skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Phase stabilization by electronic entropy in plutonium

Authors:
; ; ; ORCiD logo; ORCiD logo; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1619833
Resource Type:
Published Article
Journal Name:
Nature Communications
Additional Journal Information:
Journal Name: Nature Communications Journal Volume: 10 Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Harrison, N., Betts, J. B., Wartenbe, M. R., Balakirev, F. F., Richmond, S., Jaime, M., and Tobash, P. H. Phase stabilization by electronic entropy in plutonium. United Kingdom: N. p., 2019. Web. https://doi.org/10.1038/s41467-019-11166-0.
Harrison, N., Betts, J. B., Wartenbe, M. R., Balakirev, F. F., Richmond, S., Jaime, M., & Tobash, P. H. Phase stabilization by electronic entropy in plutonium. United Kingdom. https://doi.org/10.1038/s41467-019-11166-0
Harrison, N., Betts, J. B., Wartenbe, M. R., Balakirev, F. F., Richmond, S., Jaime, M., and Tobash, P. H. Thu . "Phase stabilization by electronic entropy in plutonium". United Kingdom. https://doi.org/10.1038/s41467-019-11166-0.
@article{osti_1619833,
title = {Phase stabilization by electronic entropy in plutonium},
author = {Harrison, N. and Betts, J. B. and Wartenbe, M. R. and Balakirev, F. F. and Richmond, S. and Jaime, M. and Tobash, P. H.},
abstractNote = {},
doi = {10.1038/s41467-019-11166-0},
journal = {Nature Communications},
number = 1,
volume = 10,
place = {United Kingdom},
year = {2019},
month = {7}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1038/s41467-019-11166-0

Citation Metrics:
Cited by: 3 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Magnetic-field, pressure, and temperature scaling of the first-order valence transition in pure and doped YbInCu 4
journal, July 1997


Equilibrium properties of delta-Pu: LDA+ U calculations (LDAequiv local density approximation)
journal, February 2000


Valence fluctuation phenomena
journal, January 1981

  • Lawrence, J. M.; Riseborough, P. S.; Parks, R. D.
  • Reports on Progress in Physics, Vol. 44, Issue 1
  • DOI: 10.1088/0034-4885/44/1/001

Electronic and phonon properties of six crystalline phases of Pu metal
journal, December 1998


Fiber Bragg Grating Dilatometry in Extreme Magnetic Field and Cryogenic Conditions
journal, November 2017

  • Jaime, Marcelo; Corvalán Moya, Carolina; Weickert, Franziska
  • Sensors, Vol. 17, Issue 11
  • DOI: 10.3390/s17112572

Melting of the light actinides
journal, January 2000


Self-interaction-corrected local spin density theory of 5 f electron localization in actinides
journal, September 2007


Electronic properties of f -electron metals using the generalized gradient approximation
journal, September 1994


Suppression of the γ–α structural phase transition in Ce 0.8 La 0.1 Th 0.1 by large magnetic fields
journal, February 2005

  • Drymiotis, F.; Singleton, J.; Harrison, N.
  • Journal of Physics: Condensed Matter, Vol. 17, Issue 7
  • DOI: 10.1088/0953-8984/17/7/L01

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997

  • Anisimov, Vladimir I.; Aryasetiawan, F.; Lichtenstein, A. I.
  • Journal of Physics: Condensed Matter, Vol. 9, Issue 4, p. 767-808
  • DOI: 10.1088/0953-8984/9/4/002

Piezomagnetism and magnetoelastic memory in uranium dioxide
journal, July 2017


Volume magnetostriction of intermediate valence systems
journal, February 1985


Volume magnetostriction of rare-earth metals with unstable 4f shells
journal, January 1986


Multiconfigurational nature of 5f orbitals in uranium and plutonium intermetallics
journal, June 2012

  • Booth, C. H.; Jiang, Y.; Wang, D. L.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 26
  • DOI: 10.1073/pnas.1200725109

Magnetic and magnetoelastic properties of PrNi 5 single crystal
journal, February 1988


Dual nature of 5 f electrons:  Effect of intra-atomic correlations on hopping anisotropies
journal, March 2004


Magnetostriction in metals
journal, November 1971


Correlated electrons in δ-plutonium within a dynamical mean-field picture
journal, April 2001

  • Savrasov, S. Y.; Kotliar, G.; Abrahams, E.
  • Nature, Vol. 410, Issue 6830
  • DOI: 10.1038/35071035

