite tandem solar cells
journal, December 2018
- Kar, M.; Körzdörfer, T.
- The Journal of Chemical Physics, Vol. 149, Issue 21
Cystamine-configured lead halide based 2D hybrid molecular crystals: Synthesis and photoluminescence systematics
journal, November 2018
- Krishnamurthy, Shrreya; Kour, Prachi; Katre, Ankita
- APL Materials, Vol. 6, Issue 11
Structural and thermodynamic limits of layer thickness in 2D halide perovskites
journal, December 2018
- Soe, Chan Myae Myae; Nagabhushana, G. P.; Shivaramaiah, Radha
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 1
Hyperbolic Dispersion Arising from Anisotropic Excitons in Two-Dimensional Perovskites
journal, September 2018
- Guo, Peijun; Huang, Wei; Stoumpos, Constantinos C.
- Physical Review Letters, Vol. 121, Issue 12
Stable biexcitons in two-dimensional metal-halide perovskites with strong dynamic lattice disorder
journal, March 2018
- Thouin, Félix; Neutzner, Stefanie; Cortecchia, Daniele
- Physical Review Materials, Vol. 2, Issue 3
Influence of -conjugated cations and halogen substitution on the optoelectronic and excitonic properties of layered hybrid perovskites
journal, October 2018
- Leveillee, Joshua; Katan, Claudine; Zhou, Liujiang
- Physical Review Materials, Vol. 2, Issue 10
Fluorination of Organic Spacer Impacts on the Structural and Optical Response of 2D Perovskites
journal, January 2020
- García-Benito, Inés; Quarti, Claudio; Queloz, Valentin I. E.
- Frontiers in Chemistry, Vol. 7