Stabilizing polymer electrolytes in high-voltage lithium batteries

Choudhury, Snehashis; Tu, Zhengyuan; Nijamudheen, A.; Zachman, Michael J.; Stalin, Sanjuna; Deng, Yue; Zhao, Qing; Vu, Duylinh; Kourkoutis, Lena F.; Mendoza-Cortes, Jose L.; Archer, Lynden A.

doi:10.1038/s41467-019-11015-0

Title: Stabilizing polymer electrolytes in high-voltage lithium batteries

Journal Article · 11 July 2019 · Nature Communications

DOI: https://doi.org/10.1038/s41467-019-11015-0 · OSTI ID:1624171

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^[4]; Stalin, Sanjuna ^[2]; Deng, Yue ^[2];

^[2]; Vu, Duylinh ^[2];

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Cornell Univ., Ithaca, NY (United States); DOE/OSTI
Cornell Univ., Ithaca, NY (United States)
Florida State Univ., Tallahassee, FL (United States)
Cornell Univ., Ithaca, NY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Electrochemical cells that utilize lithium and sodium anodes are under active study for their potential to enable high-energy batteries. Liquid and solid polymer electrolytes based on ether chemistry are among the most promising choices for rechargeable lithium and sodium batteries. However, uncontrolled anionic polymerization of these electrolytes at low anode potentials and oxidative degradation at working potentials of the most interesting cathode chemistries have led to a quite concession in the field that solid-state or flexible batteries based on polymer electrolytes can only be achieved in cells based on low- or moderate-voltage cathodes. Here, we show that cationic chain transfer agents can prevent degradation of ether electrolytes by arresting uncontrolled polymer growth at the anode. We also report that cathode electrolyte interphases composed of preformed anionic polymers and supramolecules provide a fundamental strategy for extending the high voltage stability of ether-based electrolytes to potentials well above conventionally accepted limits.

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Research Organization:: Cornell Univ., Ithaca, NY (United States)

Sponsoring Organization:: Beijing Institute of Collaboratory Innovation (BICI); Cornell Center for Materials Research (CCMR); Florida State University (FSU); National Science Foundation (NSF); State of Florida; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0001086

OSTI ID:: 1624171

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 10; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
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Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries Porcarelli, Luca; Gerbaldi, Claudio; Bella, Federico Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep19892	journal	January 2016
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Confining electrodeposition of metals in structured electrolytes Choudhury, Snehashis; Vu, Duylinh; Warren, Alexander Proceedings of the National Academy of Sciences, Vol. 115, Issue 26 https://doi.org/10.1073/pnas.1803385115	journal	June 2018
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Stable Lithium Electrodeposition in Liquid and Nanoporous Solid Electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden arXiv https://doi.org/10.48550/arxiv.1404.6177	text	January 2014

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