Lithium Metal Anode Materials Design: Interphase and Host

Wang, Hansen; Liu, Yayuan; Li, Yuzhang; Cui, Yi

doi:10.1007/s41918-019-00054-2

Title: Lithium Metal Anode Materials Design: Interphase and Host

Journal Article · 12 October 2019 · Electrochemical Energy Reviews

DOI: https://doi.org/10.1007/s41918-019-00054-2 · OSTI ID:1618516

Wang, Hansen; Liu, Yayuan; Li, Yuzhang; Cui, Yi

Abstract Li metal is the ultimate anode choice due to its highest theoretical capacity and lowest electrode potential, but it is far from practical applications with its poor cycle lifetime. Recent research progresses show that materials designs of interphase and host structures for Li metal are two effective ways addressing the key issues of Li metal anodes. Despite the exciting improvement on Li metal cycling capability, problems still exist with these methodologies, such as the deficient long-time cycling stability of interphase materials and the accelerated Li corrosion for high surface area three-dimensional composite Li anodes. As a result, Coulombic efficiency of Li metal is still not sufficient for full-cell cycling. In the near future, an interphase protected three-dimensional composite Li metal anode, combined with high performance novel electrolytes might be the ultimate solution. Besides, nanoscale characterization technologies are also vital for guiding future Li metal anode designs. Graphic Abstract

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

OSTI ID:: 1618516

Journal Information:: Electrochemical Energy Reviews, Journal Name: Electrochemical Energy Reviews Journal Issue: 4 Vol. 2; ISSN 2520-8489

Publisher:: Springer Science + Business MediaCopyright Statement

Country of Publication:: Singapore

Language:: English

References (50)

