Ferromagnetic-like behavior of Bi0.9La0.1FeO3–KBr nanocomposites
Abstract
We studied magnetostatic response of the Bi0.9La0.1FeO3– KBr composites (BLFO-KBr) consisting of nanosized (≈100nm) ferrite Bi0.9La0.1FeO3 (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15wt%)the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without Bi1-xLaxFeO3 has no magnetic response as anticipated). However, when the fraction of KBr increases above 15%,the magnetic response of the composite changes substantially and the field dependence of magnetization reveals ferromagnetic-like hysteresis loop with a remnant magnetization about 0.14emu/g and coercive field about 1.8Tesla (at room temperature). Nothing similar to the ferromagnetic-like hysteresis loop can be observed in Bi1-zLazFeO3 ceramics with z≤0.15, which magnetization quasi-linearly increases with magnetic field. Different physical mechanisms were considered to explain the unusual experimental results for BLFO-KBr nanocomposites, but only those among them, which are highly sensitive to the interaction of antiferromagnetic Bi0.9La0.1FeO3 with ionic conductor KBr, can be relevant.
- Authors:
-
- Scientific-Practical Materials Research Centre of NAS of Belarus, Minsk (Belarus)
- NAS of Ukraine, Kyiv (Ukraine). Inst. of Physics
- National Research Univ. of Electronic Technology "MIET", Moscow (Russian Federation); I.M. Sechenov First Moscow State Medical Univ., Moscow (Russian Federation)
- National Research Univ. of Electronic Technology "MIET", Moscow (Russian Federation)
- Inst. of Low Temperature and Structure Research, PAS, Wroclaw, (Poland)
- Vilnius Univ. (Lithuania). Inst. of Chemistry
- Charles Univ., Prague (Czech Republic). Faculty of Mathematics and Physics
- Univ. of Duisburg-Essen, Essen (Germany). Inst. for Materials Science and Center for Nanointegration Duisburg-Essen (CENIDE)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1624480
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 1; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; Science & Technology - Other Topics
Citation Formats
Karpinsky, Dmitry V., Fesenko, Olena M., Silibin, Maxim V., Dubkov, Sergei V., Chaika, Mykola, Yaremkevich, Andrii, Lukowiak, Anna, Gerasymchuk, Yuri, Stręk, Wiesław, Pakalniškis, Andrius, Skaudzius, Ramunas, Kareiva, Aivaras, Fomichov, Yevhen M., Shvartsman, Vladimir V., Kalinin, Sergei V., Morozovsky, Nicholas V., and Morozovska, Anna N.. Ferromagnetic-like behavior of Bi0.9La0.1FeO3–KBr nanocomposites. United States: N. p., 2019.
Web. doi:10.1038/s41598-019-46834-0.
Karpinsky, Dmitry V., Fesenko, Olena M., Silibin, Maxim V., Dubkov, Sergei V., Chaika, Mykola, Yaremkevich, Andrii, Lukowiak, Anna, Gerasymchuk, Yuri, Stręk, Wiesław, Pakalniškis, Andrius, Skaudzius, Ramunas, Kareiva, Aivaras, Fomichov, Yevhen M., Shvartsman, Vladimir V., Kalinin, Sergei V., Morozovsky, Nicholas V., & Morozovska, Anna N.. Ferromagnetic-like behavior of Bi0.9La0.1FeO3–KBr nanocomposites. United States. https://doi.org/10.1038/s41598-019-46834-0
Karpinsky, Dmitry V., Fesenko, Olena M., Silibin, Maxim V., Dubkov, Sergei V., Chaika, Mykola, Yaremkevich, Andrii, Lukowiak, Anna, Gerasymchuk, Yuri, Stręk, Wiesław, Pakalniškis, Andrius, Skaudzius, Ramunas, Kareiva, Aivaras, Fomichov, Yevhen M., Shvartsman, Vladimir V., Kalinin, Sergei V., Morozovsky, Nicholas V., and Morozovska, Anna N.. Thu .
