Understanding solvent effects on adsorption and protonation in porous catalysts

Gould, Nicholas S.; Li, Sha; Cho, Hong Je; Landfield, Harrison; Caratzoulas, Stavros; Vlachos, Dionisios; Bai, Peng; Xu, Bingjun

doi:10.1038/s41467-020-14860-6

Title: Understanding solvent effects on adsorption and protonation in porous catalysts

Journal Article · 26 February 2020 · Nature Communications

DOI: https://doi.org/10.1038/s41467-020-14860-6 · OSTI ID:1619537

Gould, Nicholas S.; Li, Sha; Cho, Hong Je; Landfield, Harrison; Caratzoulas, Stavros;

;

Abstract Solvent selection is a pressing challenge in developing efficient and selective liquid phase catalytic processes, as predictive understanding of the solvent effect remains lacking. In this work, an attenuated total reflection infrared spectroscopy technique is developed to quantitatively measure adsorption isotherms on porous materials in solvent and decouple the thermodynamic contributions of van der Waals interactions within zeolite pore walls from those of pore-phase proton transfer. While both the pore diameter and the solvent identity dramatically impact the confinement (adsorption) step, the solvent identity plays a dominant role in proton-transfer. Combined computational and experimental investigations show increasingly favorable pore-phase proton transfer to pyridine in the order: water < acetonitrile < 1,4 – dioxane. Equilibrium methods unaffected by mass transfer limitations are outlined for quantitatively estimating fundamental thermodynamic values using statistical thermodynamics.

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Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC)

Grant/Contract Number:: SC0001004

OSTI ID:: 1619537

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 11; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

References (80)