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Conductive Nanostructured Scaffolds Render Low Local Current Density to Inhibit Lithium Dendrite Growth Zhang, Rui; Cheng, Xin-Bing; Zhao, Chen-Zi Advanced Materials, Vol. 28, Issue 11 https://doi.org/10.1002/adma.201504117	journal	January 2016
An Artificial Solid Electrolyte Interphase Layer for Stable Lithium Metal Anodes Li, Nian-Wu; Yin, Ya-Xia; Yang, Chun-Peng Advanced Materials, Vol. 28, Issue 9 https://doi.org/10.1002/adma.201504526	journal	December 2015
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
An Armored Mixed Conductor Interphase on a Dendrite-Free Lithium-Metal Anode Yan, Chong; Cheng, Xin-Bing; Yao, Yu-Xing Advanced Materials, Vol. 30, Issue 45 https://doi.org/10.1002/adma.201804461	journal	September 2018
Lithium Metal Anodes: Dual‐Layered Film Protected Lithium Metal Anode to Enable Dendrite‐Free Lithium Deposition (Adv. Mater. 25/2018) Yan, Chong; Cheng, Xin‐Bing; Tian, Yang Advanced Materials, Vol. 30, Issue 25 https://doi.org/10.1002/adma.201870181	journal	June 2018
Lithium-Metal Anodes: Incorporating Ionic Paths into 3D Conducting Scaffolds for High Volumetric and Areal Capacity, High Rate Lithium-Metal Anodes (Adv. Mater. 33/2018) Zhang, Chanyuan; Liu, Shan; Li, Guojie Advanced Materials, Vol. 30, Issue 33 https://doi.org/10.1002/adma.201870248	journal	August 2018
An Interconnected Channel-Like Framework as Host for Lithium Metal Composite Anodes Wang, Hansen; Lin, Dingchang; Xie, Jin Advanced Energy Materials, Vol. 9, Issue 7 https://doi.org/10.1002/aenm.201802720	journal	January 2019
Inside Cover: Lithiophilic Sites in Doped Graphene Guide Uniform Lithium Nucleation for Dendrite-Free Lithium Metal Anodes (Angew. Chem. Int. Ed. 27/2017) Zhang, Rui; Chen, Xiao-Ru; Chen, Xiang Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201704344	journal	May 2017
Inside Cover: A Flexible Solid Electrolyte Interphase Layer for Long-Life Lithium Metal Anodes (Angew. Chem. Int. Ed. 6/2018) Li, Nian-Wu; Shi, Yang; Yin, Ya-Xia Angewandte Chemie International Edition, Vol. 57, Issue 6 https://doi.org/10.1002/anie.201713193	journal	January 2018
Controlling Nucleation in Lithium Metal Anodes Guan, Xuze; Wang, Aoxuan; Liu, Shan Small, Vol. 14, Issue 37 https://doi.org/10.1002/smll.201801423	journal	July 2018
A carbon-based 3D current collector with surface protection for Li metal anode Zhang, Ying; Liu, Boyang; Hitz, Emily Nano Research, Vol. 10, Issue 4 https://doi.org/10.1007/s12274-017-1461-2	journal	March 2017
Graphite-Encapsulated Li-Metal Hybrid Anodes for High-Capacity Li Batteries Sun, Yongming; Zheng, Guangyuan; Seh, Zhi Wei Chem, Vol. 1, Issue 2 https://doi.org/10.1016/j.chempr.2016.07.009	journal	August 2016
Implantable Solid Electrolyte Interphase in Lithium-Metal Batteries Cheng, Xin-Bing; Yan, Chong; Chen, Xiang Chem, Vol. 2, Issue 2 https://doi.org/10.1016/j.chempr.2017.01.003	journal	February 2017
Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries Fan, Xiulin; Chen, Long; Ji, Xiao Chem, Vol. 4, Issue 1 https://doi.org/10.1016/j.chempr.2017.10.017	journal	January 2018
Horizontal Centripetal Plating in the Patterned Voids of Li/Graphene Composites for Stable Lithium-Metal Anodes Wang, Aoxuan; Zhang, Xinyue; Yang, Ying-Wei Chem, Vol. 4, Issue 9 https://doi.org/10.1016/j.chempr.2018.06.017	journal	September 2018
Fundamental study on the wetting property of liquid lithium Wang, Jiangyan; Wang, Hansen; Xie, Jin Energy Storage Materials, Vol. 14 https://doi.org/10.1016/j.ensm.2018.05.021	journal	September 2018
Coralloid Carbon Fiber-Based Composite Lithium Anode for Robust Lithium Metal Batteries Zhang, Rui; Chen, Xiang; Shen, Xin Joule, Vol. 2, Issue 4 https://doi.org/10.1016/j.joule.2018.02.001	journal	April 2018
High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes Chen, Shuru; Zheng, Jianming; Yu, Lu Joule, Vol. 2, Issue 8 https://doi.org/10.1016/j.joule.2018.05.002	journal	August 2018
Lithium surface protection by polyacetylene in situ polymerization Belov, D. G.; Yarmolenko, O. V.; Peng, A. Synthetic Metals, Vol. 156, Issue 9-10 https://doi.org/10.1016/j.synthmet.2006.04.006	journal	May 2006
Design of Complex Nanomaterials for Energy Storage: Past Success and Future Opportunity Liu, Yayuan; Zhou, Guangmin; Liu, Kai Accounts of Chemical Research, Vol. 50, Issue 12 https://doi.org/10.1021/acs.accounts.7b00450	journal	December 2017
Stable Artificial Solid Electrolyte Interphases for Lithium Batteries Ma, Lin; Kim, Mun Sek; Archer, Lynden A. Chemistry of Materials, Vol. 29, Issue 10 https://doi.org/10.1021/acs.chemmater.6b03687	journal	May 2017
Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Chemical Reviews, Vol. 117, Issue 15 https://doi.org/10.1021/acs.chemrev.7b00115	journal	July 2017
Conformal Lithium Fluoride Protection Layer on Three-Dimensional Lithium by Nonhazardous Gaseous Reagent Freon Lin, Dingchang; Liu, Yayuan; Chen, Wei Nano Letters, Vol. 17, Issue 6 https://doi.org/10.1021/acs.nanolett.7b01020	journal	May 2017
Wrinkled Graphene Cages as Hosts for High-Capacity Li Metal Anodes Shown by Cryogenic Electron Microscopy Wang, Hansen; Li, Yuzhang; Li, Yanbin Nano Letters, Vol. 19, Issue 2 https://doi.org/10.1021/acs.nanolett.8b04906	journal	January 2019
Robust Pinhole-free Li ₃ N Solid Electrolyte Grown from Molten Lithium Li, Yanbin; Sun, Yongming; Pei, Allen ACS Central Science, Vol. 4, Issue 1 https://doi.org/10.1021/acscentsci.7b00480	journal	December 2017
