Nonflammable Lithium Metal Full Cells with Ultra-high Energy Density Based on Coordinated Carbonate Electrolytes

Cho, Sung-Ju; Yu, Dae-Eun; Pollard, Travis P.; Moon, Hyunseok; Jang, Minchul; Borodin, Oleg; Lee, Sang-Young

doi:10.1016/j.isci.2020.100844

Title: Nonflammable Lithium Metal Full Cells with Ultra-high Energy Density Based on Coordinated Carbonate Electrolytes

Journal Article · 01 February 2020 · iScience

DOI: https://doi.org/10.1016/j.isci.2020.100844 · OSTI ID:1623688

Cho, Sung-Ju ^[1]; Yu, Dae-Eun ^[1]; Pollard, Travis P. ^[2]; Moon, Hyunseok ^[1]; Jang, Minchul ^[3]; Borodin, Oleg ^[2]; Lee, Sang-Young ^[1]

Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of). School of Energy and Chemical Engineering. Dept. of Energy Engineering
Army Research Lab., Adelphi, MD (United States). Sensor and Electron Devices Directorate. Energy and Biomaterials Division. Battery Science Branch
LG Chem., Daejeon (Korea, Republic of). Battery R&D Center

Coupling thin Li metal anodes with high-capacity/high-voltage cathodes such as LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) is a promising way to increase lithium battery energy density. Yet, the realization of high-performance full cells remains a formidable challenge. Here, we demonstrate a new class of highly coordinated, nonflammable carbonate electrolytes based on lithium bis(fluorosulfonyl)imide (LiFSI) in propylene carbonate/fluoroethylene carbonate mixtures. Utilizing an optimal salt concentration (4 M LiFSI) of the electrolyte results in a unique coordination structure of Li⁺-FSI^--solvent cluster, which is critical for enabling the formation of stable interfaces on both the thin Li metal anode and high-voltage NCM811 cathode. Under highly demanding cell configuration and operating conditions (Li metal anode = 35 μm, areal capacity/charge voltage of NCM811 cathode = 4.8 mAh cm^-2/4.6 V, and anode excess capacity [relative to the cathode] = 0.83), the Li metal-based full cell provides exceptional electrochemical performance (energy densities = 679 Wh kg_cell^-1/1,024 Wh L_cell^-1) coupled with nonflammability.

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Research Organization:: Army Research Lab., Adelphi, MD (United States). Sensor and Electron Devices Directorate. Energy and Biomaterials Division. Battery Science Branch

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1623688

Journal Information:: iScience, Vol. 23, Issue 2; ISSN 2589-0042

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 49 works

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