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Title: Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials

Abstract

Zirconium doping has a dramatically different influence on Ce reduction in the bulk than on the surface of ceria–zirconia.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [4];  [1]; ORCiD logo [1];  [3]; ORCiD logo [1]
  1. Department of Materials Science and Engineering, Northwestern University, USA
  2. DND-CAT, Northwestern Synchrotron Research Center at the Advanced Photon Source, Argonne, USA
  3. Department of Materials Science and Engineering, University of Maryland, College Park, USA
  4. Advanced Photon Source, Argonne National Laboratory, Argonne, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1617968
Grant/Contract Number:  
AC02-06CH11357; FG02-03ER15457
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 19; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Yuan, Weizi, Ma, Qing, Liang, Yangang, Sun, Chengjun, Narayanachari, K. V. L. V., Bedzyk, Michael J., Takeuchi, Ichiro, and Haile, Sossina M. Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials. United Kingdom: N. p., 2020. Web. doi:10.1039/D0TA02762F.
Yuan, Weizi, Ma, Qing, Liang, Yangang, Sun, Chengjun, Narayanachari, K. V. L. V., Bedzyk, Michael J., Takeuchi, Ichiro, & Haile, Sossina M. Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials. United Kingdom. doi:https://doi.org/10.1039/D0TA02762F
Yuan, Weizi, Ma, Qing, Liang, Yangang, Sun, Chengjun, Narayanachari, K. V. L. V., Bedzyk, Michael J., Takeuchi, Ichiro, and Haile, Sossina M. Tue . "Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials". United Kingdom. doi:https://doi.org/10.1039/D0TA02762F.
@article{osti_1617968,
title = {Unexpected trends in the enhanced Ce 3+ surface concentration in ceria–zirconia catalyst materials},
author = {Yuan, Weizi and Ma, Qing and Liang, Yangang and Sun, Chengjun and Narayanachari, K. V. L. V. and Bedzyk, Michael J. and Takeuchi, Ichiro and Haile, Sossina M.},
abstractNote = {Zirconium doping has a dramatically different influence on Ce reduction in the bulk than on the surface of ceria–zirconia.},
doi = {10.1039/D0TA02762F},
journal = {Journal of Materials Chemistry. A},
number = 19,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {5}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: https://doi.org/10.1039/D0TA02762F

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