Modulating reactivity and stability of metallic lithium via atomic doping

Lu, Ke; Xu, Haiping; He, Haiying; Gao, Siyuan; Li, Xun; Zheng, Chong; Xu, Tao; Cheng, Yingwen

doi:10.1039/D0TA02176H

Title: Modulating reactivity and stability of metallic lithium via atomic doping

Journal Article · 26 May 2020 · Journal of Materials Chemistry. A

DOI: https://doi.org/10.1039/D0TA02176H · OSTI ID:1618877

^[1]; Xu, Haiping ^[1];

^[2]; Gao, Siyuan ^[1]; Li, Xun ^[1]; Zheng, Chong ^[1];

^[1];

^[1]

Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, USA
Department of Physics and Astronomy, Valparaiso University, Valparaiso, USA

Doping Li with Ag or Al effectively modulate its inherent chemical activity and enables very stable Li metal batteries.

View Accepted Manuscript (Publisher)

Cite

Export

Save

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1618877

Journal Information:: Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 20 Vol. 8; ISSN JMCAET; ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

References (46)

An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
Ultrafine Silver Nanoparticles for Seeded Lithium Deposition toward Stable Lithium Metal Anode Yang, Chunpeng; Yao, Yonggang; He, Shuaiming Advanced Materials, Vol. 29, Issue 38 https://doi.org/10.1002/adma.201702714	journal	August 2017
Lithiophilic Cu-CuO-Ni Hybrid Structure: Advanced Current Collectors Toward Stable Lithium Metal Anodes Wu, Shuilin; Zhang, Zhenyu; Lan, Minhuan Advanced Materials, Vol. 30, Issue 9 https://doi.org/10.1002/adma.201705830	journal	January 2018
In Situ Li ₃ PS ₄ Solid-State Electrolyte Protection Layers for Superior Long-Life and High-Rate Lithium-Metal Anodes Liang, Jianwen; Li, Xiaona; Zhao, Yang Advanced Materials, Vol. 30, Issue 45 https://doi.org/10.1002/adma.201804684	journal	October 2018
A 3D and Stable Lithium Anode for High‐Performance Lithium–Iodine Batteries Li, Kang; Hu, Ziyu; Ma, Jizhen Advanced Materials, Vol. 31, Issue 33 https://doi.org/10.1002/adma.201902399	journal	June 2019
Failure Mechanism for Fast-Charged Lithium Metal Batteries with Liquid Electrolytes Lu, Dongping; Shao, Yuyan; Lozano, Terence Advanced Energy Materials, Vol. 5, Issue 3 https://doi.org/10.1002/aenm.201400993	journal	September 2014
Temperature‐dependent Nucleation and Growth of Dendrite‐Free Lithium Metal Anodes Yan, Kang; Wang, Jiangyan; Zhao, Shuoqing Angewandte Chemie https://doi.org/10.1002/ange.201905251	journal	July 2019
Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes Zhang, Rui; Chen, Xiao-Ru; Chen, Xiang Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201702099	journal	May 2017
Guiding Uniform Li Plating/Stripping through Lithium-Aluminum Alloying Medium for Long-Life Li Metal Batteries Ye, Huan; Zheng, Zi-Jian; Yao, Hu-Rong Angewandte Chemie International Edition, Vol. 58, Issue 4 https://doi.org/10.1002/anie.201811955	journal	December 2018
Facile Generation of Polymer-Alloy Hybrid Layers for Dendrite-Free Lithium-Metal Anodes with Improved Moisture Stability Jiang, Zhipeng; Jin, Liu; Han, Zhilong Angewandte Chemie International Edition, Vol. 58, Issue 33 https://doi.org/10.1002/anie.201905712	journal	July 2019
Measurements of bandgap narrowing in Si bipolar transistors Slotboom, J. W.; de Graaff, H. C. Solid-State Electronics, Vol. 19, Issue 10 https://doi.org/10.1016/0038-1101(76)90043-5	journal	October 1976
Lithium-aluminum/iron sulfide batteries Henriksen, G. L.; Vissers, D. R. Journal of Power Sources, Vol. 51, Issue 1-2 https://doi.org/10.1016/0378-7753(94)01965-7	journal	August 1994
A short review of failure mechanisms of lithium metal and lithiated graphite anodes in liquid electrolyte solutions Aurbach, D. Solid State Ionics, Vol. 148, Issue 3-4 https://doi.org/10.1016/S0167-2738(02)00080-2	journal	June 2002
Large-volume-change electrodes for Li-ion batteries of amorphous alloy particles held by elastomeric tethers Chen, Zonghai; Christensen, L.; Dahn, J. R. Electrochemistry Communications, Vol. 5, Issue 11 https://doi.org/10.1016/j.elecom.2003.08.017	journal	November 2003
Electrochemical Interphases for High-Energy Storage Using Reactive Metal Anodes Wei, Shuya; Choudhury, Snehashis; Tu, Zhengyuan Accounts of Chemical Research, Vol. 51, Issue 1 https://doi.org/10.1021/acs.accounts.7b00484	journal	December 2017
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Lithium Metal Anodes: Toward an Improved Understanding of Coupled Morphological, Electrochemical, and Mechanical Behavior Wood, Kevin N.; Noked, Malachi; Dasgupta, Neil P. ACS Energy Letters, Vol. 2, Issue 3 https://doi.org/10.1021/acsenergylett.6b00650	journal	February 2017
Solid-State Lithium Metal Batteries Promoted by Nanotechnology: Progress and Prospects Xin, Sen; You, Ya; Wang, Shaofei ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00175	journal	May 2017
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Electrochemical Energy Storage for Green Grid Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W. Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613 https://doi.org/10.1021/cr100290v	journal	May 2011
