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Title: Wege zur Verwertung von Lignin: Fortschritte in der Biotechnik, der Bioraffination und der Katalyse

Journal Article · · Angewandte Chemie
ORCiD logo [1];  [2];  [3];  [4];  [3]; ORCiD logo [2];  [2]
  1. Department of Chemical Engineering, Imperial College London, South Kensington Campus London SW7 2AZ Großbritannien
  2. Inorganic Chemistry and Catalysis, Debye Institute for Nanomaterials Science, Utrecht University, Universiteitsweg 99 3584 CG Utrecht Niederlande
  3. Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1 45470 Mülheim an der Ruhr Deutschland
  4. Department of Energy's Great Lakes Bioenergy Research Center, Wisconsin Energy Institute, and Department of Biochemistry, University of Wisconsin, Madison WI 53726 USA

Sponsoring Organization:
USDOE
Grant/Contract Number:
BER DE-FC02-07ER64494
OSTI ID:
1619412
Journal Information:
Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 128 Journal Issue: 29; ISSN 0044-8249
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English

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  • del Río, José C.; Rencoret, Jorge; Marques, Gisela
  • Journal of Agricultural and Food Chemistry, Vol. 56, Issue 20, p. 9525-9534 https://doi.org/10.1021/jf800806h
journal October 2008
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A Critical View on Catalytic Pyrolysis of Biomass journal April 2015
Two-year field analysis of reduced recalcitrance transgenic switchgrass journal April 2014
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Over-expression of F5H in COMT-deficient Arabidopsis leads to enrichment of an unusual lignin and disruption of pollen wall formation: Lignin modification leads to male sterility journal November 2010
Aqueous-phase reforming of crude glycerol: effect of impurities on hydrogen production journal January 2016
Catalytic Ethanolysis of Kraft Lignin into High‐Value Small‐Molecular Chemicals over a Nanostructured α‐Molybdenum Carbide Catalyst journal June 2014
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From biomass to feedstock: one-step fractionation of lignocellulose components by the selective organic acid-catalyzed depolymerization of hemicellulose in a biphasic system journal January 2011
Inexpensive ionic liquids: [HSO 4 ] -based solvent production at bulk scale journal January 2014
Solution-State 2D NMR Spectroscopy of Plant Cell Walls Enabled by a Dimethylsulfoxide- d 6 /1-Ethyl-3-methylimidazolium Acetate Solvent journal March 2013
Cleavage of CO Bonds in Lignin Model Compounds Catalyzed by Methyldioxorhenium in Homogeneous Phase journal January 2014
Significant Increases in Pulping Efficiency in C4H-F5H-Transformed Poplars:  Improved Chemical Savings and Reduced Environmental Toxins journal October 2003
Cleavage and hydrodeoxygenation (HDO) of C–O bonds relevant to lignin conversion using Pd/Zn synergistic catalysis journal January 2013
Inheritance and phenotype expression of functional and null alleles of aromatic alcohol dehydrogenase (CAD) in diploid wheats journal November 2014
Ionic Liquid as a Green Solvent for Lignin journal April 2007
Mechanochemical degradation of lignin and wood by solvent-free grinding in a reactive medium journal January 2013
Ptr-miR397a is a negative regulator of laccase genes affecting lignin content in Populus trichocarpa journal June 2013
Biorefining of softwoods using ethanol organosolv pulping: Preliminary evaluation of process streams for manufacture of fuel-grade ethanol and co-products journal January 2005
Stability of Pt/γ-Al2O3 Catalysts in Model Biomass Solutions journal March 2012
New routes for lignin biosynthesis defined by biochemical characterization of recombinant ferulate 5-hydroxylase, a multifunctional cytochrome P450-dependent monooxygenase journal August 1999
Overexpression of AtSTO1 leads to improved salt tolerance in Populus tremula × P. alba journal June 2014
Solvent Effects on the Hydrogenolysis of Diphenyl Ether with Raney Nickel and their Implications for the Conversion of Lignin journal April 2012
Softwood and Hardwood Lignin Fluorescence Spectra of Wood Cell Walls in Different Mounting Media journal January 2013
Fate of lignins in soils: A review journal August 2010
Ethanol as capping agent and formaldehyde scavenger for efficient depolymerization of lignin to aromatics journal January 2015
Disruption of Mediator rescues the stunted growth of a lignin-deficient Arabidopsis mutant journal March 2014
Tuning the lignin oil OH-content with Ru and Pd catalysts during lignin hydrogenolysis on birch wood journal January 2015
Kraft Lignin-Based Rigid Polyurethane Foam journal July 2012
Induced transcriptional profiling of phenylpropanoid pathway genes increased flavonoid and lignin content in Arabidopsis leaves in response to microbial products journal January 2014