Adsorption of glucose into zeolite beta from aqueous solution Bai, Peng; Siepmann, J. Ilja; Deem, Michael W. AIChE Journal, Vol. 59, Issue 9 https://doi.org/10.1002/aic.14104	journal	April 2013
Two-Dimensional IR Pressure-Jump Spectroscopy of Adsorbed Species for Zeolites Chenevarin, Stéphane; Thibault-Starzyk, Frédéric Angewandte Chemie International Edition, Vol. 43, Issue 9 https://doi.org/10.1002/anie.200352754	journal	February 2004
Solvent Effects in Acid-Catalyzed Biomass Conversion Reactions Mellmer, Max A.; Sener, Canan; Gallo, Jean Marcel R. Angewandte Chemie International Edition, Vol. 53, Issue 44 https://doi.org/10.1002/anie.201408359	journal	September 2014
Adsorbate Clustering and Proton Transfer in Zeolites: NMR Spectroscopy and Theory Kletnieks, P. W.; Ehresmann, J. O.; Nicholas, J. B. ChemPhysChem, Vol. 7, Issue 1 https://doi.org/10.1002/cphc.200500313	journal	January 2006
Organic Solvent Effects in Biomass Conversion Reactions Shuai, Li; Luterbacher, Jeremy ChemSusChem, Vol. 9, Issue 2 https://doi.org/10.1002/cssc.201501148	journal	December 2015
Determination of Integrated Molar Extinction Coefficients for Infrared Absorption Bands of Pyridine Adsorbed on Solid Acid Catalysts Emeis, C. A. Journal of Catalysis, Vol. 141, Issue 2 https://doi.org/10.1006/jcat.1993.1145	journal	June 1993
FT-IR Studies on Light Olefin Skeletal Isomerization Catalysis Trombetta, Marcella; Busca, Guido; Rossini, Stefano Journal of Catalysis, Vol. 179, Issue 2 https://doi.org/10.1006/jcat.1998.2251	journal	October 1998
Characterization of stoichiometric adsorption complexes in H-ZSM-5 using microcalorimetry Parrillo, D. J.; Gorte, R. J. Catalysis Letters, Vol. 16, Issue 1-2 https://doi.org/10.1007/BF00764350	journal	January 1992
Microcalorimetric studies of zeolite acidity Chen, D. T.; Sharma, S. B.; Filimonov, I. Catalysis Letters, Vol. 12, Issue 1-3 https://doi.org/10.1007/BF00767202	journal	January 1992
The place of sioh groups in the absolute acidity scale from ab initio calculations Heidrich, Dietmar; Volkmann, Dietmar; Żurawski, Bronisz. xl;law Chemical Physics Letters, Vol. 80, Issue 1 https://doi.org/10.1016/0009-2614(81)80057-7	journal	May 1981
An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity Parry, E. Journal of Catalysis, Vol. 2, Issue 5 https://doi.org/10.1016/0021-9517(63)90102-7	journal	October 1963
Infrared study of cation-exchanged mordenites and Y faujasites adsorbed with ammonia and pyridine Yashima, T. Journal of Catalysis, Vol. 27, Issue 2 https://doi.org/10.1016/0021-9517(72)90277-1	journal	November 1972
Production of hydronium beta alumina from sodium beta alumina and characterization of conversion products Breiter, M. W.; Farrington, G. C.; Roth, W. L. Materials Research Bulletin, Vol. 12, Issue 9 https://doi.org/10.1016/0025-5408(77)90101-5	journal	September 1977
Adsorption of water on ZSM-5 zeolites Hunger, B.; Heuchel, M.; Matysik, S. Thermochimica Acta, Vol. 269-270 https://doi.org/10.1016/0040-6031(95)02541-3	journal	December 1995
Separation of ethanol/water mixture by silicalite membrane on pervaporation Sano, Tsuneji; Yanagishita, Hiroshi; Kiyozumi, Yoshimichi Journal of Membrane Science, Vol. 95, Issue 3, p. 221-228 https://doi.org/10.1016/0376-7388(94)00120-0	journal	November 1994
Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules Lercher, Johannes A.; Gründling, Christian; Eder-Mirth, Gabriele Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00248-0	journal	February 1996
Quantitative infrared study of the distinct acidic hydroxyl groups contained in modified Y zeolites Khabtou, S.; Chevreau, T.; Lavalley, J. C. Microporous Materials, Vol. 3, Issue 1-2 https://doi.org/10.1016/0927-6513(94)00015-8	journal	September 1994