Next-Generation Lithium Metal Anode Engineering via Atomic Layer Deposition Kozen, Alexander C.; Lin, Chuan-Fu; Pearse, Alexander J. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b02166	journal	May 2015
Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries Xu, Kang Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418 https://doi.org/10.1021/cr030203g	journal	October 2004
Electrolytes and Interphases in Li-Ion Batteries and Beyond Xu, Kang Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500003w	journal	October 2014
Dendrite-Free Lithium Deposition via Self-Healing Electrostatic Shield Mechanism Ding, Fei; Xu, Wu; Graff, Gordon L. Journal of the American Chemical Society, Vol. 135, Issue 11, p. 4450-4456 https://doi.org/10.1021/ja312241y	journal	March 2013
Surface Fluorination of Reactive Battery Anode Materials for Enhanced Stability Zhao, Jie; Liao, Lei; Shi, Feifei Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05251	journal	August 2017
Ultrathin Two-Dimensional Atomic Crystals as Stable Interfacial Layer for Improvement of Lithium Metal Anode Yan, Kai; Lee, Hyun-Wook; Gao, Teng Nano Letters, Vol. 14, Issue 10 https://doi.org/10.1021/nl503125u	journal	September 2014
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Lithium-coated polymeric matrix as a minimum volume-change and dendrite-free lithium metal anode Liu, Yayuan; Lin, Dingchang; Liang, Zheng Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10992	journal	March 2016
High rate and stable cycling of lithium metal anode Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7362	journal	February 2015
The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth Li, Weiyang; Yao, Hongbin; Yan, Kai Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8436	journal	June 2015
Accommodating lithium into 3D current collectors with a submicron skeleton towards long-life lithium metal anodes Yang, Chun-Peng; Yin, Ya-Xia; Zhang, Shuai-Feng Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9058	journal	August 2015
Selective deposition and stable encapsulation of lithium through heterogeneous seeded growth Yan, Kai; Lu, Zhenda; Lee, Hyun-Wook Nature Energy, Vol. 1, Issue 3, Article No. 16010 https://doi.org/10.1038/nenergy.2016.10	journal	February 2016
Stable lithium electrodeposition in liquid and nanoporous solid electrolytes Lu, Yingying; Tu, Zhengyuan; Archer, Lynden A. Nature Materials, Vol. 13, Issue 10 https://doi.org/10.1038/nmat4041	journal	August 2014
Interconnected hollow carbon nanospheres for stable lithium metal anodes Zheng, Guangyuan; Lee, Seok Woo; Liang, Zheng Nature Nanotechnology, Vol. 9, Issue 8 https://doi.org/10.1038/nnano.2014.152	journal	July 2014
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes Lin, Dingchang; Liu, Yayuan; Liang, Zheng Nature Nanotechnology, Vol. 11, Issue 7 https://doi.org/10.1038/nnano.2016.32	journal	March 2016
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Solubility-mediated sustained release enabling nitrate additive in carbonate electrolytes for stable lithium metal anode Liu, Yayuan; Lin, Dingchang; Li, Yuzhang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06077-5	journal	September 2018
Ionomer-Liquid Electrolyte Hybrid Ionic Conductor for High Cycling Stability of Lithium Metal Electrodes Song, Jongchan; Lee, Hongkyung; Choo, Min-Ju Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14458	journal	September 2015
Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries Suo, Liumin; Xue, Weijiang; Gobet, Mallory Proceedings of the National Academy of Sciences, Vol. 115, Issue 6 https://doi.org/10.1073/pnas.1712895115	journal	January 2018
High-capacity rechargeable batteries based on deeply cyclable lithium metal anodes Shi, Qiuwei; Zhong, Yiren; Wu, Min Proceedings of the National Academy of Sciences, Vol. 115, Issue 22 https://doi.org/10.1073/pnas.1803634115	journal	May 2018
Ultrahigh–current density anodes with interconnected Li metal reservoir through overlithiation of mesoporous AlF ₃ framework Wang, Hansen; Lin, Dingchang; Liu, Yayuan Science Advances, Vol. 3, Issue 9 https://doi.org/10.1126/sciadv.1701301	journal	September 2017
Engineering stable interfaces for three-dimensional lithium metal anodes Xie, Jin; Wang, Jiangyan; Lee, Hye Ryoung Science Advances, Vol. 4, Issue 7 https://doi.org/10.1126/sciadv.aat5168	journal	July 2018
Lithiophilicity chemistry of heteroatom-doped carbon to guide uniform lithium nucleation in lithium metal anodes Chen, Xiang; Chen, Xiao-Ru; Hou, Ting-Zheng Science Advances, Vol. 5, Issue 2 https://doi.org/10.1126/sciadv.aau7728	journal	February 2019
Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy Li, Yuzhang; Li, Yanbin; Pei, Allen Science, Vol. 358, Issue 6362 https://doi.org/10.1126/science.aam6014	journal	October 2017

Similar Records

A Highly Reversible, Dendrite‐Free Lithium Metal Anode Enabled by a Lithium‐Fluoride‐Enriched Interphase

Journal Article · 2020 · Advanced Materials · OSTI ID:1599685

Cui, Chunyu; Yang, Chongyin; Eidson, Nico; +7 more

Tortuosity Effects in Lithium-Metal Host Anodes

Journal Article · 2020 · Joule · OSTI ID:1633600

Chen, Hao; Pei, Allen; Wan, Jiayu; +12 more

Recent Progress in Understanding Solid Electrolyte Interphase on Lithium Metal Anodes

Journal Article · 2020 · Advanced Energy Materials · OSTI ID:1804553

Wu, Haiping; Jia, Hao; Wang, Chongmin; +2 more

Title: Lithium Metal Anode Materials Design: Interphase and Host

Citation Formats

References (50)

Similar Records

Related Subjects