Bond Dissociation Enthalpies of a Dibenzodioxocin Lignin Model Compound journal July 2013
Nachwachsende Rohstoffe: das Problem der Katalysatordesaktivierung und Wege zu seiner Lösung journal September 2015
Down-regulation of the caffeic acid O-methyltransferase gene in switchgrass reveals a novel monolignol analog journal January 2012
Trimethylenemethane-Ruthenium(II)-Triphos Complexes as Highly Active Catalysts for Catalytic CO Bond Cleavage Reactions of Lignin Model Compounds journal August 2012
A polymer of caffeyl alcohol in plant seeds journal January 2012
Structural Changes in Lignin During Kraft Cooking Part 3. On the Structure of Dissolved Lignins journal September 1984
Lignin Depolymerization into Aromatic Monomers over Solid Acid Catalysts journal November 2014
NMR Evidence for Benzodioxane Structures Resulting from Incorporation of 5-Hydroxyconiferyl Alcohol into Lignins of O-Methyltransferase-Deficient Poplars journal November 2000
Performance of lignin derived aromatic oxygenates in a heavy-duty diesel engine journal January 2014
Dissolution of lignocellulosic materials and its constituents using ionic liquids—A review journal November 2010
Selective Degradation of Wood Lignin over Noble‐Metal Catalysts in a Two‐Step Process journal July 2008
Important Issues and Results from Knut Lundquist's Lignin Research at Chalmers journal September 2014
Correction: Deciphering ‘water-soluble lignocellulose’ obtained by mechanocatalysis: new insights into the chemical processes leading to deep depolymerization journal January 2014
Structural analysis for lignin characteristics in biomass straw journal October 2013
Lignin Depolymerization and Conversion A Review of Thermochemical Methods journal November 2010
Ionic liquids: not always innocent solvents for cellulose journal January 2015
Recent advances in low-cost carbon fiber manufacture from lignin journal April 2013
Petroleomics: Chemistry of the underworld journal October 2008
Degradation of Carbohydrates during Dilute Sulfuric Acid Pretreatment Can Interfere with Lignin Measurements in Solid Residues journal March 2013
Characterization of Miscanthus giganteus Lignin Isolated by Ethanol Organosolv Process under Reflux Condition journal August 2012
Cycloaddition of Biomass-Derived Furans for Catalytic Production of Renewable p -Xylene journal April 2012
Hydrodeoxygenation of Anisole over Silica-Supported Ni 2 P, MoP, and NiMoP Catalysts journal March 2011
A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin journal October 2014
A Genomics Approach to Deciphering Lignin Biosynthesis in Switchgrass journal November 2013
Catalytic C−O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers journal September 2010
Quantitative hsqc Analyses of Lignin: a Practical Comparison journal March 2013
Selective cleavage of the C α –C β linkage in lignin model compounds via Baeyer–Villiger oxidation journal January 2015
A Mechanistic Investigation of Acid-Catalyzed Cleavage of Aryl-Ether Linkages: Implications for Lignin Depolymerization in Acidic Environments journal November 2013
13 C-NMR Spectra of Kraft Lignins journal January 1983
Transition-metal catalyzed valorization of lignin: the key to a sustainable carbon-neutral future journal January 2016
Molecular phenotyping of lignin-modified tobacco reveals associated changes in cell-wall metabolism, primary metabolism, stress metabolism and photorespiration: Molecular phenotyping of lignin-modified tobacco journal August 2007
Genetic manipulation of lignin reduces recalcitrance and improves ethanol production from switchgrass journal February 2011
Catalytic Biorefining of Plant Biomass to Non-Pyrolytic Lignin Bio-Oil and Carbohydrates through Hydrogen Transfer Reactions journal June 2014
Reductive deconstruction of organosolv lignin catalyzed by zeolite supported nickel nanoparticles journal January 2015
Potential transgenic routes to increase tree biomass journal November 2013
Hydrodeoxygenation of mono- and dimeric lignin model compounds on noble metal catalysts journal September 2014
Vanillin: Synthetic Flavoring from Spent Sulfite Liquor journal September 1997
Softwood kraft lignin for value-added applications: Fractionation and structural characterization journal April 2015
Catalytic Hydrotreatment of Fast Pyrolysis Oils Using Supported Metal Catalysts book November 2014
Acid in ionic liquid: An efficient system for hydrolysis of lignocellulose journal January 2008
Metabolic engineering for p -coumaryl alcohol production in Escherichia coli by introducing an artificial phenylpropanoid pathway : Phenylpropanoids Produced in Bacteria journal November 2014
Synergien zwischen Bio- und Ölraffinerien bei der Herstellung von Biomassetreibstoffen journal September 2007