"Ferromagnetic-like behavior of Bi0.9La0.1FeO3–KBr nanocomposites". United States. https://doi.org/10.1038/s41598-019-46834-0. https://www.osti.gov/servlets/purl/1624480.
@article{osti_1624480,
title = {Ferromagnetic-like behavior of Bi0.9La0.1FeO3–KBr nanocomposites},
author = {Karpinsky, Dmitry V. and Fesenko, Olena M. and Silibin, Maxim V. and Dubkov, Sergei V. and Chaika, Mykola and Yaremkevich, Andrii and Lukowiak, Anna and Gerasymchuk, Yuri and Stręk, Wiesław and Pakalniškis, Andrius and Skaudzius, Ramunas and Kareiva, Aivaras and Fomichov, Yevhen M. and Shvartsman, Vladimir V. and Kalinin, Sergei V. and Morozovsky, Nicholas V. and Morozovska, Anna N.},
abstractNote = {We studied magnetostatic response of the Bi0.9La0.1FeO3– KBr composites (BLFO-KBr) consisting of nanosized (≈100nm) ferrite Bi0.9La0.1FeO3 (BLFO) conjugated with fine grinded ionic conducting KBr. When the fraction of KBr is rather small (less than 15wt%)the magnetic response of the composite is very weak and similar to that observed for the BLFO (pure KBr matrix without Bi1-xLaxFeO3 has no magnetic response as anticipated). However, when the fraction of KBr increases above 15%,the magnetic response of the composite changes substantially and the field dependence of magnetization reveals ferromagnetic-like hysteresis loop with a remnant magnetization about 0.14emu/g and coercive field about 1.8Tesla (at room temperature). Nothing similar to the ferromagnetic-like hysteresis loop can be observed in Bi1-zLazFeO3 ceramics with z≤0.15, which magnetization quasi-linearly increases with magnetic field. Different physical mechanisms were considered to explain the unusual experimental results for BLFO-KBr nanocomposites, but only those among them, which are highly sensitive to the interaction of antiferromagnetic Bi0.9La0.1FeO3 with ionic conductor KBr, can be relevant.},
doi = {10.1038/s41598-019-46834-0},
journal = {Scientific Reports},
number = 1,
volume = 9,
place = {United States},
year = {2019},
month = {7}
}
Works referenced in this record:
Thermodynamic potential and phase diagram for multiferroic bismuth ferrite (BiFeO 3 )
journal, May 2017
- Karpinsky, Dmitry V.; Eliseev, Eugene A.; Xue, Fei
- npj Computational Materials, Vol. 3, Issue 1
Size-Dependent Properties of Multiferroic BiFeO 3 Nanoparticles
journal, December 2007
- Selbach, Sverre M.; Tybell, Thomas; Einarsrud, Mari-Ann
- Chemistry of Materials, Vol. 19, Issue 26
Evolution of crystal structure and ferroic properties of La-doped BiFeO3 ceramics near the rhombohedral-orthorhombic phase boundary
journal, April 2013
- Karpinsky, D. V.; Troyanchuk, I. O.; Tovar, M.
- Journal of Alloys and Compounds, Vol. 555
Linear magnetoelectric coupling and ferroelectricity induced by the flexomagnetic effect in ferroics
journal, November 2011
- Eliseev, E. A.; Glinchuk, M. D.; Khist, V.
- Physical Review B, Vol. 84, Issue 17
Structural transitions and unusual magnetic behavior in Mn-doped Bi 1−x La x FeO 3 perovskites
journal, October 2012
- Khomchenko, V. A.; Troyanchuk, I. O.; Karpinsky, D. V.
- Journal of Applied Physics, Vol. 112, Issue 8
Equilibrium and stability of polarization in ultrathin ferroelectric films with ionic surface compensation
journal, August 2011
- Stephenson, G. Brian; Highland, Matthew J.
- Physical Review B, Vol. 84, Issue 6
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Structure and Properties of Functional Oxide Thin Films: Insights From Electronic-Structure Calculations
journal, July 2011
- Rondinelli, James M.; Spaldin, Nicola A.