Limitation in the application of pyridine for quantitative studies of brönsted acidity in relatively aluminous zeolites Makarova, Marina A.; Karim, Khalid; Dwyer, John Microporous Materials, Vol. 4, Issue 2-3 https://doi.org/10.1016/0927-6513(94)00093-B	journal	June 1995
Evidence for dimeric and tetrameric water clusters in HZSM-5 Olson, D. H.; Zygmunt, S. A.; Erhardt, M. K. Zeolites, Vol. 18, Issue 5-6 https://doi.org/10.1016/S0144-2449(97)00024-9	journal	May 1997
An FT-IR study of the internal and external surfaces of HZSM5 zeolite Trombetta, Marcella; Armaroli, Tiziana; Gutièrrez Alejandre, Aı̀da Applied Catalysis A: General, Vol. 192, Issue 1 https://doi.org/10.1016/S0926-860X(99)00338-5	journal	February 2000
Catalytic reaction rates in thermodynamically non-ideal systems Madon, Rostam J.; Iglesia, Enrique Journal of Molecular Catalysis A: Chemical, Vol. 163, Issue 1-2 https://doi.org/10.1016/S1381-1169(00)00386-1	journal	December 2000
Novel pathways for the preparation of mesoporous MCM-41 materials: control of porosity and morphology Grün, Michael; Unger, Klaus K.; Matsumoto, Akihiko Microporous and Mesoporous Materials, Vol. 27, Issue 2-3 https://doi.org/10.1016/S1387-1811(98)00255-8	journal	February 1999
Measuring sorption effects at zeolite acid sites: pursuing ideas from W.O. Haag Gorte, R. J.; White, D. Microporous and Mesoporous Materials, Vol. 35-36 https://doi.org/10.1016/S1387-1811(99)00241-3	journal	April 2000
In situ ATR-IR study on aqueous phase reforming reactions of glycerol over a Pt/γ-Al2O3 catalyst Copeland, John R.; Foo, Guo Shiou; Harrison, Lindsey A. Catalysis Today, Vol. 205 https://doi.org/10.1016/j.cattod.2012.08.002	journal	April 2013
Sensitivity enhancement and dynamic behavior analysis by modulation excitation spectroscopy: Principle and application in heterogeneous catalysis Urakawa, Atsushi; Bürgi, Thomas; Baiker, Alfons Chemical Engineering Science, Vol. 63, Issue 20 https://doi.org/10.1016/j.ces.2007.06.009	journal	October 2008
Effect of liquid water on acid sites of NaY: An in situ liquid phase spectroscopic study Gould, Nicholas S.; Xu, Bingjun Journal of Catalysis, Vol. 342 https://doi.org/10.1016/j.jcat.2016.08.008	journal	October 2016
Quantification of acid site densities on zeolites in the presence of solvents via determination of extinction coefficients of adsorbed pyridine Gould, Nicholas S.; Xu, Bingjun Journal of Catalysis, Vol. 358 https://doi.org/10.1016/j.jcat.2017.11.016	journal	February 2018
Impact of environmental conditions on the sorption behavior of Pb(II) in Na-bentonite suspensions Yang, Shitong; Zhao, Donglin; Zhang, Hui Journal of Hazardous Materials, Vol. 183, Issue 1-3 https://doi.org/10.1016/j.jhazmat.2010.07.072	journal	November 2010
Influence of the nitric acid treatment on Al removal, framework composition and acidity of BEA zeolite investigated by XRD, FTIR and NMR Baran, Rafal; Millot, Yannick; Onfroy, Thomas Microporous and Mesoporous Materials, Vol. 163 https://doi.org/10.1016/j.micromeso.2012.06.055	journal	November 2012
New insights on zeolite chemistry by advanced IR and NMR characterization tools Gilson, Jean-Pierre; Fernandez, Christian; Thibault-Starzyk, Frédéric Journal of Molecular Catalysis A: Chemical, Vol. 305, Issue 1-2 https://doi.org/10.1016/j.molcata.2009.02.036	journal	June 2009
Are the thermodynamic parameters correctly estimated in liquid-phase adsorption phenomena? Anastopoulos, Ioannis; Kyzas, George Z. Journal of Molecular Liquids, Vol. 218 https://doi.org/10.1016/j.molliq.2016.02.059	journal	June 2016
Theory of complicated liquidsInvestigation of liquids, solvents and solvent effects with modern theoretical methods Kirchner, B. Physics Reports, Vol. 440, Issue 1-3 https://doi.org/10.1016/j.physrep.2006.11.005	journal	March 2007