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Ultimate Limits to Intercalation Reactions for Lithium Batteries Whittingham, M. Stanley Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr5003003	journal	October 2014
Synthesis of Supported Platinum Nanoparticles from Li−Pt Solid Solution Xu, Tao; Lin, Chikai; Wang, Chao Journal of the American Chemical Society, Vol. 132, Issue 7 https://doi.org/10.1021/ja909442c	journal	February 2010
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries Gao, Yue; Zhao, Yuming; Li, Yuguang C. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06437	journal	October 2017
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
Design principles for electrolytes and interfaces for stable lithium-metal batteries Tikekar, Mukul D.; Choudhury, Snehashis; Tu, Zhengyuan Nature Energy, Vol. 1, Issue 9 https://doi.org/10.1038/nenergy.2016.114	journal	September 2016
A facile surface chemistry route to a stabilized lithium metal anode Liang, Xiao; Pang, Quan; Kochetkov, Ivan R. Nature Energy, Vol. 2, Issue 9 https://doi.org/10.1038/nenergy.2017.119	journal	July 2017
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes Zhao, Jie; Zhou, Guangmin; Yan, Kai Nature Nanotechnology, Vol. 12, Issue 10 https://doi.org/10.1038/nnano.2017.129	journal	July 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries Albertus, Paul; Babinec, Susan; Litzelman, Scott Nature Energy, Vol. 3, Issue 1 https://doi.org/10.1038/s41560-017-0047-2	journal	December 2017
Fast ion transport at solid–solid interfaces in hybrid battery anodes Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J. Nature Energy, Vol. 3, Issue 4 https://doi.org/10.1038/s41560-018-0096-1	journal	March 2018
Stable cycling of high-voltage lithium metal batteries in ether electrolytes Jiao, Shuhong; Ren, Xiaodi; Cao, Ruiguo Nature Energy, Vol. 3, Issue 9 https://doi.org/10.1038/s41560-018-0199-8	journal	July 2018
Langmuir–Blodgett artificial solid-electrolyte interphases for practical lithium metal batteries Kim, Mun Sek; Ryu, Ji-Hyun Nature Energy, Vol. 3, Issue 10 https://doi.org/10.1038/s41560-018-0237-6	journal	September 2018
Stable metal battery anodes enabled by polyethylenimine sponge hosts by way of electrokinetic effects Li, Guoxing; Liu, Zhe; Huang, Qingquan Nature Energy, Vol. 3, Issue 12 https://doi.org/10.1038/s41560-018-0276-z	journal	November 2018
Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
Bridging the academic and industrial metrics for next-generation practical batteries Cao, Yuliang; Li, Matthew; Lu, Jun Nature Nanotechnology, Vol. 14, Issue 3 https://doi.org/10.1038/s41565-019-0371-8	journal	February 2019
Self-smoothing anode for achieving high-energy lithium metal batteries under realistic conditions Niu, Chaojiang; Pan, Huilin; Xu, Wu Nature Nanotechnology, Vol. 14, Issue 6 https://doi.org/10.1038/s41565-019-0427-9	journal	April 2019
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Electrochemical in situ investigations of SEI and dendrite formation on the lithium metal anode Bieker, Georg; Winter, Martin; Bieker, Peter Physical Chemistry Chemical Physics, Vol. 17, Issue 14 https://doi.org/10.1039/C4CP05865H	journal	January 2015
A fast and stable Li metal anode incorporating an Mo ₆ S ₈ artificial interphase with super Li-ion conductivity Lu, Ke; Gao, Siyuan; Dick, Robert J. Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/C8TA12450G	journal	January 2019
Lithium-ion batteries. A look into the future Scrosati, Bruno; Hassoun, Jusef; Sun, Yang-Kook Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c1ee01388b	journal	January 2011
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017
Factors Which Limit the Cycle Life of Rechargeable Lithium (Metal) Batteries Aurbach, D.; Zinigrad, E.; Teller, H. Journal of The Electrochemical Society, Vol. 147, Issue 4 https://doi.org/10.1149/1.1393349	journal	January 2000
Investigation of diode-pumped 28-μm Er:LiYF_4 lasers with various doping levels Jensen, T.; Chai, B. H. T.; Diening, A. Optics Letters, Vol. 21, Issue 8 https://doi.org/10.1364/OL.21.000585	journal	January 1996

Similar Records

Comparative Analysis of Reactivity of Al and Ga Doped Garnet Solid State Electrolyte at the Interface with Li Metal

Journal Article · 2024 · ACS Materials Letters · OSTI ID:2997243

Klenk, Matthew; Paul, Neelima; Counihan, Michael J.; +8 more

Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition

Journal Article · 2015 · ACS Nano · OSTI ID:1386080

Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J.; +6 more

Crystal Orientation-Dependent Reactivity of Oxide Surfaces in Contact with Lithium Metal

Journal Article · 2018 · ACS Applied Materials and Interfaces · OSTI ID:1455046

Connell, Justin G.; Zhu, Yisi; Zapol, Peter; +7 more

Title: Modulating reactivity and stability of metallic lithium via atomic doping

Citation Formats

References (46)

Similar Records

Related Subjects