- Advanced Materials, Vol. 23, Issue 30
Temperature and Composition-Induced Structural Transitions in Bi 1− x La(Pr) x FeO 3 Ceramics
journal, May 2014
- Karpinsky, Dmitry V.; Troyanchuk, Igor O.; Tovar, Michael
- Journal of the American Ceramic Society, Vol. 97, Issue 8
Structural stability and magnetic properties of Bi1−xLa(Pr)xFeO3 solid solutions
journal, November 2011
- Karpinsky, D. V.; Troyanchuk, I. O.; Mantytskaya, O. S.
- Solid State Communications, Vol. 151, Issue 22
The evolution of multiferroics
journal, July 2016
- Fiebig, Manfred; Lottermoser, Thomas; Meier, Dennis
- Nature Reviews Materials, Vol. 1, Issue 8
Surface-induced piezomagnetic, piezoelectric, and linear magnetoelectric effects in nanosystems
journal, August 2010
- Eliseev, E. A.; Morozovska, A. N.; Glinchuk, M. D.
- Physical Review B, Vol. 82, Issue 8
Structural Evolution of the BiFeO 3 −LaFeO 3 System
journal, January 2011
- Rusakov, Dmitriy A.; Abakumov, Artem M.; Yamaura, Kazunari
- Chemistry of Materials, Vol. 23, Issue 2
Polarization Switching without Domain Formation at the Intrinsic Coercive Field in Ultrathin Ferroelectric
journal, October 2010
- Highland, Matthew J.; Fister, Timothy T.; Richard, Marie-Ingrid
- Physical Review Letters, Vol. 105, Issue 16
Elastic effects of vacancies in strontium titanate: Short- and long-range strain fields, elastic dipole tensors, and chemical strain
journal, August 2009
- Freedman, Daniel A.; Roundy, D.; Arias, T. A.
- Physical Review B, Vol. 80, Issue 6
Rotomagnetic coupling in fine-grained multiferroic : Theory and experiment
journal, April 2018
- Morozovska, Anna N.; Eliseev, Eugene A.; Glinchuk, Maya D.
- Physical Review B, Vol. 97, Issue 13
phase and metal-insulator transition in multiferroic
journal, January 2008
- Palai, R.; Katiyar, R. S.; Schmid, H.
- Physical Review B, Vol. 77, Issue 1
Physics and Applications of Bismuth Ferrite
journal, June 2009
- Catalan, Gustau; Scott, James F.
- Advanced Materials, Vol. 21, Issue 24
The β-to-γ Transition in BiFeO3: A Powder Neutron Diffraction Study
journal, June 2010
- Arnold, Donna C.; Knight, Kevin S.; Catalan, Gustau
- Advanced Functional Materials, Vol. 20, Issue 13
Sol–gel (combustion) synthesis and characterization of different alkaline earth metal (Ca, Sr, Ba) stannates
journal, October 2012
- Stanulis, Andrius; Sakirzanovas, Simas; Van Bael, Marlies
- Journal of Sol-Gel Science and Technology, Vol. 64, Issue 3
Spiral magnetic ordering in bismuth ferrite
journal, August 1982
- Sosnowska, I.; Neumaier, T. P.; Steichele, E.
- Journal of Physics C: Solid State Physics, Vol. 15, Issue 23
Anisotropic conductivity of uncharged domain walls in BiFeO
journal, August 2012
- Morozovska, Anna N.; Vasudevan, Rama K.; Maksymovych, Peter
- Physical Review B, Vol. 86, Issue 8
Composition-driven structural phase transitions in rare-earth-doped bifeo<sub>3</sub> ceramics: a review
journal, January 2015
- Arnold, Donna
- IEEE Transactions on Ultrasonics, Ferroelectrics, and Frequency Control, Vol. 62, Issue 1
Domain Wall Conduction and Polarization-Mediated Transport in Ferroelectrics
journal, April 2013
- Vasudevan, Rama K.; Wu, Weida; Guest, Jeffrey R.