Spin-polarized relativistic linear-muffin-tin-orbital method: Volume-dependent electronic structure and magnetic moment of plutonium
journal, June 1991


Cancellation of spin and orbital magnetic moments in δ-Pu: Theory
journal, October 2007


Density-functional investigation of magnetism in δ -Pu
journal, November 2002


A unified and efficient theory for the structural properties of actinides and phases of plutonium
journal, September 2018


Phase stability and phase transformations in Pu–Ga alloys
journal, January 2004


Gallium stabilization of δ Pu : Density-functional calculations
journal, November 2005


Density-Functional Calculations of α , β , γ , δ , δ , and ϵ Plutonium
journal, May 2004


Phonon density of states of α - and δ -plutonium by inelastic x-ray scattering
journal, February 2009


Hidden disorder in the α δ transformation of Pu-1.9 at. % Ga
journal, June 2012


Influence of point defects and impurities on the dynamical stability of δ -plutonium
journal, May 2017

  • Dorado, B.; Bieder, J.; Torrent, M.
  • Journal of Physics: Condensed Matter, Vol. 29, Issue 24
  • DOI: 10.1088/1361-648X/aa6eb7

Absence of magnetic moments in plutonium
journal, August 2005


Magnetism or bonding: A nearly periodic table of transition elements
journal, March 1983


Simple Scaling Approach to the Volume Magnetostriction in Unstable-Moment Systems
journal, April 1986


Fluctuating valence in a correlated solid and the anomalous properties of δ-plutonium
journal, March 2007


First-order valence transition in YbInCu 4 in the ( B , T )-plane
journal, November 2000

  • Dzero, M. O.; Gor'kov, L. P.; Zvezdin, A. K.
  • Journal of Physics: Condensed Matter, Vol. 12, Issue 47
  • DOI: 10.1088/0953-8984/12/47/102

Coulomb- U and magnetic-moment collapse in δ-Pu
journal, February 2005


Phase stability and phase transformations in plutonium and plutonium-gallium alloys
journal, August 2004

  • Mitchell, Jeremy N.; Schwartz, Daniel S.; Stan, Marius
  • Metallurgical and Materials Transactions A, Vol. 35, Issue 8
  • DOI: 10.1007/s11661-006-0206-8

Phonon Dispersions of fcc  -Plutonium-Gallium by Inelastic X-ray Scattering
journal, August 2003


Giant magnetic Grüneisen parameters in nearly ferromagnetic and heavy-fermion systems
journal, April 1988


Spectral properties of δ -plutonium: Sensitivity to 5 f occupancy
journal, December 2007


The valence-fluctuating ground state of plutonium
journal, July 2015

  • Janoschek, Marc; Das, Pinaki; Chakrabarti, Bismayan
  • Science Advances, Vol. 1, Issue 6
  • DOI: 10.1126/sciadv.1500188

The dual nature of 5f electrons and the origin of heavy fermions in U compounds
journal, July 2003


The mixed valence energy parameters of some Ce and Yb systems
journal, February 1985


Nature of the 5 f states in actinide metals
journal, February 2009


Experimental Electronic Heat Capacities of α - and δ -Plutonium: Heavy-Fermion Physics in an Element
journal, November 2003


A novel electronic configuration of the 5f states in δ-plutonium as revealed by the photo-electron spectra
journal, April 2004

  • Wills, J. M.; Eriksson, O.; Delin, A.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 135, Issue 2-3
  • DOI: 10.1016/j.elspec.2004.02.169

Calculated Phonon Spectra of Plutonium at High Temperatures
journal, May 2003


Dynamical mean-field theory of strongly correlated fermion systems and the limit of infinite dimensions
journal, January 1996

  • Georges, Antoine; Kotliar, Gabriel; Krauth, Werner
  • Reviews of Modern Physics, Vol. 68, Issue 1
  • DOI: 10.1103/RevModPhys.68.13

The α γ Transition of Cerium Is Entropy Driven
journal, February 2006


Origin of the multiple configurations that drive the response of δ-plutonium’s elastic moduli to temperature
journal, September 2016

  • Migliori, Albert; Söderlind, Per; Landa, Alexander
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 40
  • DOI: 10.1073/pnas.1609215113

Novel electronic configuration in ∂−Pu
journal, June 1999


Invar model for δ-phase Pu: thermal expansion, elastic and magnetic properties
journal, June 2006