Applications of Modulation Excitation Spectroscopy in Heterogeneous Catalysis Müller, Philipp; Hermans, Ive Industrial & Engineering Chemistry Research, Vol. 56, Issue 5 https://doi.org/10.1021/acs.iecr.6b04855	journal	January 2017
Solvent–Solid Interface of Acid Catalysts Studied by High Resolution MAS NMR Johnson, Robert L.; Hanrahan, Michael P.; Mellmer, Max The Journal of Physical Chemistry C, Vol. 121, Issue 32 https://doi.org/10.1021/acs.jpcc.7b04102	journal	August 2017
The Strength of Brønsted Acid Sites in Microporous Aluminosilicates Jones, Andrew J.; Iglesia, Enrique ACS Catalysis, Vol. 5, Issue 10 https://doi.org/10.1021/acscatal.5b01133	journal	August 2015
Phenomena Affecting Catalytic Reactions at Solid–Liquid Interfaces Sievers, Carsten; Noda, Yu; Qi, Long ACS Catalysis, Vol. 6, Issue 12 https://doi.org/10.1021/acscatal.6b02532	journal	November 2016
Operando Solid-State NMR Observation of Solvent-Mediated Adsorption-Reaction of Carbohydrates in Zeolites Qi, Long; Alamillo, Ricardo; Elliott, William A. ACS Catalysis, Vol. 7, Issue 5 https://doi.org/10.1021/acscatal.7b01045	journal	April 2017
Temperature-Programmed Desorption of Pyridine on Zeolites in the Presence of Liquid Solvents Gould, Nicholas S.; Xu, Bingjun ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b02536	journal	August 2018
What Is Measured When Measuring Acidity in Zeolites with Probe Molecules? Boronat, Mercedes; Corma, Avelino ACS Catalysis, Vol. 9, Issue 2 https://doi.org/10.1021/acscatal.8b04317	journal	January 2019
A Universal Descriptor for the Entropy of Adsorbed Molecules in Confined Spaces Dauenhauer, Paul J.; Abdelrahman, Omar A. ACS Central Science, Vol. 4, Issue 9 https://doi.org/10.1021/acscentsci.8b00419	journal	September 2018
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering Huber, George W.; Iborra, Sara; Corma, Avelino Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098 https://doi.org/10.1021/cr068360d	journal	September 2006
Adsorption of water on ZSM 5 zeolites Jentys, Andreas; Warecka, Gerhard; Derewinski, Miroslav The Journal of Physical Chemistry, Vol. 93, Issue 12 https://doi.org/10.1021/j100349a032	journal	June 1989
Potential maps of methane, water, and methanol in silicalite Vigne-Maeder, F.; Auroux, A. The Journal of Physical Chemistry, Vol. 94, Issue 1 https://doi.org/10.1021/j100364a053	journal	January 1990
Hydrophobic properties of zeolites Chen, N. Y. The Journal of Physical Chemistry, Vol. 80, Issue 1 https://doi.org/10.1021/j100542a013	journal	January 1976
Relationships between the thermodynamics of protonation in the gas and aqueous phase for 2-, 3-, and 4- substituted pyridines Aue, Donald H.; Webb, Hugh M.; Davidson, William R. Journal of the American Chemical Society, Vol. 113, Issue 5 https://doi.org/10.1021/ja00005a048	journal	February 1991
Integrated NMR and Ab Initio Study of Acetonitrile in Zeolites: A Reactive Complex Model of Zeolite Acidity Haw, James F.; Hall, Michael B.; Alvarado-Swaisgood, Aileen E. Journal of the American Chemical Society, Vol. 116, Issue 16 https://doi.org/10.1021/ja00095a039	journal	August 1994
Solvation and hydrogen bonding of pyridinium ions Arnett, E. M.; Chawla, B.; Bell, L. Journal of the American Chemical Society, Vol. 99, Issue 17 https://doi.org/10.1021/ja00459a034	journal	August 1977
Simple Synthesis Route to Monodispersed SBA-15 Silica Rods Sayari, Abdelhamid; Han, Bao-Hang; Yang, Yong Journal of the American Chemical Society, Vol. 126, Issue 44 https://doi.org/10.1021/ja0478734	journal	November 2004