Looking for Arabidopsis thaliana peroxidases involved in lignin biosynthesis journal June 2013
Peroxidase and not laccase is the enzyme responsible for cell wall lignification in the secondary thickening of xylem vessels inLupinus journal March 1995
Naturally p-Hydroxybenzoylated Lignins in Palms journal February 2015
CC or CO Bond Cleavage in a Phenolic Lignin Model Compound: Selectivity Depends on Vanadium Catalyst journal January 2012
The cell biology of lignification in higher plants journal April 2015
Tricin, a Flavonoid Monomer in Monocot Lignification journal February 2015
Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts journal June 2015
Down-regulation of Cinnamoyl-CoA Reductase induces significant changes of lignin profiles in transgenic tobacco plants journal January 1998
Hydrogenolysis of β-O-4 lignin model dimers by a ruthenium-xantphos catalyst journal January 2012
Isolation of Functionalized Phenolic Monomers through Selective Oxidation and CO Bond Cleavage of the β-O-4 Linkages in Lignin journal November 2014
A Possible Mechanism for the Oxidation of Sinapyl Alcohol by Peroxidase-Dependent Reactions in the Apoplast: Enhancement of the Oxidation by Hydroxycinnamic Acids and Components of the Apoplast journal June 1996
Unprecedented organocatalytic reduction of lignin model compounds to phenols and primary alcohols using hydrosilanes journal January 2014
Sequencing around 5-Hydroxyconiferyl Alcohol-Derived Units in Caffeic Acid O -Methyltransferase-Deficient Poplar Lignins journal April 2010
Suppression of CCR impacts metabolite profile and cell wall composition in Pinus radiata tracheary elements journal November 2012
Ruthenium-Catalyzed CC Bond Cleavage in Lignin Model Substrates journal March 2015
Value-added uses for crude glycerol--a byproduct of biodiesel production journal January 2012
Elucidation of new structures in lignins of CAD- and COMT-deficient plants by NMR journal July 2001
Acidolysis book January 1992
Switchgrass (Panicum virgatum) possesses a divergent family of cinnamoyl CoA reductases with distinct biochemical properties journal September 2009
The Simultaneous Repression of CCR and CAD, Two Enzymes of the Lignin Biosynthetic Pathway, Results in Sterility and Dwarfism in Arabidopsis thaliana journal January 2011
Metabolic engineering of novel lignin in biomass crops journal October 2012
Highly Selective Catalytic Conversion of Phenolic Bio-Oil to Alkanes journal May 2009
Lignin Biosynthesis and Structure journal May 2010
NMR observation of a new lignin structure, a spiro-dienoneElectronic supplementary information (ESI) available: 13C, QUAT, HMBC and HSQC NMR spectra. See http://www.rsc.org/suppdata/cc/b1/b108285j/ journal December 2001
A lignocellulosic ethanol strategy via nonenzymatic sugar production: Process synthesis and analysis journal April 2015
Milled Wood Lignin: A Linear Oligomer journal November 2011
Disruption of LACCASE4 and 17 Results in Tissue-Specific Alterations to Lignification of Arabidopsis thaliana Stems journal March 2011
Distribution of Syringyl and Guaiacyl Lignins in Hardwoods in Relation to Habitat and Porosity Form in Wood journal January 1992
Adipic acid production from lignin journal January 2015
Solvents and Solvent Effects in Biomass Conversion book November 2014
Distinct cinnamoyl CoA reductases involved in parallel routes to lignin in Medicago truncatula journal September 2010
Progress in Green Polymer Composites from Lignin for Multifunctional Applications: A Review journal April 2014
Fractionation of lignocellulosic biomass with the ionic liquid 1-butylimidazolium hydrogen sulfate journal January 2014
Systematic analysis of maize class III peroxidase gene family reveals a conserved subfamily involved in abiotic stress response journal July 2015
A Route for Lignin and Bio-Oil Conversion: Dehydroxylation of Phenols into Arenes by Catalytic Tandem Reactions journal September 2013
Rewriting the lignin roadmap journal June 2002
Transgenic poplars with reduced lignin show impaired xylem conductivity, growth efficiency and survival: Transgenic poplars with reduced lignin journal February 2011
Production of monomeric phenols by thermochemical conversion of biomass: a review journal September 2001
Upgrading of lignin-derived bio-oils by catalytic hydrodeoxygenation journal January 2014
Lignin Pyrolysis Components and Upgrading—Technology Review journal February 2013
Thermal conversion of alkaline lignin and its structured derivatives to porous carbonized materials journal May 2011
Characterization of organosolv switchgrass lignin by using high performance liquid chromatography/high resolution tandem mass spectrometry using hydroxide-doped negative-ion mode electrospray ionization journal January 2014