- Advanced Functional Materials, Vol. 23, Issue 20
Magnetism in undoped MgO studied by density functional theory
journal, October 2009
- Wang, Fenggong; Pang, Zhiyong; Lin, Liang
- Physical Review B, Vol. 80, Issue 14
Surface phase transitions in BiFeO below room temperature
journal, May 2012
- Jarrier, R.; Marti, X.; Herrero-Albillos, J.
- Physical Review B, Vol. 85, Issue 18
Linear antiferrodistortive-antiferromagnetic effect in multiferroics: Physical manifestations
journal, August 2015
- Morozovska, Anna N.; Khist, Victoria V.; Glinchuk, Maya D.
- Physical Review B, Vol. 92, Issue 5
Magnetotransport at Domain Walls in
journal, February 2012
- He, Q.; Yeh, C. -H.; Yang, J. -C.
- Physical Review Letters, Vol. 108, Issue 6
Enhanced electric conductivity at ferroelectric vortex cores in BiFeO3
journal, November 2011
- Balke, Nina; Winchester, Benjamin; Ren, Wei
- Nature Physics, Vol. 8, Issue 1
Stabilization of weak ferromagnetism by strong magnetic response to epitaxial strain in multiferroic BiFeO3
journal, August 2015
- Dixit, Hemant; Hee Lee, Jun; Krogel, Jaron T.
- Scientific Reports, Vol. 5, Issue 1
Enhancement of ferroelectricity and ferromagnetism in rare earth element doped BiFeO3
journal, December 2008
- Cheng, Z. X.; Wang, X. L.; Dou, S. X.
- Journal of Applied Physics, Vol. 104, Issue 11
Temperature-Dependent Interplay of Dzyaloshinskii-Moriya Interaction and Single-Ion Anisotropy in Multiferroic
journal, September 2014
- Jeong, Jaehong; Le, Manh Duc; Bourges, P.
- Physical Review Letters, Vol. 113, Issue 10
MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005
- Spaldin, N. A.
- Science, Vol. 309, Issue 5733
Domain Wall Geometry Controls Conduction in Ferroelectrics
journal, September 2012
- Vasudevan, R. K.; Morozovska, A. N.; Eliseev, E. A.
- Nano Letters, Vol. 12, Issue 11
Reversible Chemical Switching of a Ferroelectric Film
journal, January 2009
- Wang, R. V.; Fong, D. D.; Jiang, F.
- Physical Review Letters, Vol. 102, Issue 4
Ferroionic states in ferroelectric thin films
journal, May 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Morozovsky, Nicholas V.
- Physical Review B, Vol. 95, Issue 19
Temperature dependence of the crystal and magnetic structures of BiFeO 3
journal, April 1980
- Fischer, P.; Polomska, M.; Sosnowska, I.
- Journal of Physics C: Solid State Physics, Vol. 13, Issue 10
Thermodynamics of electromechanically coupled mixed ionic-electronic conductors: Deformation potential, Vegard strains, and flexoelectric effect
journal, May 2011
- Morozovska, A. N.; Eliseev, E. A.; Tagantsev, A. K.
- Physical Review B, Vol. 83, Issue 19
Magnetoelectric and multiferroic media
journal, June 2012
- Pyatakov, Aleksandr P.; Zvezdin, Anatolii K.
- Physics-Uspekhi, Vol. 55, Issue 6
Structure and spin dynamics of multiferroic BiFeO 3
journal, October 2014
- Park, Je-Geun; Le, Manh Duc; Jeong, Jaehong
- Journal of Physics: Condensed Matter, Vol. 26, Issue 43
Electric-Field-Induced Spin Flop in Single Crystals at Room Temperature
journal, June 2008
- Lebeugle, D.; Colson, D.; Forget, A.
- Physical Review Letters, Vol. 100, Issue 22
Ferromagnetism of undoped GaN mediated by through-bond spin polarization between nitrogen dangling bonds
journal, April 2009
- Jin, Hao; Dai, Ying; Huang, BaiBiao
- Applied Physics Letters, Vol. 94, Issue 16
Mixed electrochemical–ferroelectric states in nanoscale ferroelectrics
journal, May 2017
- Yang, Sang Mo; Morozovska, Anna N.; Kumar, Rajeev
- Nature Physics, Vol. 13, Issue 8
Stabilization of Monodomain Polarization in Ultrathin Films
journal, March 2006
- Fong, D. D.; Kolpak, A. M.; Eastman, J. A.