Acidity Differences between Inorganic Solids Induced by Their Framework Structure. A Combined Quantum Mechanics/Molecular Mechanics ab Initio Study on Zeolites Brändle, Martin; Sauer, Joachim Journal of the American Chemical Society, Vol. 120, Issue 7 https://doi.org/10.1021/ja9729037	journal	February 1998
Genesis and Stability of Hydronium Ions in Zeolite Channels Wang, Meng; Jaegers, Nicholas R.; Lee, Mal-Soon Journal of the American Chemical Society, Vol. 141, Issue 8 https://doi.org/10.1021/jacs.8b07969	journal	January 2019
FTIR Adsorption Studies of H ₂ O and CH ₃ OH in the Isostructural H-SSZ-13 and H-SAPO-34: Formation of H-Bonded Adducts and Protonated Clusters Bordiga, Silvia; Regli, Laura; Lamberti, Carlo The Journal of Physical Chemistry B, Vol. 109, Issue 16 https://doi.org/10.1021/jp044324b	journal	April 2005
Efficient Approach for the Computational Study of Alcohol and Nitrile Adsorption in H-ZSM-5 Van der Mynsbrugge, Jeroen; Hemelsoet, Karen; Vandichel, Matthias The Journal of Physical Chemistry C, Vol. 116, Issue 9 https://doi.org/10.1021/jp2123828	journal	February 2012
Interaction of Water with Brønsted Acidic Sites of Zeolite Catalysts. Ab Initio Study of 1:1 and 2:1 Surface Complexes Krossner, Mariann; Sauer, Joachim The Journal of Physical Chemistry, Vol. 100, Issue 15 https://doi.org/10.1021/jp952775d	journal	January 1996
Confinement of Acetonitrile Molecules in Mordenite. A Computer Modeling Study Smirnov, Konstantin S.; Thibault-Starzyk, Frédéric The Journal of Physical Chemistry B, Vol. 103, Issue 40 https://doi.org/10.1021/jp991520n	journal	October 1999
Adsorption of Water and Ethanol in MFI-Type Zeolites Zhang, Ke; Lively, Ryan P.; Noel, James D. Langmuir, Vol. 28, Issue 23 https://doi.org/10.1021/la301122h	journal	May 2012
Multicomponent Adsorption of Alcohols onto Silicalite-1 from Aqueous Solution: Isotherms, Structural Analysis, and Assessment of Ideal Adsorbed Solution Theory Bai, Peng; Tsapatsis, Michael; Siepmann, J. Ilja Langmuir, Vol. 28, Issue 44 https://doi.org/10.1021/la303247c	journal	October 2012
A New Calorimeter for Simultaneous Measurements of Loading and Heats of Adsorption from Gaseous Mixtures Siperstein, Flor; Gorte, Raymond J.; Myers, Alan L. Langmuir, Vol. 15, Issue 4 https://doi.org/10.1021/la980946a	journal	February 1999
Solvent-assisted proton transfer in catalysis by zeolite solid acids Haw, James F.; Xu, Teng; Nicholas, John B. Nature, Vol. 389, Issue 6653 https://doi.org/10.1038/39843	journal	October 1997
Solvent-enabled control of reactivity for liquid-phase reactions of biomass-derived compounds Mellmer, Max A.; Sanpitakseree, Chotitath; Demir, Benginur Nature Catalysis, Vol. 1, Issue 3 https://doi.org/10.1038/s41929-018-0027-3	journal	February 2018
Production of 5-hydroxymethylfurfural and furfural by dehydration of biomass-derived mono- and poly-saccharides Chheda, Juben N.; Román-Leshkov, Yuriy; Dumesic, James A. Green Chem., Vol. 9, Issue 4, p. 342-350 https://doi.org/10.1039/B611568C	journal	January 2007
Production and upgrading of 5-hydroxymethylfurfural using heterogeneous catalysts and biomass-derived solvents Gallo, Jean Marcel R.; Alonso, David Martin; Mellmer, Max A. Green Chem., Vol. 15, Issue 1 https://doi.org/10.1039/C2GC36536G	journal	January 2013
Solvent effects in catalysis: rational improvements of catalysts via manipulation of solvent interactions Dyson, Paul J.; Jessop, Philip G. Catalysis Science & Technology, Vol. 6, Issue 10 https://doi.org/10.1039/C5CY02197A	journal	January 2016
A thermodynamic and kinetic analysis of solvent-enhanced selectivity in monophasic and biphasic reactor systems Schwartz, T. J.; Bond, J. Q. Chemical Communications, Vol. 53, Issue 58 https://doi.org/10.1039/C7CC03164E	journal	January 2017
