Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks
Abstract
Water adsorption is becoming increasingly important for many applications including thermal energy storage, desalination, and water harvesting. To develop such applications, it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy required for adsorption/desorption processes of porous material-adsorbate systems, such as zeolites and metalorganic frameworks (MOFs). In this study, we present a technique to characterize the enthalpy of adsorption/desorption of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conventional differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). With this method, the enthalpies of adsorption of previously uncharacterized adsorbents were estimated as a function of both uptake and temperature. Our characterizations indicate that the adsorption enthalpies of type I zeolites can increase to greater than twice the latent heat whereas adsorption enthalpies of MOF-801 are nearly constant for a wide range of vapor uptakes.
- Authors:
-
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States). Dept. of Mechanical Engineering
- Univ. of California, Berkeley, CA (United States); Kavli Energy NanoScience Institute, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Materials Sciences Division
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1624815
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; Science & Technology - Other Topics
Citation Formats
Kim, Hyunho, Cho, H. Jeremy, Narayanan, Shankar, Yang, Sungwoo, Furukawa, Hiroyasu, Schiffres, Scott, Li, Xiansen, Zhang, Yue-Biao, Jiang, Juncong, Yaghi, Omar M., and Wang, Evelyn N. Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks. United States: N. p., 2016.
Web. doi:10.1038/srep19097.
Kim, Hyunho, Cho, H. Jeremy, Narayanan, Shankar, Yang, Sungwoo, Furukawa, Hiroyasu, Schiffres, Scott, Li, Xiansen, Zhang, Yue-Biao, Jiang, Juncong, Yaghi, Omar M., & Wang, Evelyn N. Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks. United States. https://doi.org/10.1038/srep19097
Kim, Hyunho, Cho, H. Jeremy, Narayanan, Shankar, Yang, Sungwoo, Furukawa, Hiroyasu, Schiffres, Scott, Li, Xiansen, Zhang, Yue-Biao, Jiang, Juncong, Yaghi, Omar M., and Wang, Evelyn N. Fri .
"Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks". United States. https://doi.org/10.1038/srep19097. https://www.osti.gov/servlets/purl/1624815.
@article{osti_1624815,
title = {Characterization of Adsorption Enthalpy of Novel Water-Stable Zeolites and Metal-Organic Frameworks},
author = {Kim, Hyunho and Cho, H. Jeremy and Narayanan, Shankar and Yang, Sungwoo and Furukawa, Hiroyasu and Schiffres, Scott and Li, Xiansen and Zhang, Yue-Biao and Jiang, Juncong and Yaghi, Omar M. and Wang, Evelyn N.},
abstractNote = {Water adsorption is becoming increasingly important for many applications including thermal energy storage, desalination, and water harvesting. To develop such applications, it is essential to understand both adsorbent-adsorbate and adsorbate-adsorbate interactions, and also the energy required for adsorption/desorption processes of porous material-adsorbate systems, such as zeolites and metalorganic frameworks (MOFs). In this study, we present a technique to characterize the enthalpy of adsorption/desorption of zeolites and MOF-801 with water as an adsorbate by conducting desorption experiments with conventional differential scanning calorimetry (DSC) and thermogravimetric analyzer (TGA). With this method, the enthalpies of adsorption of previously uncharacterized adsorbents were estimated as a function of both uptake and temperature. Our characterizations indicate that the adsorption enthalpies of type I zeolites can increase to greater than twice the latent heat whereas adsorption enthalpies of MOF-801 are nearly constant for a wide range of vapor uptakes.},
doi = {10.1038/srep19097},
journal = {Scientific Reports},
number = 1,
volume = 6,
place = {United States},
year = {Fri Jan 22 00:00:00 EST 2016},
month = {Fri Jan 22 00:00:00 EST 2016}
}
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