- Physical Review Letters, Vol. 96, Issue 12, Article No. 127601
Electric-field control of spin waves at room temperature in multiferroic BiFeO3
journal, November 2010
- Rovillain, P.; de Sousa, R.; Gallais, Y.
- Nature Materials, Vol. 9, Issue 12
Low-temperature synthesis of single-crystalline BiFeO3 using molten KCl–KBr salt
journal, September 2013
- Liu, Yin; Qian, Qian; Yi, Zhiguo
- Ceramics International, Vol. 39, Issue 7
Domain wall nanoelectronics
journal, February 2012
- Catalan, G.; Seidel, J.; Ramesh, R.
- Reviews of Modern Physics, Vol. 84, Issue 1
Single phase, electrically insulating, multiferroic La-substituted BiFeO 3 prepared by mechanosynthesis
journal, January 2014
- Perejón, Antonio; Sánchez-Jiménez, Pedro E.; Pérez-Maqueda, Luis A.
- J. Mater. Chem. C, Vol. 2, Issue 39
Piezoresponse of ferroelectric films in ferroionic states: Time and voltage dynamics
journal, May 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Morozovsky, Nicholas V.
- Applied Physics Letters, Vol. 110, Issue 18
Anisotropic Superexchange Interaction and Weak Ferromagnetism
journal, October 1960
- Moriya, Tôru
- Physical Review, Vol. 120, Issue 1
Effect of surface ionic screening on the polarization reversal scenario in ferroelectric thin films: Crossover from ferroionic to antiferroionic states
journal, December 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Kurchak, Anatolii I.
- Physical Review B, Vol. 96, Issue 24
Sol-gel combustion synthesis of high-quality chromium-doped mixed-metal garnets Y3Ga5O12 and Gd3Sc2Ga3O12
journal, March 2018
- Butkute, S.; Gaigalas, E.; Beganskiene, A.
- Journal of Alloys and Compounds, Vol. 739
Equilibrium Polarization of Ultrathin with Surface Compensation Controlled by Oxygen Partial Pressure
journal, October 2011
- Highland, M. J.; Fister, T. T.; Fong, D. D.
- Physical Review Letters, Vol. 107, Issue 18
Domain switching in single-phase multiferroics
journal, June 2018
- Jia, Tingting; Cheng, Zhenxiang; Zhao, Hongyang
- Applied Physics Reviews, Vol. 5, Issue 2
Surface-screening mechanisms in ferroelectric thin films and their effect on polarization dynamics and domain structures
journal, January 2018
- Kalinin, Sergei V.; Kim, Yunseok; Fong, Dillon D.
- Reports on Progress in Physics, Vol. 81, Issue 3
Magnetoelectric and multiferroic media [Магнитоэлектрические материалы и мультиферроики]
journal, January 2012
- Pyatakov, Aleksandr P.; Zvezdin, Anatolii K.
- Uspekhi Fizicheskih Nauk, Vol. 182, Issue 6
Electric-field control of spin waves at room temperature in multiferroic BiFeO3
text, January 2010
- Rovillain, P.; de Sousa, R.; Gallais, Y.
- arXiv
Equilibrium and Stability of Polarization in Ultrathin Ferroelectric Films with Ionic Surface Compensation
text, January 2011
- Stephenson, G. Brian; Highland, Matthew J.
- arXiv
Effect of surface ionic screening on polarization reversal scenario in ferroelectric thin films: crossover from ferroionic to antiferroionic states
text, January 2017
- Morozovska, Anna N.; Eliseev, Eugene A.; Kurchak, Anatolii I.
- arXiv
Rotomagnetic coupling in fine grained multiferroic BiFeO3: Theory and experiment
text, January 2018
- Morozovska, Anna N.; Eliseev, Eugene A.; Glinchuk, Maya D.
- arXiv