Universal kinetic solvent effects in acid-catalyzed reactions of biomass-derived oxygenates Walker, Theodore W.; Chew, Alex K.; Li, Huixiang Energy & Environmental Science, Vol. 11, Issue 3 https://doi.org/10.1039/C7EE03432F	journal	January 2018
Catalyst characterization in the presence of solvent: development of liquid phase structure–activity relationships Gould, Nicholas S.; Xu, Bingjun Chemical Science, Vol. 9, Issue 2 https://doi.org/10.1039/C7SC03728G	journal	January 2018
Solid-state ¹ H NMR studies of the acidity of mordenites Heeribout, Lara; Semmer, Virginie; Batamack, Patrice J. Chem. Soc., Faraday Trans., Vol. 91, Issue 21 https://doi.org/10.1039/FT9959103933	journal	January 1995
Confinement effect on the interaction of hydroxy groups contained in the side pockets of H-mordenite with nitriles; a FT-IR study Anquetil, Rodolphe; Saussey, Jacques; Lavalley, Jean-Claude Physical Chemistry Chemical Physics, Vol. 1, Issue 4 https://doi.org/10.1039/a807260d	journal	January 1999
Acetonitrile as probe molecule for an integrated 1H NMR and FTIR study of zeolitic Brønsted acidity: Interaction with zeolites H-ferrierite and H-beta Paze´, C.; Zecchina, A.; Spera, S. Physical Chemistry Chemical Physics, Vol. 2, Issue 24 https://doi.org/10.1039/b005677o	journal	January 2000
Confirmation of the strongest nitriles–hydroxy groups interaction in the side pockets of mordenite zeolites Marie, Olivier; Thibault-Starzyk, Fre´de´ric; Lavalley, Jean-Claude Physical Chemistry Chemical Physics, Vol. 2, Issue 22 https://doi.org/10.1039/b005901n	journal	January 2000
A calorimetric and statistical mechanics study of water adsorption in zeolite NaY Boddenberg, B.; Rakhmatkariev, G. U.; Hufnagel, S. Physical Chemistry Chemical Physics, Vol. 4, Issue 17 https://doi.org/10.1039/b203088h	journal	August 2002
Protonation of water clusters in the cavities of acidic zeolites: (H2O)n·H-chabazite, n = 1–4 Vener, Mikhail V.; Rozanska, Xavier; Sauer, Joachim Physical Chemistry Chemical Physics, Vol. 11, Issue 11 https://doi.org/10.1039/b817905k	journal	January 2009
Analysing and understanding the active site by IR spectroscopy Vimont, Alexandre; Thibault-Starzyk, Frédéric; Daturi, Marco Chemical Society Reviews, Vol. 39, Issue 12 https://doi.org/10.1039/b919543m	journal	January 2010
Gamma-valerolactone, a sustainable platform molecule derived from lignocellulosic biomass Alonso, David Martin; Wettstein, Stephanie G.; Dumesic, James A. Green Chemistry, Vol. 15, Issue 3 https://doi.org/10.1039/c3gc37065h	journal	January 2013
Spontaneous nucleation and growth of pure silica zeolite-? free of connectivity defects Camblor, Miguel A.; Corma, Avelino; Valencia, Susana Chemical Communications, Issue 20 https://doi.org/10.1039/cc9960002365	journal	January 1996
Pyridine and ammonia as probes for FTIR analysis of solid acid catalysts Barzetti, Tommy; Selli, Elena; Moscotti, Daniele Journal of the Chemical Society, Faraday Transactions, Vol. 92, Issue 8 https://doi.org/10.1039/ft9969201401	journal	January 1996
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu Grimme, Stefan; Antony, Jens; Ehrlich, Stephan The Journal of Chemical Physics, Vol. 132, Issue 15 https://doi.org/10.1063/1.3382344	journal	April 2010
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
From ultrasoft pseudopotentials to the projector augmented-wave method Kresse, G.; Joubert, D. Physical Review B, Vol. 59, Issue 3, p. 1758-1775 https://doi.org/10.1103/PhysRevB.59.1758	journal	January 1999
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Phase Modifiers Promote Efficient Production of Hydroxymethylfurfural from Fructose Roman-Leshkov, Yuriy; Chheda, Juben N.; Dumesic, James A. Science, Vol. 312, Issue 5782, p. 1933-1937 https://doi.org/10.1126/science.1126337	journal	June 2006

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